Sheet 0071370Printer Friendly View
Safety Data Sheet Date of Issue: 01/25/13 |Revision Date: |Revision Number: Imperial Supplies Part Number: 0071370 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Z-WORKS RAPID PENETRANT CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Aerosol Penetrant 1.3. Name, Address, and Telephone of the Responsible Party Company Zep Inc. 1310 Seaboard Industrial Blvd. Atlanta, GA 30318 Phone: 1-877-793-7776 1.4. Emergency Telephone Number Emergency |For MSDS Information: Compliance Services 1-877-793-7776, For number |Medical Emergency: (877) 541-2016 Toll Free - All Calls Recorded, |For Transportation Emergency: CHEMTREC: (800) 424-9300 - All Calls |Recorded In the District of Columbia (202) 483-7616 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) | Hazard Statements (GHS-US) | Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Distillates (petroleum), |64742-47-8 |75 - 85 | hydrotreated light | | | Fuel oil, No 2 |68476-30-2 |1 - 10 | Carbon dioxide |124-38-9 |1 - 10 | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. First-aid Measures After Skin Contact: Flush affected skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation develops. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately. First-aid Measures After Ingestion: Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. If affected person is conscious, give plenty of water to drink. Never give anything by mouth to an unconscious person. Get medical attention immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Avoid breathing vapors, spray or mists. Over-exposure by inhalation may cause respiratory irritation. Can cause central nervous system (CNS) depression. Symptoms/Injuries After Skin Contact: May cause skin irritation. May be harmul if absorbed through the skin. Skin inflammation is characterized by itching, scaling, or reddening. Symptoms/Injuries After Eye Contact: Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching. Symptoms/Injuries After Ingestion: Harmful or fatal if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. Call physician immediately. Chronic Symptoms: Contains material which may cause damage to the following organs: lungs, skin, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage. Prolonged or repeated contact may dry skin and cause irritation. Repeated inhalation of dust can produce varying degrees of respiratory irritation or lung damage. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Flammable aerosol. Combustible material. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use an extinguishing agent suitable for the surrounding fire. Cool closed containers exposed to fire with water. Fire-fighters should wear appropriate protective equipment. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Spills are unlikely due to packaging. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Put on appropriate personal protective equipment (see section 8). Store and use away from heat, sparks, open flame or any other ignition source. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Observe label precautions. Wash contaminated clothing before reusing. Wash thoroughly after handling. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: CONTENTS UNDER PRESSURE. Eliminate all ignition sources. Do not puncture, incinerate or store the container at temperatures above 49�C (120�F) or in direct sunlight. Keep out of the reach of children. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Product name Exposure limits Fuel oil, No 2 ACGIH TLV (United States, 2/2010). Absorbed through skin. TWA: 100 mg/m�, (measured as total hydrocarbons) 8 hour(s). Form: Total hydrocarbons Carbon dioxide ACGIH TLV (United States, 2/2010). TWA: 5000 ppm 8 hour(s). TWA: 9000 mg/m� 8 hour(s). STEL: 30000 ppm 15 minute(s). STEL: 54000 mg/m� 15 minute(s). OSHA PEL 1989 (United States, 3/1989). TWA: 10000 ppm 8 hour(s). TWA: 18000 mg/m� 8 hour(s). STEL: 30000 ppm 15 minute(s). STEL: 54000 mg/m� 15 minute(s). NIOSH REL (United States, 6/2009). TWA: 5000 ppm 10 hour(s). TWA: 9000 mg/m� 10 hour(s). STEL: 30000 ppm 15 minute(s). STEL: 54000 mg/m� 15 minute(s). OSHA PEL (United States, 6/2010). TWA: 5000 ppm 8 hour(s). TWA: 9000 mg/m� 8 hour(s). 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses. Skin and Body Protection |Recommended: Neoprene gloves. Nitrile gloves. Rubber |gloves. Respiratory Protection |Use with adequate ventilation. Provide exhaust |ventilation or other engineering controls to keep |the airborne concentrations of vapors below their |respective occupational exposure limits. Wear |appropriate respirator when ventilation is |inadequate. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. [Aerosol.] Appearance | Odor |Solvent-like. Odor Threshold | pH |Not applicable. Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point | Freezing Point | Boiling Point |Not available. Flash Point |Closed cup: <60�C (<140�F) [Liquid Contents] Auto-ignition Temperature | Decomposition Temperature | Flammability (solid, gas) | Vapor Pressure |Not available. Relative Vapor Density at 20 �C |>1 [Air = 1] Relative Density | Specific Gravity |0.8625 Solubility |Insoluble in the following materials: cold |water and hot water. Partition coefficient: | n-octanol/water | Viscosity | Lower Flammable Limit |Not available. Upper Flammable Limit |Not available. 9.2. Other Information VOC (Consumer): 0.77 % (w/w) 0.0555 lbs/gal (6.6 g/l) SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable. 10.2 Chemical Stability 10.3 Possibility of Hazardous Reactions Hazardous Polymerization: Under normal conditions of storage and use, hazardous polymerization will not occur. 10.4 Conditions to Avoid 10.5 Incompatible Materials Avoid contact with strong oxidizers, excessive heat, sparks or open flame. 10.6 Hazardous Decomposition Products carbon oxides (CO, CO2). SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Product/ingredient name Result Species Dose Exposure Fuel oil, No 2 LD50 Oral Rat 12 g/kg - Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Aquatic Ecotoxicity: Distillates (petroleum), hydrotreated light - Acute LC50 2200 ug/L Fish - Bluegill - 4 days Fresh water Lepomis macrochirus - 35 to 75 mm 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Environmental Effects: Not available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities for additional information. Waste Stream: Code: D001 Classification: Hazardous waste Origin: RCRA waste. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Consumer commodity Hazard Class |ORM-D |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, flammable Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | |[pic] Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313 toxic chemical notification and release reporting: No products were found. Clean Water Act (CWA) 307: naphthalene Clean Water Act (CWA) 311: naphthalene Clean Air Act (CAA) 112 regulated toxic substances: No products were found. SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |All Components of this product are listed or |exempt from listing on TSCA Inventory. 15.2 US State Regulations <COMPONENT> California Prop 65: WARNING: This product contains a chemical or chemicals known to the State of California to cause cancer.: naphthalene. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.