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SDS Sheet 0067880Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: ICE BLASTER CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Automotive De-Icing 1.3. Name, Address, and Telephone of the Responsible Party Company The Blaster Corporation 8500 Sweet Valley Drive Valley View, Ohio 44125 Phone: (216) 901-5800 1.4. Emergency Telephone Number Emergency |CHEMTREC 24 hr. 1-800-424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flam. Aerosol |1 Compressed | dissolved gas | Acute Tox. |3 STOT SE |1 STOT RE |2 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Skull and Crossbones |Gas Cylinder |Health Hazard Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Extremely flammable aerosol. |Contains gas under pressure; may explode if heated. |Toxic if inhaled. |Toxic in contact with skin. |Toxic if swallowed. |Causes damage to organs: Optic nerve, Central |nervous system |May cause damage to organs through prolonged or |repeated exposure: oral, Kidneys. Precautionary Statements |Keep away from heat, hot surfaces, sparks, open (GHS-US) |flames and other ignition sources. No smoking. |Do not spray on an open flame or other ignition |source. |Do not pierce or burn, even after use. |Avoid breathing dust/fume/gas/mist/vapours/spray. |Use only outdoors or in a well-ventilated area. |Wear protective gloves/protective clothing/eye |protection/face protection. |Wash hands and exposed skin after use. |Do not eat, drink or smoke when using this product. |Keep out of reach of children. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Intentional inhalation of gas from the container may be fatal. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Methanol |67-56-1 |30 - 60 |Flam. Liq. 2; H225 | | | | | |Acute Tox. 3; | | |H301, H311, H331 | | |STOT SE 1; H370 Ethylene Glycol |107-21-1 |2 - 10 |Acute Tox. 4; H302 | | | | | |STOT RE 2; H373 Carbon Dioxide |124-38-9 |1 - 3 |Compressed | | |dissolved gas; | | |H280 | | |Simple asphyxiant | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air and keep comfortable for breathing. If breathing is labored, administer oxygen. If symptoms develop, obtain medical attention. Call a POISON CENTER/doctor if you feel unwell. First-aid Measures After Skin Contact: IF ON SKIN: Wash with plenty of water. Get immediate medical attention. Take off immediately all contaminated clothing and wash it before reuse. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. First-aid Measures After Ingestion: Do not give anything by mouth to an unconscious person. Get immediate medical attention. Rinse mouth. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: If exposed or concerned: Get medical attention/advice. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Extinguish with carbon dioxide, dry chemical, foam or waterspray. Unsuitable Extinguishing Media: Do not use water jet. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Highly flammable vapour (flash point below 23Â°C). Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: A self contained breathing apparatus and suitable protective clothing should be worn in fire conditions. Keep containers cool by spraying with water if exposed to fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid contact with skin and eyes. Avoid breathing gas/spray. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent liquid entering sewers, basements and work pits. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Cover spills with inert absorbent material. Methods for Cleaning Up: Transfer to a container for disposal or recovery. 6.4. Reference to Other Sections None. Additional Information: None. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid contact with skin and eyes. Use product in a well-ventilated area only. Do not use in confined spaces. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store locked up. Store in a well-ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50Â°C/ 122Â°F. Keep container tightly closed. Incompatible materials: This product should be stored away from sources of strong heat or oxidizing chemicals. 7.3. Specific End Use(s) Automotive De-Icing. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters SUBSTANCE. CAS No. (8hr TWA) (STEL) Note: PEL (OSHA) TLV (ACGIH) PEL (OSHA) TLV (ACGIH) Methanol 67-56-1 200 ppm 200 ppm ---- 250 ppm None Ethylene Glycol^^ 107-21-1 ---- ---- ---- 100 mg/m3 (ceiling) Aerosol Carbon dioxide 124-38-9 ---- 5000 ppm ---- 30,000 ppm ---- ^^ACGIHÂ® Notice of Intended Changes (2014) = 10 mg/m3 (8hr TWA); inhalable fraction and vapor. 8.2. Exposure Controls Appropriate Engineering |Ensure adequate ventilation. Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear protective eyewear (goggles, face shield, or |safety glasses). Skin and Body Protection |Wear suitable gloves if prolonged skin contact is |likely (Butyl rubber). Respiratory Protection |Normally no personal respiratory protection is |necessary. In case of insufficient ventilation, wear |suitable respiratory equipment. Check with |protective equipment manufacturer's data. Thermal Hazard Protection |Not normally required. Use gloves with insulation |for thermal protection, when needed. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Aerosol spray Odor |Methanol / Alcohol-like Odor Threshold | Not available pH |Not available Relative Evaporation Rate |Not available (butylacetate=1) | Melting Point |~ -50ÂºC (-58ÂºF) Freezing Point | ~ -50ÂºC (-58ÂºF) Boiling Point |~77ÂºC (170ÂºF) Flash Point |~23ÂºC (73ÂºF) Auto-ignition Temperature |Not available Decomposition Temperature |Not available Flammability (solid, gas) |Extremely flammable Vapor Pressure |Not available Relative Vapor Density at 20 Â°C |1.11 (Methanol) Relative Density | Specific Gravity | Solubility |(Water) Miscible |Solubility (Other) Not available Partition coefficient: |Not available n-octanol/water | Viscosity |Not available Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information Not available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable under normal conditions. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions None anticipated. 10.4 Conditions to Avoid Avoid contact with heat and ignition sources. 10.5 Incompatible Materials This product should be stored away from sources of strong heat or oxidizing chemicals. 10.6 Hazardous Decomposition Products Carbon monoxide, Carbon dioxide, Other, Acrid smoke. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Methanol (CAS# 67-56-1) LD50 (oral, monkey): 7000 mg/kg-bw LD0 (oral, rat): > 2528 mg/kg-bw LC50 (inhal., cat, 6-hours): 43.68 mg/L LC50 (inhal., monkey, 4-hours): 52 mg/L Ingestion may damage the optic nerve. May cause dizziness and drowsiness. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: May cause eye irritation. Respiratory or Skin Sensitization: It is not a skin sensitiser. Germ Cell Mutagenicity: Carcinogenicity: NTP IARC ACGIH OSHA NIOSHNo. No. No. No. No. No. Other information: * ATE (oral) = 100 mg/kg * ATE (dermal) = 300 mg/kg * ATE (inhalation) = 3 mg/L *ATE = Acute Toxicity Estimate for purposes of classification Reproductive Toxicity: Negative. Not a specific reproductive toxin. Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Methanol (CAS# 67-56-1) Short term LC50 (96 hour): 15400 mg/L (Lepomis macrochirus) EC50 (48 hour): 18260 mg/L (Daphnia magna, mobility) EC50 (96 hour): 22000 mg/L (Pseudokirchnerella subcapitata) Long Term NOEC (28 days) 446.7 mg/l (Fish) QSAR NOEC (21 days): 208 mg/l (Daphnia magna) QSAR 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal should be in accordance with local, state or national legislation. Consult an accredited waste disposal contractor or the local authority for advice. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols, flammable Hazard Class |2.1 Identification Number|1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable Identification Number|1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313 - Toxic Chemicals (40 CFR 372): Chemical Name CAS No. Typical %wt. Methanol 67-56-1 30 - 60 Ethylene Glycol 107-21-1 2 - 10 SARA 302 - Extremely Hazardous Substances(40 CFR 355): Chemical Name CAS No. Typical %wt. TPQ (pounds) None ---- ---- ---- SARA Section 311/312 Hazard Classes |X Fire |X Sudden Release |Reactivity |X Immediate (acute) |X Chronic (delayed) Toxic Substances Control Act (TSCA) - Inventory Status: All components listed or polymer exempt. Designated Hazardous Substances and Reportable Quantities (40 CFR 302.4): Chemical Name |CAS No. |Typical %wt. |RQ (Pounds) Methanol |67-56-1 |30 - 60 |5000 Ethylene Glycol |107-21-1 |2 - 10 |5000 15.2 US State Regulations <COMPONENT> California Proposition 65 List: Chemical Name CAS No. Type of Toxicity Methanol 67-56-1 Developmental SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |June 5, 2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|H225 |Highly flammable liquid and vapour. -- | | ----|H226 |Flammable liquid and vapour. -- | | ----|H280 |Contains gas under pressure; may explode if -- | |heated. ----|H301 |Toxic if swallowed. -- | | ----|H302 |Harmful if swallowed. -- | | |H311 |Toxic in contact with skin. |H331 |Toxic if inhaled. |H370 |Causes damage to organs: |H373 |May cause damage to organs <state all organs | |affected if known> through prolonged or | |repeated exposure. Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.