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MATERIAL SAFETY DATA SHEET Zep Professionals Zep Inc. Section 1. Chemical Product and 1310 Seaboard Company Identification Industrial Blvd. Atlanta, GA 30318 1-877-793-7776 Product name HEAVY -DUTY CITRUS DEGREASER AEROSOL Product use Cleaner. Degreaser Product code R196 Date of issue 08/20/09 Supersedes Emergency Telephone Numbers For MSDS Information: Compliance Services 1-877-793-7776 For Medical Emergency (877) 541-2016 Toll Free - All Calls Recorded For Transportation Emergency CHEMTREC: (800) 424-9300 - All Calls Recorded In the District of Columbia (202) 483-7616 Prepared By Compliance Services 1420 Seaboard Industrial Blvd. Atlanta, GA 30318 Section 2. Hazards Identification Emergency overview *Hazard Determination System (HDS): Health, Flammability, Reactivity DANGER! 1 4 0 EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. Do not smoke. Eliminate all ignition sources. VAPOR HARMFUL. CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. CONTENTS UNDER PRESSURE. NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all prescribed safety precautions, including the use of proper personal protective equipment. Acute Effects Routes of Entry Dermal contact. Eye contact. Inhalation. Eyes Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching. Skin May cause skin irritation. May cause skin sensitization. Defatting properties, may aggravate an existing dermatitis Skin inflammation is characterized by itching, scaling, or reddening. Inhalation Over-exposure by inhalation may cause respiratory irritation. Ingestion Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. Chronic effects Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Carcinogenicity No known significant effects or critical hazards. Product/ingredient name Not available. Additional Information: See Toxicological Information (Section 11) Section 3. Composition/Information on Ingredients CAS number D-LIMONENE; orange distillate; citrus terpene, 5989-27-5 70-80 cyclohexene, 1-methy 1-4-(1-methylethenyl)-, (R)- BLEND OF ISOBUTANE & PROPANE 74-98-6; 10-20 75-28-5 NONYLPHENOXY POLY(ETHYLENEOXY) ETHANOL - npe; 9016-45-9 1-10 poly(oxy-1,2-ethanediyl) alpha-(nonylphenyl)-omega-hydroxy Section 4. First Aid Measures Eye Contact Immediately flush eye with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately. Skin Contact Flush affected skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Wash clothing before reuse. Get medical attention if irritation develops. Inhalation Move exposed person to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention immediately. Ingestion Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention immediately. Section 5. Fire Fighting Measures National Fire Protection Association (U.S.A.) Flash Point Not available. Flammable Limits Not available. Flammability Extremely flammable. (CSMA) Aerosol that may flash back. Fire hazard EXTREMELY FLAMMABLE LIQUID AND VAPOR. CONTENTS UNDER PRESSURE. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Bursting aerosol containers may be propelled from a fire at high speed. Rags, steel wool or other wastes soaked with product may spontaneously catch fire if improperly discarded. Fire-Fighting Use an extinguishing agent suitable for the surrounding Procedures fire. Section 6. Accidental Release Measures Spill Clean up Large spills are unlikely due to packaging. Section 7. Handling and Storage Handling Put on appropriate personal protective equipment (see section 8). Store and use away from heat, sparks, open flame or any other ignition source. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Watch for accumulation in low confined areas. Wash thoroughly after handling. Empty containers retain product residue and can be hazardous. Observe label precautions. Storage CONTENTS UNDER PRESSURE. Do not store above the following temperature: 49�C (120.2�F). Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Do not puncture or incinerate container. Keep out of the reach of children. Section 8. Exposure Controls/Personal Protection Product name Exposure limits BLEND OF ISOBUTANE & PROPANE ACGIH TLV (United States). TWA: 800 ppm 8 hour(s). OSHA PEL (United States). TWA: 1000 ppm 8 hour(s). Personal Protective Equipment (PPE) Eyes Safety glasses. Body Wear appropriate protective clothing to prevent skin contact. Recommended: Nitrile gloves. Neoprene gloves. Respiratory Use with adequate ventilation. Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective occupational exposure limits. Wear appropriate respirator when ventilation is inadequate. Section 9: Physical and Chemical Properties Physical State Liquid. [Aerosol.] Color Clear. Colorless pH Not applicable Odor Citrus Boiling Point Not determined. Vapor Pressure Not determined. Specific 0.859 Vapor Density >1[Air = 1] Gravity Solubility Emulsifies in water. Evaporation Rate Not determined. VOC (Consumer) 813.79 (g/l). 6.79 lbs/gal (94.90%) Section 10. Stability and Reactivity Stability and The product is stable. Reactivity Incompatibility Keep away from heat, sparks, and flame. Reactive or incompatible with the following materials: oxidizing materials and acids. Hazardous Will not occur. Polymerization Hazardous carbon oxides (CO, CO2) Decomposition Products Section 11. Toxicological Information Acute Toxicity Product/Ingredient name Result Species Dose Exposure d-Limonene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - Nonylphenoxypoly LD50 Dermal Rabbit 2000 mg/kg - (Ethyleneoxy) Ethano LD50 Oral Rat 3310 mg/kg - Section 12. Ecological Information Aquatic Exotoxicity Not available. Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities for additional information. Waste Stream Code: D001 Classification: - [Hazardous waste.] Origin: - [RCRA waste.] Section 14. Transport Information Regulatory UN number Proper Classes PG* Label Information shipping name DOT Not Consumer ORM-D - Classificati regulated. commodity on IMDG Class NOTE: DOT classification applies to most package sizes. For specific container size classification or for size exceptions, refer to the Bill of Lading with your shipment. PG*: Packing group Section 15. Regulatory Information U.S. Federal Regulations SARA 313 toxic chemical notification and release reporting: No products were found. Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. All Components of this product are listed or exempt from listing on the TSCA Inventory. State Regulations California Prop 65 No products were found. Section 16. Other Information To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. *NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing significant hazards or risks Although these ratings are not required on MSDSs under 29 CRF 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to relay the meaning of this scale.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.