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Material Safety Data Sheet Zep Zep Inc. Section 1. Chemical Product and Company Professional 1310 Seaboard Identification Industrial Blvd. Atlanta, GA 30318 1-877-793-7776 Product name BROMINATED SOLVENT DEGREASER AEROSOL Product use Degreaser Product code R192 Date of issue 08/20/09 Supersedes Emergency Telephone Numbers For MSDS Information: Compliance Services 1-877-793-7776 For Medical Emergency (877) 541-2016 Toll Free - All Calls Recorded For Transportation Emergency CHEMTREC: (800) 424-9300 - All Calls Recorded In the District of Columbia (202) 483-7616 Prepared By Compliance Services 1420 Seaboard Industrial Blvd. Atlanta, GA 30318 Section 2: Hazards Identification Emergency overview *Hazard Determination System (HDS): Health, Flammability, Reactivity WARNING ! 2 0 0 VAPOR HARMFUL. HARMFUL IF ABSORBED THROUGH SKIN. CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION. CONTENTS UNDER PRESSURE. NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all prescribed safety precautions, including the use of proper personal protective equipment. Acute Effects Routes of Entry Dermal contact. Eye contact. Inhalation. Eyes Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching. Skin Causes skin irritation. Harmful if absorbed through the skin. Direct contact may cause irritation and redness. Prolonged or repeated contact may dry skin and cause irritation. Inhalation Over-exposure by inhalation may cause respiratory irritation. Can cause central nervous system (CNS) depression. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea. Ingestion Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. Chronic effects Inhalation of spray mists or vapors may cause central nervous system depression characterized by headache, dizziness, nausea, stupor, weakness and/or numbness and tingling in the extremities (medical term - peripheral neuropathy). The substance may be toxic to kidneys, lungs, liver, peripheral nervous system and central nervous system (CNS). Carcinogenicity Ingredients: Not listed as carcinogen by OSHA, NTP or IARC. Product/ingredient name Not available. Additional Information: See Toxicological Information (Section 11) Section 3. Composition/Information on Ingredients CAS number 1-BROMOPROPANE; n-propyl bromide 106-94-5 >95 t-butyl alcohol 75-65-0 <5 METHYLAL; dimethoxymethane 109-87-5 <5 CARBON DIOXIDE 124-38-9 1 - 5 Section 4. First Aid Measures Eye Contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately. Skin Contact Flush affected skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Wash clothing before reuse. Get medical attention if irritation develops. Inhalation Move exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, administer oxygen. Get medical attention immediately. Ingestion Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention immediately. Section 5. Fire Fighting Measures National Fire Protection Association (U.S.A.) Flash Point Not available. Flammable Limits Lower: 4.6% Upper: 8.5% Flammability Non-flammable. (CSMA) Fire hazard CONTENTS UNDER PRESSURE. May emit toxic fumes under fire conditions. Bursting aerosol containers may be propelled from a fire at high speed. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Vapor will form a flammable mixture in a narrow concentration range of 4.6% to 8.5% by volume in air. Fire-Fighting Procedures Use an extinguishing agent suitable for the surrounding fire. Section 6. Accidental Release Measures Spill Clean up Large spills are unlikely due to packaging. Section 7. Handling and Storage Handling Put on appropriate personal protective equipment (see section 8). Avoid contact with eyes, skin and clothing. Do not breathe vapor or mist. Use only with adequate ventilation. Watch for accumulation in low confined areas. Wash thoroughly after handling. Storage CONTENTS UNDER PRESSURE. Do not puncture or incinerate container. Store between the following temperatures: 4.4�C (39.9�F). Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep out of the reach of children. Section 8. Exposure Controls/Personal Protection Product name Exposure Limits 1-BROMOPROPANE; n-propyl bromide US EPA (United States). TWA: 25 ppm 8 hour(s). Supplier (United States). TWA: 100 ppm 8 hour(s). t-butyl alcohol ACGIH TLV (United States). TWA: 100 ppm METHYLAL; dimethoxymethane OSHA PEL (United States). TWA: 1000 ppm CARBON DIOXIDE ACGIH TLV (United States). TWA: 5000 ppm 8 hour(s). STEL: 30000 ppm 15 minute(s). Personal Protective Equipment (PPE) Eyes Splash goggles. Body Recommended: Viton gloves. Respiratory Use with adequate ventilation. Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective occupational exposure limits. Wear appropriate respirator when ventilation is inadequate. Section 9. Physical and Chemical Properties Physical State Liquid. [Aerosol.] Color Clear. Colorless. pH Not applicable. Odor Characteristic. (Strong.) Boiling Point 70�C (158�F) Vapor Pressure 15.5 kPa (116 mm Hg) Specific 1.35 (Water = 1) Vapor Density >1 (Air=1) Gravity Solubility Very slightly soluble in the Evaporation >1 compared with following materials: cold Rate Butyl acetate. water and hot water. VOC (Consumer) 1303.39 (g/l). 10.88 Ibs/gal (96.50%) Section 10. Stability and Reactivity Stability and The product is stable. Reactivity Incompatibility Reactive or incompatible with the following materials: natural rubber (latex), oxidizing materials, metals, acids and alkalis. Prolonged contact with aluminum, magnesium and zinc. Hazardous Will not occur. Polymerization Hazardous Decomposition Carbon oxides (CO2), Carbon monoxide and Hydrogen Products Bromide (HBr). Section 11. Toxicological Information Acute Toxicity Product/ingredient Result Species Dose Exposure name 1-Bromopropane LD50 Oral Rat 4260 mg/kg - LC50 Inhalation Rat 14374 ppm 4 hours Vapor 2-methyl-2-propanol LD50 Dermal Rat 2743 mg/kg - LC50 Inhalation Rat >10000 ppm 4 hours Vapor METHYLAL LD50 Oral Rat >7950 mg/kg - LD50 Oral Rabbit 5708 mg/kg - Section 12. Ecological Information Environmental Effects No known significant effects or critical hazards. Aquatic Ecotoxicity Not available. Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities for additional information. Waste Stream Code: - (Not applicable.) Classification: - (Non-hazardous waste) Section 14. Transport Information Regulatory UN number Proper shipping Classes PG* Label information name DOT Classification Not applicable. Consumer commodity ORM-D IMDG Class Not determined. NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to the Bill of Lading with your shipment. PG* : Packing group Section 15. Regulatory Information U.S. Federal Regulations SARA 313 toxic chemical notification and release reporting: Product name No products were found. Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. All Components of this product are listed or exempt from listing on TSCA Inventory. State Regulations California WARNING: This product contains a chemical or Prop 65 chemicals known to the state of California to cause cancer, birth defects or other reproductive harm.: 1- Bromopropane Section 16. Other Information To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. *NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although these ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to relay the meanings of this scale.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.