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Zep Zep Inc. Profession 1310 Seaboard Industrial Blvd. al Atlanta, GA 30318 1-877-793-7776 Section 1. Chemical Product and Company Identification Product Name Z-WORKS HIGH PRESSURE LUBRICANT Product use Aerosol Penetrating Grease Product Code R071 Date of 07/18/08 Supersedes issue Emergency Telephone Number For MSDS Information: Compliance Services 1-877-793-7776 For Medical Emergency INFOTRAC: (877) 541-2016 Toll Free - All Calls Recorded For Transportation Emergency CHEMTREC: (800) 424-9300 - All Calls Recorded In the District of Columbia (202) 483-7616 Prepared By Compliance Services 1420 Seaboard Industrial Blvd. Atlanta, GA 30318 Section 2. Hazards Identification Emergency overview *Hazard Determination System (HDS): Health, Flammability, Reactivity DANGER 1 4 0 EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. Keep away from sources of ignition - No smoking. CAUSES EYE AND SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED. HARMFUL IF INHALED. CONTENTS UNDER PRESSURE NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by the following all prescribed safety precautions, including the use of proper personal protective equipment. Acute Effects Routes of Entry Dermal Contact. Inhalation Eyes Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching. Skin Direct contact may cause irritation and redness. Product may be dermal absorbed. Skin inflammation is characterized by itching, scaling, or reddening. Defatting properties, may aggravate an existing dermatitis. Inhalation Avoid breathing vapors, spray or mists. Over-exposure by inhalation may cause respiratory irritation. Can cause central nervous system (CNS) depression. High vapor concentrations can cause headaches, dizziness, drowsiness and nausea and may lead to unconsciousness. Ingestion Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. Vomiting increases risk of chemical pneumonia or pulmonary edema caused by aspiration of hydrocarbon solvents. Chronic effects Prolonged or repeated contact may dry skin and cause irritation. Overexposure of this product by inhalation or absorption can produce central nervous system depression resulting in headache, nausea and/or dizziness. Contains material which may cause damage to the following organs: kidneys, liver, heart, brain, central nervous system (CNS). Carcinogenicity Ingredients: Not listed as carcinogen by OSHA, NTP or IARC. Additional Information: See Toxicological Information (Section 11) Section 3. Composition/Information on Ingredients Name of Hazardous Ingredients CAS number % by Weight HEPTANE; n-heptane 142-82-5 5-15 PROPRIETARY SOLVENT BLEND Proprietary 50-60 CARBON DIOXIDE 124-38-9 5-15 Section 4. First Aid Measures Eye Contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately. Skin Contact Wash affected area with soap or mild detergent and water. Remove contaminated clothing and shoes. Get medical attention if irritation develops. Inhalation Move exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion ASPIRATION HAZARD. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention immediately. Section 5. Fire Fighting Measures National Fire Protection Association (U.S.A.) Flash Point Close cup:<-18Â°C (<0Â°F) (Tagliabue.) Flammable Not available. Limits Flammability Extremely flammable. (CSMA) Aerosol that may flash back. Fire hazard FLAMMABLE LIQUID AND VAPOR. Vapor may cause flash fire. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Bursting aerosol containers may be propelled from a fire at high speed. Fire-Fighting Use an extinguishing agent suitable for the surrounding fire. Procedures Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear. Cool closed containers exposed to fire with water. Section 6. Accidental Release Measures Spill Clean up Large spills are unlikely due to packaging Section 7. Handling and Storage Handling Store and use away from heat, sparks, open flame or any other ignition source. Put on appropriate personal protective equipment (see section 8). Avoid contact with eyes, skin and clothing. Do not breathe vapor or mist. Use only with adequate ventilation. Do not ingest. Wash thoroughly after handling. Wash contaminated clothing before reusing. Observe label precautions. Storage CONTENTS UNDER PRESSURE. Do not puncture or incinerate. Do not store above the following temperature: 49Â°C (120.2Â°F). Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Keep out of reach of children. Section 8. Exposure Controls/Personal Protection Product Name Exposure limits HEPTANE; n-heptane ACGIH/OSHA (United States). TWA: 400 ppm 8 hour(s). ACGIH/OSHA (United States). STEL: 400ppm 15 minute(s). BLEND OF ISOBUTANE & PROPANE ACGIH TLV (United Stated). TWA: 800 ppm 8 hour(s). OSHA PEL (United States). TWA: 1000 ppm 8 hour(s). HYDROTREATED LIGHT PETROLEUM Supplier Suggested (United States). DISTILLATES; paraffinic, naphthenic TWA: 100 ppm 8 hour(s). solvent Personal Protective Equipment (PPE) Eyes Safety glasses. Body Wear appropriate protective clothing to prevent skin contact. Recommended: Viton gloves. Nitrile gloves. Neoprene gloves. Respiratory Use with adequate ventilation. Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective occupational exposure limits. Wear appropriate respirator when ventilation is inadequate. Section 9. Physical and Chemical Properties Physical Liquid. [Aerosol.] Color Clear. Amber. State [Light] pH Not applicable Odor Solvent. Boiling Not determined. Vapor Pressure Not determined. Point Specific 0.75 Vapor Density >1 [Air = 1] Gravity Solubility Insoluble in the following Evaporation >1 (Butyl acetate. = materials: cold water and Rate 1) hot water VOC (Consumer) 374 (g/l). 3.12 lbs/gal (50.0%) Section 10. Stability and Reactivity Stability and The product is stable. Reactivity Incompatibility Avoid contact with strong oxidizers, excessive heat, sparks or open flame. Hazardous Will not occur. Polymerization Hazardous carbon oxides (CO,CO?) Decomposition Section 11. Toxicological Information Acute Toxicity Product/ingredient name Result Species Dose Exposure Heptane LD50 Oral Mouse 15000 mg/kg - LC50 Inhalation Mouse 18295 ppm 2 hours Gas. Hydrotreated Light Petroleum LD50 Dermal Rabbit >2000 mg/kg - Distillates LD50 Oral Rat >5000 mg/kg - Section 12. Ecological Information Environmental Effects No known significant effects or critical hazards. Aquatic Ecotoxicity Not available. Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities for additional information. Waste Stream Code: D001 Classification: - [Hazardous waste] Origin: - [RCRA waste.] Section 14. Transportation Information Regulatory UN number Proper shipping name Classes PG* Label Information DOT Classification None. Consumer commodity ORM-D - IMDG Class Not l determined. NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to the Bill of Lading with your shipment. PG*: Packing group Section 15. Regulatory Information U.S. Federal Regulations SARA 313 toxic chemical notification and release reporting: No product were found Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. All components of this product are listed or exempt from listing on TSCA Inventory. State Regulations California Prop 65 WARNING: This product contains a chemical or chemicals known to the state of California to cause cancer, birth defects or other reproductive harm. : Toluene Section 16. Other Information To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. *NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing significant hazards or risks Although these ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may shooed to provide them. HDS ratings are to be used with a fully implemented program to relay the meanings of this scale.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.