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SDS Sheet 0071440Printer Friendly View
Safety Data Sheet Date of Issue: |Revision Date: 05/22/2015 |Revision Number: 1.1 Imperial Supplies Part Number: 0071440 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: A07301 ZEP PRO ZWKS MOLY R22201 20N18 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company: Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Phone: 404-352-1680 1.4. Emergency Telephone Number Emergency |For SDS Information: Compliance Services 1-877-428-9937 number |For a Medical Emergency: 877-541-2016 Toll Free - All Calls |Recorded |For a Transportation Emergency: CHEMTREC: 800-424-9300 - All Calls |Recorded. In the District of Columbia 202-483-7616 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 2 aerosols | Gases under |Liquefied gas pressure | Skin |Category 2 irritation | Eye irritation|Category 2A Carcinogenicit|Category 1A y | Specific |Category 3 target organ |(Central toxicity - |nervous single |system) exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas |Health |Exclamat| | | |Cylinder|Hazard |ion Mark| | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H223 Flammable aerosol. |H280 Contains gas under pressure; may explode if |heated. |H315 Causes skin irritation. |H319 Causes serious eye irritation. |H336 May cause drowsiness or dizziness. |H350 May cause cancer. Precautionary Statements |Prevention: (GHS-US) |P201 Obtain special instructions before use. |P202 Do not handle until all safety precautions have |been read and understood. |P210 Keep away from heat, hot surfaces, sparks, open |flames and other ignition sources. No smoking. |P211 Do not spray on an open flame or other ignition |source. |P251 Pressurized container: Do not pierce or burn, |even after use. |P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ |spray. |P264 Wash skin thoroughly after handling. |P271 Use only outdoors or in a well-ventilated area. | |P280 Wear eye protection/ face protection. |P280 Wear protective gloves. |P281 Use personal protective equipment as required. | |Response: |P302 + P352 IF ON SKIN: Wash with plenty of soap and |water. |P304 + P340 + P312 IF INHALED: Remove victim to |fresh air and keep at rest in a position comfortable |for breathing. Call a POISON CENTER or doctor/ |physician if you feel unwell. |P305 + P351 + P338 IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P308 + P313 IF exposed or concerned: Get medical |advice/ attention. |P332 + P313 If skin irritation occurs: Get medical |advice/ attention. |P337 + P313 If eye irritation persists: Get medical |advice/ attention. |P362 Take off contaminated clothing and wash before |reuse. | |Storage: |P403 + P233 Store in a well-ventilated place. Keep |container tightly closed. |P405 Store locked up. |P410 + P412 Protect from sunlight. Do not expose to |temperatures exceeding 50 Â°C/ 122 Â°F. | |Disposal: |P501 Dispose of contents/container in accordance |with local regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Trichloroethylene |79-01-6 |>= 50 - | | |< 70 | Propane |74-98-6 |>= 10 - | | |< 20 | Propan-2-ol |67-63-0 |>= 10 - | | |< 20 | Butane |106-97-8 |>= 10 - | | |< 20 | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. First-aid Measures After Inhalation: Consult a physician after significant exposure. If unconscious place in recovery position and seek medical advice. First-aid Measures After Skin Contact: If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. Wash off immediately with plenty of water for at least 15 minutes. First-aid Measures After Eye Contact: Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes. First-aid Measures After Ingestion: Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. DO NOT induce vomiting unless directed to do so by a physician or poison control center. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable Extinguishing Media: High volume water jet 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Do not allow run-off from fire fighting to enter drains or water courses. Explosion Hazard: Carbon dioxide (CO2), Carbon monoxide, Smoke, Chlorine compounds. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up or vacuum up spillage and collect in suitable container for disposal. Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 Â°C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Keep in a cool, well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid: Oxidizing agents, Keep away from metals. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Trichloroethylene 79-01-6 TWA 10 ppm ACGIH STEL 25 ppm ACGIH TWA 100 ppm OSHA Z-2 CEIL 200 ppm OSHA Z-2 Peak 300 ppm OSHA Z-2 TWA 50 ppm 270 mg/m3 OSHA P0 STEL 200 ppm 1,080 mg/m3 OSHA P0 Propane 74-98-6 TWA 1,000 ppm ACGIH TWA 1,000 ppm 1,800 mg/m3 NIOSH REL TWA 1,000 ppm 1,800 mg/m3 OSHA Z-1 TWA 1,000 ppm 1,800 mg/m3 OSHA P0 propan-2-ol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm 980 mg/m3 NIOSH REL ST 500 ppm 1,225 mg/m3 NIOSH REL TWA 400 ppm 980 mg/m3 OSHA Z-1 TWA 400 ppm 980 mg/m3 OSHA P0 STEL 500 ppm 1,225 mg/m3 OSHA P0 Butane 106-97-8 TWA 800 ppm 1,900 mg/m3 NIOSH REL TWA 800 ppm 1,900 mg/m3 OSHA P0 Biological occupational exposure limits Component CAS-No. Control parameters Biological specimen Sampling time Permissible concentration Basis TRICHLOROETHENE 79-01-6 Trichloroacetic acid Urine End of shift at end of workweek 15 mg/l ACGIH BEI TRICHLOROETHENE Trichloroethanol In blood End of shift at end of workweek 0.5 mg/l ACGIH BEI TRICHLOROETHENE Trichloroethylene In blood End of shift at end of workweek ACGIH BEI TRICHLOROETHENE Trichloroethylene In end-exhaled air End of shift at end of workweek ACGIH BEI PROPAN-2-OL 67-63-0 Acetone Urine End of shift at end of workweek ACGIH BEI 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Remarks: The suitability for a specific workplace |should be discussed with the producers of the |protective gloves. Eye Protection |Eye wash bottle with pure water Tightly fitting |safety goggles Wear face-shield and protective suit |for abnormal processing problems. Skin and Body Protection |impervious clothing Choose body protection according |to the amount and concentration of the dangerous |substance at the work place. Respiratory Protection |In the case of vapour formation use a respirator |with an approved filter. |In the case of dust or aerosol formation use |respirator with an approved filter. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Aerosol containing a liquefied gas Odor |slight, solvent-like Odor Threshold |no data available pH |not applicable Relative Evaporation Rate |no data available (butylacetate=1) | Melting Point |not determined Freezing Point |not determined Boiling Point |82.2 - 87.7 Â°C Flash Point |not applicable Auto-ignition Temperature |not determined Decomposition Temperature |no data available Flammability (solid, gas) |Extremely flammable aerosol. Vapor Pressure |no data available Relative Vapor Density at 20 Â°C |no data available Relative Density | Specific Gravity | Solubility |Solubility(ies) Water solubility: insoluble |Solubility in other solvents: not determined Partition coefficient: |no data available n-octanol/water | Viscosity |no data available Lower Flammable Limit |no data available Upper Flammable Limit |no data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions No decomposition if stored and applied as directed. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials Oxidizing agents Metals Alkali metals 10.6 Hazardous Decomposition Products Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). Chlorine Phosgene Hydrogen chloride gas SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Product: Acute oral toxicity: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: trichloroethylene: Acute oral toxicity: LD50 Oral rat: 4,920 mg/kg Acute inhalation toxicity: LC50 mouse: 8450 ppm Exposure time: 4 h Acute dermal toxicity: LD50 Dermal rabbit: > 20,000 mg/kg propane: Acute inhalation toxicity: LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 658 mg/l Exposure time: 4 h LC50 rat: 1,355 mg/l propan-2-ol: Acute oral toxicity: LD50 Oral rat: 4,396 mg/kg Method: Calculation method butane: Acute inhalation toxicity: LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 1,355 mg/l Skin Corrosion/Irritation: Product: Remarks: May cause skin irritation in susceptible persons. Serious Eye Damage/Irritation: Product: Remarks: Irritating to eyes. Respiratory or Skin Sensitization: no data available Germ Cell Mutagenicity: no data available Carcinogenicity: no data available Reproductive Toxicity: no data available Specific Target Organ Toxicity (Single Exposure): no data available Specific Target Organ Toxicity (Repeated Exposure): no data available Aspiration Hazard: no data available Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting., Concentrations substantially above the TLV value may cause narcotic effects., Solvents may degrease the skin. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity no data available 12.2. Persistence and Degradability no data available 12.3. Bioaccumulative Potential Product: Partition coefficient: n-octanol/water: Remarks: no data available Components: trichloroethylene : Partition coefficient: n-octanol/water: log Pow: 2.29 butane : Partition coefficient: n-octanol/water: Pow: 2.89 12.4. Mobility in Soil no data available 12.5. Other Adverse Effects no data available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of in accordance with local regulations. The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Additional Information: Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, NON-FLAMMABLE Hazard Class |2.2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, NON-FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.2 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Trichloroethylene 79-01-6 100 160 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: The following components are subject to reporting levels established by SARA Title III, Section 313: Trichloroethylene 79-01-6 62.3498 % SARA Section 311/312 Hazard Classes |Sudden Release of Pressure Hazard |Acute Health Hazard |Chronic Health Hazard |Fire Hazard Toxic Substances Control Act (TSCA) |On the inventory, or in compliance with the |inventory 15.2 US State Regulations <COMPONENT> California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. Trichloroethylene 79-01-6 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |05/22/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Hazard statements |Flammable aerosol. -- | | ----| |Contains gas under pressure; may explode if -- | |heated. ----| |Causes skin irritation. -- | | ----| |Causes serious eye irritation. -- | | ----| |May cause drowsiness or dizziness. -- | | | |May cause cancer. |Precautionary statements |Obtain special instructions before use. | |Do not handle until all safety precautions | |have been read and understood. | |Keep away from heat, hot surfaces, sparks, | |open flames and other ignition sources. No | |smoking. | |Do not spray on an open flame or other | |ignition source. | |Pressurized container: Do not pierce or burn, | |even after use | |Avoid breathing dust/ fume/ gas/ mist/ | |vapours/ spray. | |Wash skin thoroughly after handling. | |Use only outdoors or in a well-ventilated | |area. | |Wear eye protection/ face protection. Wear | |protective gloves. | |Use personal protective equipment as | |required. | |IF ON SKIN: Wash with plenty of soap and | |water. | |IF INHALED: Remove victim to fresh air and | |keep at rest in a position comfortable for | |breathing. | |Call a POISON CENTER or doctor/ physician if | |you feel unwell. | |IF IN EYES: Rinse cautiously with water for | |several minutes. | |Remove contact lenses, if present and easy to | |do. Continue rinsing. | |IF exposed or concerned: Get medical advice/ | |attention. | |If skin irritation occurs: Get medical | |advice/ attention. | |If eye irritation persists: Get medical | |advice/ attention. | |Take off contaminated clothing and wash | |before reuse. | |Store in a well-ventilated place. Keep | |container tightly closed. | |Store locked up | |Protect from sunlight. | |Do not expose to temperatures exceeding 50 | |Â°C/ 122 Â°F. | |Dispose of contents/container in accordance | |with local regulation. Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.