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SDS Sheet 0071390 Printer Friendly View
SECTION 1: IDENTIFICATION
1.1. Product Identifier
Product Form:
Product Name: A07286 ZEP PRO MP PENETRANT R22101 20N14
CAS No:
Synonyms:
1.2. Intended Use of the Product
Use of the substance/mixture:
1.3. Name, Address, and Telephone of the Responsible Party
Company
Zep Inc.
1310 Seaboard Industrial Blvd., NW
Atlanta, GA 30318
Phone: 404-352-1680
1.4. Emergency Telephone Number
Emergency | 1-877-428-9937, 877-541-2016, 800-424-9300, 202-483-7616
number |
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
Classification (GHS-US)
Flammable |Category 1
aerosols |
Gases under |Liquefied gas
pressure |
Skin |Category 2
irritation |
Eye irritation|Category 2A
Skin |Category 1
sensitisation |
2.2. Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Exclamation Mark
Signal Word (GHS-US) |Danger
Hazard Statements (GHS-US) |H222 Extremely flammable aerosol.
|H280 Contains gas under pressure; may explode if
|heated.
|H315 Causes skin irritation.
|H317 May cause an allergic skin reaction.
|H319 Causes serious eye irritation.
Precautionary Statements |Prevention:
(GHS-US) |P210 Keep away from heat, hot surfaces, sparks,
open
|flames and other ignition sources. No smoking.
|P211 Do not spray on an open flame or other
ignition
|source.
|P251 Pressurized container: Do not pierce or burn,
|even after use.
|P261 Avoid breathing dust/ fume/ gas/ mist/
vapours/
|spray.
|P264 Wash skin thoroughly after handling.
|P272 Contaminated work clothing should not be
|allowed out of the workplace.
|P280 Wear eye protection/ face protection.
|P280 Wear protective gloves.
|Response:
|P302 + P352 IF ON SKIN: Wash with plenty of soap
and
|water.
|P305 + P351 + P338 IF IN EYES: Rinse cautiously
with
|water for several minutes. Remove contact lenses,
if
|present and easy to do. Continue rinsing.
|P333 + P313 If skin irritation or rash occurs: Get
|medical advice/ attention.
|P337 + P313 If eye irritation persists: Get
medical
|advice/ attention.
|P362 Take off contaminated clothing and wash
before
|reuse.
|Storage:
|P410 + P412 Protect from sunlight. Do not expose
to
|temperatures exceeding 50 °C/ 122 °F.
|Disposal:
|P501 Dispose of contents/container in accordance
|with local regulation.
2.3. Other Hazards
Other Hazards Not Contributing to the Classification:
2.4. Unknown Acute Toxicity (GHS-US)
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
Name |Product identifier |% |Classification
| | |(GHS-US)
Mixture | | |
| | |
| | |
| | |
| | |
Full text of H-phrases: See Section 16
3.2. Mixture
Name |Product identifier |% |Classification
| | |(GHS-US)
Distillates (petroleum), |64742-47-8 |>= 20 - |
hydrotreated light | |< 30 |
Stoddard solvent |8052-41-3 |>= 20 - |
| |< 30 |
Distillates (petroleum), |64741-44-2 |>= 10 - |
straight-run middle | |< 20 |
Propane |74-98-6 |>= 5 - <|
| |10 |
Butane |106-97-8 |>= 1 - <|
| |5 |
1,2,4-trimethylbenzene |95-63-6 |>= 1 - <|
| |5 |
Hydrocarbons, terpene processing|68956-56-9 |>= 0.1 -|
by-products | |< 1 |
SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
First-aid Measures General: Move out of dangerous area. Show this safety data
sheet to the doctor in attendance. Do not leave the victim unattended.
First-aid Measures After Inhalation: If unconscious place in recovery position
and
seek medical advice. If symptoms persist, call a physician.
First-aid Measures After Skin Contact: If skin irritation persists, call a
physician. Wash off immediately with plenty of water for at least 15 minutes. If
on clothes, remove clothes.
First-aid Measures After Eye Contact: Remove contact lenses. Protect unharmed
eye.
Keep eye wide open while rinsing. If eye irritation persists, consult a
specialist. If in eyes, rinse with water for 15 minutes.
First-aid Measures After Ingestion: Keep respiratory tract clear. Never give
anything by mouth to an unconscious person. If symptoms persist, call a
physician.
DO NOT induce vomiting unless directed to do so by a physician or poison control
center.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:
Symptoms/Injuries After Inhalation:
Symptoms/Injuries After Skin Contact:
Symptoms/Injuries After Eye Contact:
Symptoms/Injuries After Ingestion:
Chronic Symptoms:
4.3. Indication of Any Immediate Medical Attention and Special Treatment
Needed
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media: Alcohol-resistant foam, Carbon dioxide (CO2), Dry
chemical, Water spray jet
Unsuitable Extinguishing Media: High volume water jet
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard:
Explosion Hazard: Carbon dioxide (CO2) Carbon monoxide Smoke
Reactivity:
5.3. Advice for Firefighters
Precautionary Measures Fire: Do not allow run-off from fire fighting to enter
drains or water courses.
Firefighting Instructions: Use extinguishing measures that are appropriate to
local circumstances and the surrounding environment.
Further information: Collect contaminated fire extinguishing water separately.
This must not be discharged into drains. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local regulations.
For
safety reasons in case of fire, cans should be stored separately in closed
containments. Use a water spray to cool fully closed containers.
Protection During Firefighting: Wear self-contained breathing apparatus for
firefighting if necessary.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Use personal protective equipment. Ensure adequate
ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of
vapours accumulating to form explosive concentrations. Vapours can accumulate in
low areas.
6.1.1. For Non-emergency Personnel
Protective Equipment:
Emergency Procedures:
6.1.2. For Emergency Responders
Protective Equipment:
Emergency Procedures:
6.2. Environmental Precautions
Prevent product from entering drains. Prevent further leakage or spillage if
safe
to do so. If the product contaminates rivers and lakes or drains inform
respective
authorities.
6.3. Methods and Material for Containment and Cleaning Up
For Containment:
Methods for Cleaning Up: Soak up with inert absorbent material (e.g. sand,
silica
gel, acid binder, universal binder, sawdust). Sweep up or vacuum up spillage and
collect in suitable container for disposal.
6.4. Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Additional Hazards When Processed: Avoid exposure - obtain special instructions
before use. Avoid contact with skin and eyes. For personal protection see
section
8. Smoking, eating and drinking should be prohibited in the application area.
Take
precautionary measures against static discharges. Provide sufficient air
exchange
and/or exhaust in work rooms. Open drum carefully as content may be under
pressure. Dispose of rinse water in accordance with local and national
regulations. Persons susceptible to skin sensitisation problems or asthma,
allergies, chronic or recurrent respiratory disease should not be employed in
any
process in which this mixture is being used. Always replace cap after use. Do
not
breathe vapours or spray mist.
Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash
hands before breaks and at the end of workday.
7.2. Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:
Storage Conditions: BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force or throw into fire
even
after use. Do not spray on flames or red-hot objects. No smoking. Containers
which
are opened must be carefully resealed and kept upright to prevent leakage.
Observe
label precautions. Keep in a dry, cool and well-ventilated place. Electrical
installations / working materials must comply with the technological safety
standards.
Materials to avoid: Oxidizing agents
7.3. Specific End Use(s)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
Components
CAS-No.
Value type (Form of exposure)
Control parameters / Permissible concentration
Basis
Distillates (petroleum), hydrotreated light
64742-47-8
TWA
500 ppm
2,000 mg/m3
OSHA Z-1
TWA
400 ppm
1,600 mg/m3
OSHA P0
Stoddard solvent
8052-41-3
TWA
100 ppm
ACGIH
TWA
350 mg/m3
NIOSH REL
C
1,800 mg/m3
NIOSH REL
TWA
500 ppm
2,900 mg/m3
OSHA Z-1
TWA
100 ppm
525 mg/m3
OSHA P0
propane
74-98-6
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm
1,800 mg/m3
NIOSH REL
TWA
1,000 ppm
1,800 mg/m3
OSHA Z-1
TWA
1,000 ppm
1,800 mg/m3
OSHA P0
butane
106-97-8
TWA
800 ppm
1,900 mg/m3
NIOSH REL
TWA
800 ppm
1,900 mg/m3
OSHA P0
1,2,4-trimethylbenzene
95-63-6
TWA
25 ppm
125 mg/m3
NIOSH REL
8.2. Exposure Controls
Appropriate Engineering |
Controls |
Personal Protective Equipment|
Materials for Protective |
Clothing |
Hand Protection |Remarks: The suitability for a specific workplace
|should be discussed with the producers of the
|protective gloves.
Eye Protection |Tightly fitting safety goggles. Wear face-shield
and
|protective suit for abnormal processing problems.
|Ensure that eyewash stations and safety showers
are
|close to the workstation location.
Skin and Body Protection |Impervious clothing. Choose body protection
|according to the amount and concentration of the
|dangerous substance at the work place.
Respiratory Protection |Use respiratory protection unless adequate local
|exhaust ventilation is provided or exposure
|assessment demonstrates that exposures are within
|recommended exposure guidelines.
Thermal Hazard Protection |
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State |
Appearance |Aerosol containing a liquefied gas
Odor |Solvent-like
Odor Threshold |No data available
pH |No data available
Relative Evaporation Rate |Not determined
(butylacetate=1) |
Melting Point |No data available
Freezing Point |No data available
Boiling Point |151.67 °C
Flash Point |41.6 °C Method: closed cup
Auto-ignition Temperature |Not determined
Decomposition Temperature |No data available
Flammability (solid, gas) |Extremely flammable aerosol.
Vapor Pressure |Not determined
Relative Vapor Density at 20 °C |
Relative Density |
Specific Gravity |
Solubility |Insoluble
Partition coefficient: |No data available
n-octanol/water |
Viscosity |No data available
Lower Flammable Limit |No data available
Upper Flammable Limit |No data available
9.2. Other Information
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity
No data available
10.2 Chemical Stability
Stable under normal conditions.
10.3 Possibility of Hazardous Reactions
No decomposition if stored and applied as directed. Vapours may form explosive
mixture with air.
10.4 Conditions to Avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
10.5 Incompatible Materials
Oxidizing agents
10.6 Hazardous Decomposition Products
Carbon oxides
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects
Acute Toxicity:
Acute inhalation toxicity: Acute toxicity estimate : > 10 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method
Skin Corrosion/Irritation: Remarks: Irritating to skin.
Serious Eye Damage/Irritation: Remarks: Severe eye irritation.
Respiratory or Skin Sensitization: Remarks: Causes sensitisation.
Germ Cell Mutagenicity: No data available
Carcinogenicity: No data available.
Reproductive Toxicity: No data available.
Specific Target Organ Toxicity (Single Exposure): No data available.
Specific Target Organ Toxicity (Repeated Exposure): No data available.
Aspiration Hazard: No data available
Symptoms/Injuries After Inhalation:
Symptoms/Injuries After Skin Contact:
Symptoms/Injuries After Eye Contact:
Symptoms/Injuries After Ingestion:
Chronic Symptoms:
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
No data available
12.2. Persistence and Degradability
No data available
12.3. Bioaccumulative Potential
Product:
Partition coefficient: n-octanol/water: Remarks: no data available
Components:
Butane :
Partition coefficient: n-octanol/water: Pow: 2.89
12.4. Mobility in Soil
No data available
12.5. Other Adverse Effects
No data available.
Product:
Regulation: 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric
Ozone - CAA Section 602 Class I Substances
Remarks: This product neither contains, nor was manufactured with a Class I or
Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt.
A, App.A + B).
Additional ecological Information: An environmental hazard cannot be excluded in
the event of unprofessional handling or disposal., Toxic to aquatic life with
long
lasting effects.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Waste from residues: The product should not be
allowed to enter drains, water courses or the soil. Do not contaminate ponds,
waterways or ditches with chemical or used container. Dispose of in accordance
with local regulations.
Additional Information: Contaminated packaging: Empty remaining contents.
Dispose
of as unused product. Do not re-use empty containers. Do not burn, or use a
cutting torch on, the empty drum.
SECTION 14: TRANSPORT INFORMATION
14.1 In Accordance with DOT
Proper Shipping Name |
Hazard Class | |<PICTOGRAM PHRASE>
Identification Number| |
Label Codes | |
ERG Number |
14.2 In Accordance with IMDG
Proper Shipping Name |Vessel: AEROSOLS
Hazard Class |2.1
Identification Number|UN1950
Label Codes | |<PICTOGRAM PHRASE>
ntification Of The | |
Substance/m | |
EmS-No. (Fire) | |
EmS-No. (Spillage) | |
14.3 In Accordance with IATA
Proper Shipping Name |Cargo Air: Aerosols
|Passenger Air: Aerosols
Identification Number|UN1950 |<PICTOGRAM PHRASE>
Hazard Class |2.1 |
Label Codes | |
ntification Of The | |
Substance/m | |
ERG Code (IATA) |
SECTION 15: REGULATORY INFORMATION
15.1 US Federal Regulations
<COMPONENT>
CERCLA Reportable Quantity:
Components
CAS-No.
Component RQ (lbs)
Calculated product RQ (lbs)
Xylenes
1330-20-7
100
*
SARA 304 Extremely Hazardous Substances Reportable Quantity: This material does
not contain any components with a section 304 EHS RQ.
SARA 302: No chemicals in this material are subject to the reporting
requirements
of SARA Title III, Section 302.
SARA 313: The following components are subject to reporting levels established
by
SARA Title III, Section 313:
1,2,4-trimethylbenzene 95-63-6
1.3569 %
SARA Section 311/312 Hazard Classes |Fire Hazard
|Sudden Release of Pressure Hazard
|Acute Health Hazard
Toxic Substances Control Act (TSCA) |On TSCA Inventory
15.2 US State Regulations
<COMPONENT>
California Prop 65
This product does not contain any chemicals known to State of California to
cause
cancer, birth defects, or any other reproductive harm.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision date |05/06/2015
Other |This document has been prepared in accordance with the SDS
Information |requirements of the OSHA Hazard Communication Standard 29 CFR
|1910.1200.
GHS Full Text Phrases:
----|Hazard statements |Extremely flammable aerosol. Contains gas
-- | |under pressure; may explode if heated.
Causes
| |skin irritation. May cause an allergic skin
| |reaction. Causes serious eye irritation.
----|Precautionary statements |Prevention: Keep away from heat, hot
-- | |surfaces, sparks, open flames and other
| |ignition sources. No smoking. Do not spray
on
| |an open flame or other ignition source.
| |Pressurized container: Do not pierce or
burn,
| |even after use. Avoid breathing dust/ fume/
| |gas/ mist/ vapours/ spray. Wash skin
| |thoroughly after handling. Contaminated
work
| |clothing should not be allowed out of the
| |workplace. Wear eye protection/ face
| |protection. Wear protective gloves.
----| |Response: IF ON SKIN: Wash with plenty of
-- | |soap and water. IF IN EYES: Rinse
cautiously
| |with water for several minutes. Remove
| |contact lenses, if present and easy to do.
| |Continue rinsing. If skin irritation or
rash
| |occurs: Get medical advice/ attention. If
eye
| |irritation persists: Get medical advice/
| |attention. Take off contaminated clothing
and
| |wash before reuse.
----| |Storage: Protect from sunlight. Do not
expose
-- | |to temperatures exceeding 50 °C/ 122 °F.
----| |Disposal: Dispose of contents/container in
-- | |accordance with local regulation.
Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance. |