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Sheet 0071390 Printer Friendly ViewSECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: A07286 ZEP PRO MP PENETRANT R22101 20N14 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Phone: 404-352-1680 1.4. Emergency Telephone Number Emergency | 1-877-428-9937, 877-541-2016, 800-424-9300, 202-483-7616 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Gases under |Liquefied gas pressure | Skin |Category 2 irritation | Eye irritation|Category 2A Skin |Category 1 sensitisation | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H222 Extremely flammable aerosol. |H280 Contains gas under pressure; may explode if |heated. |H315 Causes skin irritation. |H317 May cause an allergic skin reaction. |H319 Causes serious eye irritation. Precautionary Statements |Prevention: (GHS-US) |P210 Keep away from heat, hot surfaces, sparks, open |flames and other ignition sources. No smoking. |P211 Do not spray on an open flame or other ignition |source. |P251 Pressurized container: Do not pierce or burn, |even after use. |P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ |spray. |P264 Wash skin thoroughly after handling. |P272 Contaminated work clothing should not be |allowed out of the workplace. |P280 Wear eye protection/ face protection. |P280 Wear protective gloves. |Response: |P302 + P352 IF ON SKIN: Wash with plenty of soap and |water. |P305 + P351 + P338 IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P333 + P313 If skin irritation or rash occurs: Get |medical advice/ attention. |P337 + P313 If eye irritation persists: Get medical |advice/ attention. |P362 Take off contaminated clothing and wash before |reuse. |Storage: |P410 + P412 Protect from sunlight. Do not expose to |temperatures exceeding 50 �C/ 122 �F. |Disposal: |P501 Dispose of contents/container in accordance |with local regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Mixture | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Distillates (petroleum), |64742-47-8 |>= 20 - | hydrotreated light | |< 30 | Stoddard solvent |8052-41-3 |>= 20 - | | |< 30 | Distillates (petroleum), |64741-44-2 |>= 10 - | straight-run middle | |< 20 | Propane |74-98-6 |>= 5 - <| | |10 | Butane |106-97-8 |>= 1 - <| | |5 | 1,2,4-trimethylbenzene |95-63-6 |>= 1 - <| | |5 | Hydrocarbons, terpene processing|68956-56-9 |>= 0.1 -| by-products | |< 1 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. First-aid Measures After Inhalation: If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. First-aid Measures After Skin Contact: If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. First-aid Measures After Eye Contact: Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes. First-aid Measures After Ingestion: Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol-resistant foam, Carbon dioxide (CO2), Dry chemical, Water spray jet Unsuitable Extinguishing Media: High volume water jet 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Carbon dioxide (CO2) Carbon monoxide Smoke Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Do not allow run-off from fire fighting to enter drains or water courses. Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up or vacuum up spillage and collect in suitable container for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Always replace cap after use. Do not breathe vapours or spray mist. Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 �C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Keep in a dry, cool and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid: Oxidizing agents 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Distillates (petroleum), hydrotreated light 64742-47-8 TWA 500 ppm 2,000 mg/m3 OSHA Z-1 TWA 400 ppm 1,600 mg/m3 OSHA P0 Stoddard solvent 8052-41-3 TWA 100 ppm ACGIH TWA 350 mg/m3 NIOSH REL C 1,800 mg/m3 NIOSH REL TWA 500 ppm 2,900 mg/m3 OSHA Z-1 TWA 100 ppm 525 mg/m3 OSHA P0 propane 74-98-6 TWA 1,000 ppm ACGIH TWA 1,000 ppm 1,800 mg/m3 NIOSH REL TWA 1,000 ppm 1,800 mg/m3 OSHA Z-1 TWA 1,000 ppm 1,800 mg/m3 OSHA P0 butane 106-97-8 TWA 800 ppm 1,900 mg/m3 NIOSH REL TWA 800 ppm 1,900 mg/m3 OSHA P0 1,2,4-trimethylbenzene 95-63-6 TWA 25 ppm 125 mg/m3 NIOSH REL 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Remarks: The suitability for a specific workplace |should be discussed with the producers of the |protective gloves. Eye Protection |Tightly fitting safety goggles. Wear face-shield and |protective suit for abnormal processing problems. |Ensure that eyewash stations and safety showers are |close to the workstation location. Skin and Body Protection |Impervious clothing. Choose body protection |according to the amount and concentration of the |dangerous substance at the work place. Respiratory Protection |Use respiratory protection unless adequate local |exhaust ventilation is provided or exposure |assessment demonstrates that exposures are within |recommended exposure guidelines. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Aerosol containing a liquefied gas Odor |Solvent-like Odor Threshold |No data available pH |No data available Relative Evaporation Rate |Not determined (butylacetate=1) | Melting Point |No data available Freezing Point |No data available Boiling Point |151.67 �C Flash Point |41.6 �C Method: closed cup Auto-ignition Temperature |Not determined Decomposition Temperature |No data available Flammability (solid, gas) |Extremely flammable aerosol. Vapor Pressure |Not determined Relative Vapor Density at 20 �C | Relative Density | Specific Gravity | Solubility |Insoluble Partition coefficient: |No data available n-octanol/water | Viscosity |No data available Lower Flammable Limit |No data available Upper Flammable Limit |No data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions No decomposition if stored and applied as directed. Vapours may form explosive mixture with air. 10.4 Conditions to Avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Oxidizing agents 10.6 Hazardous Decomposition Products Carbon oxides SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Acute inhalation toxicity: Acute toxicity estimate : > 10 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Skin Corrosion/Irritation: Remarks: Irritating to skin. Serious Eye Damage/Irritation: Remarks: Severe eye irritation. Respiratory or Skin Sensitization: Remarks: Causes sensitisation. Germ Cell Mutagenicity: No data available Carcinogenicity: No data available. Reproductive Toxicity: No data available. Specific Target Organ Toxicity (Single Exposure): No data available. Specific Target Organ Toxicity (Repeated Exposure): No data available. Aspiration Hazard: No data available Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity No data available 12.2. Persistence and Degradability No data available 12.3. Bioaccumulative Potential Product: Partition coefficient: n-octanol/water: Remarks: no data available Components: Butane : Partition coefficient: n-octanol/water: Pow: 2.89 12.4. Mobility in Soil No data available 12.5. Other Adverse Effects No data available. Product: Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological Information: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Toxic to aquatic life with long lasting effects. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste from residues: The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations. Additional Information: Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Vessel: AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Cargo Air: Aerosols |Passenger Air: Aerosols Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> CERCLA Reportable Quantity: Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Xylenes 1330-20-7 100 * SARA 304 Extremely Hazardous Substances Reportable Quantity: This material does not contain any components with a section 304 EHS RQ. SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: The following components are subject to reporting levels established by SARA Title III, Section 313: 1,2,4-trimethylbenzene 95-63-6 1.3569 % SARA Section 311/312 Hazard Classes |Fire Hazard |Sudden Release of Pressure Hazard |Acute Health Hazard Toxic Substances Control Act (TSCA) |On TSCA Inventory 15.2 US State Regulations <COMPONENT> California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |05/06/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Hazard statements |Extremely flammable aerosol. Contains gas -- | |under pressure; may explode if heated. Causes | |skin irritation. May cause an allergic skin | |reaction. Causes serious eye irritation. ----|Precautionary statements |Prevention: Keep away from heat, hot -- | |surfaces, sparks, open flames and other | |ignition sources. No smoking. Do not spray on | |an open flame or other ignition source. | |Pressurized container: Do not pierce or burn, | |even after use. Avoid breathing dust/ fume/ | |gas/ mist/ vapours/ spray. Wash skin | |thoroughly after handling. Contaminated work | |clothing should not be allowed out of the | |workplace. Wear eye protection/ face | |protection. Wear protective gloves. ----| |Response: IF ON SKIN: Wash with plenty of -- | |soap and water. IF IN EYES: Rinse cautiously | |with water for several minutes. Remove | |contact lenses, if present and easy to do. | |Continue rinsing. If skin irritation or rash | |occurs: Get medical advice/ attention. If eye | |irritation persists: Get medical advice/ | |attention. Take off contaminated clothing and | |wash before reuse. ----| |Storage: Protect from sunlight. Do not expose -- | |to temperatures exceeding 50 �C/ 122 �F. ----| |Disposal: Dispose of contents/container in -- | |accordance with local regulation. Grainger disclaimer. The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance. |