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Safety Data Sheet Date of Issue: |Revision Date: 05/04/2015 |Revision Number: 1.0 Imperial Supplies Part Number: 0071470 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: A07296 ZEP PRO ANTISPATTER R23001 20N19 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Phone: 404-352-1680 1.4. Emergency Telephone Number Emergency |For SDS Information: Compliance Services 1-877-428-9937 number |For a Medical Emergency: 877-541-2016 Toll Free - All Calls |Recorded |For a Transportation Emergency: CHEMTREC: 800-424-9300 - All Calls |Recorded. In the District of Columbia 202-483-7616 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Gases under |Compressed gas pressure | Skin |Category 2 irritation | Eye irritation|Category 2A Carcinogenicit|Category 1A y | Specific |Category 3 target organ |(Central toxicity |nervous -single |system) exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas |Health |Exclamat| | | |Cylinder|Hazard |ion Mark| | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H280 Contains gas under pressure; may explode if |heated. |H315 Causes skin irritation. |H319 Causes serious eye irritation. |H336 May cause drowsiness or dizziness. |H350 May cause cancer. Precautionary Statements |Prevention: (GHS-US) |P201 Obtain special instructions before use. |P202 Do not handle until all safety precautions have |been read and understood. |P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ |spray. |P264 Wash skin thoroughly after handling. |P271 Use only outdoors or in a well-ventilated area. | |P280 Wear eye protection/ face protection. |P280 Wear protective gloves. |P281 Use personal protective equipment as required. | |Response: |P302 + P352 IF ON SKIN: Wash with plenty of soap and |water. |P304 + P340 + P312 IF INHALED: Remove victim to |fresh air and keep at rest in a position comfortable |for breathing. Call a POISON CENTER or doctor/ |physician if you feel unwell. |P305 + P351 + P338 IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P308 + P313 IF exposed or concerned: Get medical |advice/ attention. |P332 + P313 If skin irritation occurs: Get medical |advice/ attention. |P337 + P313 If eye irritation persists: Get medical |advice/ attention. |P362 Take off contaminated clothing and wash before |reuse. | |Storage: |P403 + P233 Store in a well-ventilated place. Keep |container tightly closed. |P405 Store locked up. |P410 + P403 Protect from sunlight. Store in a |well-ventilated place. | |Disposal: |P501 Dispose of contents/container in accordance |with local regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Trichloroethylene |79-01-6 |>= 50 - | | |< 70 | Tetrachloroethylene |127-18-4 |>= 30 - | | |< 50 | Carbon dioxide |124-38-9 |>= 1 - <| | |5 | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. First-aid Measures After Inhalation: Consult a physician after significant exposure. If unconscious place in recovery position and seek medical advice. First-aid Measures After Skin Contact: If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. First-aid Measures After Eye Contact: Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes. First-aid Measures After Ingestion: Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Take victim immediately to hospital. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water spray jet Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable Extinguishing Media: High volume water jet 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Do not allow run-off from fire fighting to enter drains or water courses. Explosion Hazard: Carbon dioxide (CO2) Carbon monoxide Smoke Chlorine compounds Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Methods for Cleaning Up: Sweep up or vacuum up spillage and collect in suitable container for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Always replace cap after use. Dispose of rinse water in accordance with local and national regulations. Do not breathe vapours or spray mist. Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 �C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Keep in a dry, cool and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid: Oxidizing agents, Keep away from metals. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis trichloroethylene 79-01-6 TWA 10 ppm ACGIH STEL 25 ppm ACGIH TWA 100 ppm OSHA Z-2 CEIL 200 ppm OSHA Z-2 Peak 300 ppm OSHA Z-2 TWA 50 ppm 270 mg/m3 OSHA P0 STEL 200 ppm 1,080 mg/m3 OSHA P0 tetrachloroethylene 127-18-4 TWA 25 ppm ACGIH STEL 100 ppm ACGIH TWA 100 ppm OSHA Z-2 CEIL 200 ppm OSHA Z-2 Peak 300 ppm OSHA Z-2 TWA 25 ppm 170 mg/m3 OSHA P0 carbon dioxide 124-38-9 TWA 5,000 ppm ACGIH STEL 30,000 ppm ACGIH TWA 5,000 ppm 9,000 mg/m3 NIOSH REL ST 30,000 ppm 54,000 mg/m3 NIOSH REL TWA 5,000 ppm 9,000 mg/m3 OSHA Z-1 TWA 10,000 ppm 18,000 mg/m3 OSHA P0 STEL 30,000 ppm 54,000 mg/m3 OSHA P0 Biological occupational exposure limits Component CAS-No. Control parameters Biological specimen Sampling time Permissible concentration Basis TRICHLOROETHENE 79-01-6 Trichloroacetic acid Urine End of shift at end of workweek 15 mg/l ACGIH BEI TRICHLOROETHENE Trichloroethanol In blood End of shift at end of workweek 0.5 mg/l ACGIH BEI TRICHLOROETHENE Trichloroethylene In blood End of shift at end of workweek ACGIH BEI TRICHLOROETHENE Trichloroethylene In end-exhaled air End of shift at end of workweek ACGIH BEI TETRACHLOROETHENE 127-18-4 Tetrachloroethylene In blood Prior to shift (16 hours after exposure ceases) 0.5 mg/l ACGIH BEI TETRACHLOROETHENE Tetrachloroethylene In end-exhaled air Prior to shift (16 hours after exposure ceases) 3 .parts per million ACGIH BEI 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |The suitability for a specific workplace should be |discussed with the producers of the protective |gloves. Eye Protection |Tightly fitting safety goggles. Wear face-shield and |protective suit for abnormal processing problems. |Ensure that eyewash stations and safety showers are |close to the workstation location. Skin and Body Protection |Tightly fitting safety goggles. Wear face-shield and |protective suit for abnormal processing problems. |Ensure that eyewash stations and safety showers are |close to the workstation location. Respiratory Protection |Use respiratory protection unless adequate local |exhaust ventilation is provided or exposure |assessment demonstrates that exposures are within |recommended exposure guidelines. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Aerosol containing a compressed gas Odor |solvent-like Odor Threshold |no data available pH |no data available Relative Evaporation Rate |0.3 (butylacetate=1) | Melting Point |no data available Freezing Point |no data available Boiling Point |no data available Flash Point |not applicable Auto-ignition Temperature |not determined Decomposition Temperature |no data available Flammability (solid, gas) | Vapor Pressure |77 hPa Relative Vapor Density at 20 �C | Relative Density | Specific Gravity | Solubility |Insoluble Partition coefficient: |no data available n-octanol/water | Viscosity |no data available Lower Flammable Limit |not applicable Upper Flammable Limit |not applicable 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Vapours may form explosive mixture with air. No decomposition if stored and applied as directed. 10.4 Conditions to Avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Oxidizing agents Metals Alkali metals 10.6 Hazardous Decomposition Products Carbon oxides Gaseous hydrogen chloride (HCl). SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Product: Acute oral toxicity: Acute toxicity estimate : 4,057 mg/kg Method: Calculation method Acute dermal toxicity: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: trichloroethylene: Acute oral toxicity: LD50 Oral rat: 4,920 mg/kg Acute inhalation toxicity: LC50 mouse: 8450 ppm Exposure time: 4 h Acute dermal toxicity: LD50 Dermal rabbit: > 20,000 mg/kg tetrachloroethylene: Acute oral toxicity: LD50 Oral rat: 2,629 mg/kg Acute inhalation toxicity: LC50 rat: 34,200 mg/l Exposure time: 8 h Acute dermal toxicity: LD50 Dermal rabbit: 5,000 mg/kg Skin Corrosion/Irritation: Remarks: Irritating to skin. Serious Eye Damage/Irritation: Remarks: Severe eye irritation Respiratory or Skin Sensitization: no data available Germ Cell Mutagenicity: no data available Carcinogenicity: no data available Reproductive Toxicity: no data available Specific Target Organ Toxicity (Single Exposure): no data available Specific Target Organ Toxicity (Repeated Exposure): no data available Aspiration Hazard: no data available Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting., Concentrations substantially above the TLV value may cause narcotic effects., Solvents may degrease the skin. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity no data available 12.2. Persistence and Degradability no data available 12.3. Bioaccumulative Potential Product: Partition coefficient: n-octanol/water: Remarks: no data available Components: trichloroethylene : Partition coefficient: n-octanol/water: log Pow: 2.29 tetrachloroethylene : Partition coefficient: n-octanol/water: log Pow: 3.40 12.4. Mobility in Soil no data available 12.5. Other Adverse Effects no data available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste from residues: The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations. Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, NON-FLAMMABLE Hazard Class |2.2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, NON-FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.2 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> CERCLA Reportable Quantity Components CAS-No Component RQ (lbs) Calculated product RQ (lbs) Trichloroethylene 79-01-6 100 169 SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: The following components are subject to reporting levels established by SARA Title III, Section 313: Trichloroethylene 79-01-6 59 % Tetrachloroethylene 127-18-4 33.2799 % SARA Section 311/312 Hazard Classes |Sudden Release of Pressure Hazard |Acute Health Hazard |Chronic Health Hazard Toxic Substances Control Act (TSCA) |On TSCA Inventory 15.2 US State Regulations <COMPONENT> California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. Trichloroethylene 79-01-6 Tetrachloroethylene 127-18-4 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |05/04/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Hazard statements |Contains gas under pressure; may explode if -- | |heated. Causes skin irritation. Causes | |serious eye irritation. May cause drowsiness | |or dizziness. May cause cancer. ----|Precautionary statements |Prevention: Obtain special instructions -- | |before use. Do not handle until all safety | |precautions have been read and understood. | |Avoid breathing dust/ fume/ gas/ mist/ | |vapours/ spray. Wash skin thoroughly after | |handling. Use only outdoors or in a | |well-ventilated area. Wear eye protection/ | |face protection. Wear protective gloves. Use | |personal protective equipment as required. ----| |Response: IF ON SKIN: Wash with plenty of -- | |soap and water. IF INHALED: Remove victim to | |fresh air and keep at rest in a position | |comfortable for breathing. Call a POISON | |CENTER or doctor/ physician if you feel | |unwell. IF IN EYES: Rinse cautiously with | |water for several minutes. Remove contact | |lenses, if present and easy to do. Continue | |rinsing. IF exposed or concerned: Get medical | |advice/ attention. If skin irritation occurs: | |Get medical advice/ attention. If eye | |irritation persists: Get medical advice/ | |attention. Take off contaminated clothing and | |wash before reuse. ----| |Storage: Store in a well-ventilated place. -- | |Keep container tightly closed. Store locked | |up. Protect from sunlight. Store in a | |well-ventilated place. ----| |Storage: Store in a well-ventilated place. -- | |Keep container tightly closed. Store locked | |up. Protect from sunlight. Store in a | |well-ventilated place. Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.