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SECTION 1: IDENTIFICATION | |1.1. Product Identifier Product Form: Product Name: ROHPER LSPR 6PK LEAK SEAL 13.75OZ CLEAR CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Leak Seal/Aerosols 1.3. Name, Address, and Telephone of the Responsible Party Company Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Phone 1.4. Emergency Telephone Number Emergency | 24 Hour Hotline: 847-367-7700 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |category 1 Aerosol | Flammable |Category 1 Liquid | Flammable |Category 1 Aerosol | Acute |Category 5 Toxicity, Oral| Aspiration |Category 2 Hazard | Acute |Category 5 Toxicity, | Dermal | Skin |Category 2 Irritation | Eye Irritation|Category 2 Eye Irritation|Category 2B Acute |Category 4 Toxicity, | Inhalation | STOT, single |Category 3, exposure |RTI STOT, single |Category 3, NE exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Flame Hazard Statements (GHS-US) |H222 Extremely flammable aerosol. |H224 Extremely flammable liquid and vapour. |H280 Contains gas under pressure; may explode if |heated |H303 May be harmful if swallowed. |H305 May be harmful if swallowed and enters airways. | |H313 May be harmful in contact with skin. |H315 Causes skin irritation. |H319 Causes serious eye irritation. |H320 Causes eye irritation. |H332 Harmful if inhaled. |H335 May cause respiratory irritation. |H336 May cause drowsiness or dizziness. Precautionary Statements |P102 Keep out of reach of children. (GHS-US) |P103 Read label before use. |P202 Do not handle until all safety precautions have |been read and understood. |P210 Keep away from heat/sparks/open flames/hot |surfaces. - No smoking. |P211 Do not spray on an open flame or other ignition |source. |P220 Keep/Store away from clothing/.../combustible |materials. |P234 Keep only in original container. |P235 Keep cool. |P240 Ground/bond container and receiving equipment. |P241 Use explosion-proof |electrical/ventilating/lighting/.../ equipment. |P242 Use only non-sparking tools. |P243 Take precautionary measures against static |discharge. |P251 Pressurized container: Do not pierce or burn, |even after use. |P260 Do not breathe |dust/fume/gas/mist/vapours/spray. |P261 Avoid breathing |dust/fume/gas/mist/vapours/spray. |P262 Do not get in eyes, on skin, or on clothing. |P264 Wash ... thoroughly after handling. |P270 Do not eat, drink or smoke when using this |product. |P271 Use only outdoors or in a well-ventilated area. | |P273 Avoid release to the environment. |P280 Wear protective gloves/protective clothing/eye |protection/face protection. |P281 Use personal protective equipment as required. |P285 In case of inadequate ventilation wear |respiratory protection. |P302+P350 IF ON SKIN: Gently wash with plenty of |soap and water. |P303+P361+P353 IF ON SKIN (or hair): Remove/Take off |immediately all contaminated clothing. Rinse skin |with water/shower. |P304+P340 IF INHALED: Remove victim to fresh air and |keep at rest in a position comfortable for |breathing. |P305+P351+P338 IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P312 Call a POISON CENTER or doctor/physician if you |feel unwell. |P321 Specific treatment (see ... on this label). |P332+P313 If skin irritation occurs: Get medical |advice/attention. |P337+P313 If eye irritation persists: Get medical |advice/attention. |P351 Rinse cautiously with water for several |minutes. |P352 Wash with plenty of soap and water. |P362 Take off contaminated clothing and wash before |reuse. |P370+P378 In case of fire: Use ... for extinction. |P374 Fight fire with normal precautions from a |reasonable distance. |P375 Fight fire remotely due to the risk of |explosion. |P402 Store in a dry place. |P403+P233 Store in a well-ventilated place. Keep |container tightly closed. |P403+P235 Store in a well-ventilated place. Keep |cool. |P405 Store locked up. |P410+P412 Protect from sunlight. Do no expose to |temperatures exceeding 50�C/ 122�F. |P501 Dispose of contents/container to ... | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Aliphatic Hydrocarbon |64742-89-8 |25-50 | Liquefied Petroleum Gas |68476-86-8 |25-50 | n-Butyl Acetate |123-86-4 |10-25 |GHS02 H225 Xylene |1330-20-7 |2.5-10 |GHS02 H226 Ethylbenzene |100-41-4 |1.0-2.5 |GHS02-GHS07 | | |H225-332 | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. First-aid Measures After Skin Contact: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed. First-aid Measures After Ingestion: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: FLASH POINT IS LESS THAN 20 �. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR! Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only in a well-ventilated area. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 � F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Keep away from heat, sparks, flame and sources of ignition. Contents under pressure. Do not expose to heat or store above 120 � F. Avoid excess heat. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Use process enclosures, local exhaust ventilation, Controls |or other engineering controls to control airborne |levels below recommended exposure limits. Use |explosion-proof ventilation equipment. Provide |general dilution of local exhaust ventilation in |volume and pattern to keep TLV of hazardous |ingredients below acceptable limits. Prevent |build-up of vapors by opening all doors and windows |to achieve cross-ventilation. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Use safety eyewear designed to protect against |splash of liquids. Skin and Body Protection |Use gloves to prevent prolonged skin contact. Use |impervious gloves to prevent skin contact and |absorption of this material through the skin. |Nitrile or Neoprene gloves may afford adequate skin |protection. Respiratory Protection |A respiratory protection program that meets OSHA |1910.134 and ANSI Z88.2 requirements must be |followed whenever workplace conditions warrant a |respirator's use. A NIOSH/MSHA approved air |purifying respirator with organic vapor cartridge or |canister may be permissible under certain |circumstances where airborne concentrations are |expected to exceed exposure limits. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Aerosolized Mist Odor |Solvent Like Odor Threshold |N.E. pH |N.A. Relative Evaporation Rate |Faster than Ether (butylacetate=1) | Melting Point | Freezing Point |N.D Boiling Point |-34 - 662 Deg C Flash Point |-105 Deg C Auto-ignition Temperature |No Information Decomposition Temperature |No Information Flammability (solid, gas) |Supports Combustion Vapor Pressure |N.D. Relative Vapor Density at 20 �C |Heavier than Air Relative Density |0.720 Specific Gravity | Solubility |Negligible Partition coefficient: |No Information n-octanol/water | Viscosity |N.D. Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information VOLATILE ORGANIC COMPOUNDS, g/L: 622 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability This product is stable under normal storage conditions. 10.3 Possibility of Hazardous Reactions 10.4 Conditions to Avoid Avoid temperatures above 120 � F. Avoid contact with strong acid and strong bases. Avoid all possible sources of ignition. 10.5 Incompatible Materials Incompatible with strong oxidizing agents, strong acids and strong alkalies. 10.6 Hazardous Decomposition Products By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Avoid breathing fumes, spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation. Symptoms/Injuries After Skin Contact: Substance may cause slight skin irritation. May cause skin irritation. Allergic reactions are possible. Prolonged or repeated contact may cause skin irritation. Symptoms/Injuries After Eye Contact: Causes Serious Eye Irritation. Symptoms/Injuries After Ingestion: Harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage. Chronic Symptoms: May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B). SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Product is a mixture of listed components. Product is a mixture of listed components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Paint Products in |Limited Quantities Hazard Class |N.A. |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols Hazard Class |2.1 Identification Number|1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols Identification Number|1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes |Fire Hazard, Pressure Hazard, Acute Health |Hazard, Chronic Health Hazard Toxic Substances Control Act (TSCA) |This product contains the following chemical |substances subject to the reporting |requirements of TSCA 12(B) if exported from |the United States: No TSCA components exist |in this product. 15.2 US State Regulations Sara Section 313: Sara Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. Xylene 1330-20-7 Ethylbenzene 100-41-4 Modified Urea PROPRIETARY CALIFORNIA PROPOSITION 65: Warning: This products contains a substance known to the State of California to cause cancer. Chemical Name CAS-No. Ethylbenzene 100-41-4 CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive harm. Chemical Name CAS-No. Modified Urea PROPRIETARY n-Methyl 2-Pyrrolidone 872-50-4 International Regulations: CANADIAN WHMIS: This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. CANADIAN WHMIS CLASS: B2 D2A SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |9/15/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: | |H225 Highly flammable liquid and vapour ----|[pic]GHS02 |H226 Flammable liquid and vapour. -- | | ----|[pic] GHS07 |H332 Toxic if inhaled. -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer. Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust- Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users' consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.