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SDS Sheet 0067880

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: ICE BLASTER                                                       
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Automotive De-Icing                               
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
The Blaster Corporation                                                         
 
8500 Sweet Valley Drive                                                         
 
Valley View, Ohio 44125                                                         
 
Phone: (216) 901-5800                                                           
 


1.4.  Emergency Telephone Number
Emergency     |CHEMTREC 24 hr. 1-800-424-9300                                   
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flam. Aerosol |1             
Compressed    |              
dissolved gas |              
Acute Tox.    |3             
STOT SE       |1             
STOT RE       |2             


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame |Skull and Crossbones |Gas Cylinder |Health
Hazard
        
Signal Word (GHS-US)         |DANGER                                            
 
Hazard Statements (GHS-US)   |Extremely flammable aerosol.                      
 
                             |Contains gas under pressure; may explode if
heated. 
                             |Toxic if inhaled.                                 
 
                             |Toxic in contact with skin.                       
 
                             |Toxic if swallowed.                               
 
                             |Causes damage to organs: Optic nerve, Central     
 
                             |nervous system                                    
 
                             |May cause damage to organs through prolonged or   
 
                             |repeated exposure: oral, Kidneys.                 
 
Precautionary Statements     |Keep away from heat, hot surfaces, sparks, open   
 
(GHS-US)                     |flames and other ignition sources. No smoking.    
 
                             |Do not spray on an open flame or other ignition   
 
                             |source.                                           
 
                             |Do not pierce or burn, even after use.            
 
                             |Avoid breathing dust/fume/gas/mist/vapours/spray. 
 
                             |Use only outdoors or in a well-ventilated area.   
 
                             |Wear protective gloves/protective clothing/eye    
 
                             |protection/face protection.                       
 
                             |Wash hands and exposed skin after use.            
 
                             |Do not eat, drink or smoke when using this
product. 
                             |Keep out of reach of children.                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Intentional inhalation of 
 
gas from the container may be fatal.                                            
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Methanol                        |67-56-1              |30 - 60 |Flam. Liq. 2;
H225
                                |                     |        |                
 
                                |                     |        |Acute Tox. 3;   
 
                                |                     |        |H301, H311, H331
 
                                |                     |        |STOT SE 1; H370 
 
Ethylene Glycol                 |107-21-1             |2 - 10  |Acute Tox. 4;
H302
                                |                     |        |                
 
                                |                     |        |STOT RE 2; H373 
 
Carbon Dioxide                  |124-38-9             |1 - 3   |Compressed      
 
                                |                     |        |dissolved gas;  
 
                                |                     |        |H280            
 
                                |                     |        |Simple
asphyxiant 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Remove person to fresh air and keep        
 
comfortable for breathing. If breathing is labored, administer oxygen. If
symptoms
develop, obtain medical attention. Call a POISON CENTER/doctor if you feel
unwell.
First-aid Measures After Skin Contact: IF ON SKIN: Wash with plenty of water.
Get 
immediate medical attention. Take off immediately all contaminated clothing and 
 
wash it before reuse.                                                           
 
First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water
for 
several minutes. Remove contact lenses, if present and easy to do. Continue     
 
rinsing. If eye irritation persists, get medical advice/attention.              
 
First-aid Measures After Ingestion: Do not give anything by mouth to an         
 
unconscious person. Get immediate medical attention. Rinse mouth. IF SWALLOWED: 
 
Immediately call a POISON CENTER or doctor/physician.                           
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion: If exposed or concerned: Get medical         
 
attention/advice.                                                               
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.             
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Extinguish with carbon dioxide, dry chemical, foam
 
or waterspray.                                                                  
 
Unsuitable Extinguishing Media: Do not use water jet.                           
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:  Highly flammable vapour (flash point below 23°C).                 
 
Explosion Hazard:                                                               
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: A self contained breathing apparatus and
suitable 
protective clothing should be worn in fire conditions. Keep containers cool by  
 
spraying with water if exposed to fire.                                         
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Keep away from heat/sparks/open flames/hot surfaces. - No     
 
smoking. Avoid contact with skin and eyes. Avoid breathing gas/spray.           
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Prevent liquid entering sewers, basements and work pits.                        
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Cover spills with inert absorbent material.                    
 
Methods for Cleaning Up: Transfer to a container for disposal or recovery.      
 


6.4.  Reference to Other Sections
None.                                                                           
 
Additional Information: None.                                                   
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Keep away from heat, hot surfaces, sparks,
open
flames and other ignition sources. No smoking. Avoid contact with skin and eyes.
 
Use product in a well-ventilated area only. Do not use in confined spaces.      
 
Hygiene Measures:                                                               
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions:  Store locked up. Store in a well-ventilated place. Protect 
 
from sunlight. Do not expose to temperatures exceeding 50°C/ 122°F. Keep
container
tightly closed.                                                                 
 
Incompatible materials: This product should be stored away from sources of
strong 
heat or oxidizing chemicals.                                                    
 


7.3.  Specific End Use(s)
Automotive De-Icing.                                                            
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
SUBSTANCE.                                                                      
 
CAS No.                                                                         
 
(8hr TWA)                                                                       
 
(STEL)                                                                          
 
Note:                                                                           
 
                                                                                
 
                                                                                
 
                                                                                
 
PEL (OSHA)                                                                      
 
TLV (ACGIH)                                                                     
 
PEL (OSHA)                                                                      
 
TLV (ACGIH)                                                                     
 
                                                                                
 
                                                                                
 
Methanol                                                                        
 
67-56-1                                                                         
 
200 ppm                                                                         
 
200 ppm                                                                         
 
----                                                                            
 
250 ppm                                                                         
 
None                                                                            
 
                                                                                
 
Ethylene Glycol^^                                                               
 
107-21-1                                                                        
 
----                                                                            
 
----                                                                            
 
----                                                                            
 
100 mg/m3 (ceiling)                                                             
 
Aerosol                                                                         
 
                                                                                
 
Carbon dioxide                                                                  
 
124-38-9                                                                        
 
----                                                                            
 
5000 ppm                                                                        
 
----                                                                            
 
30,000 ppm                                                                      
 
----                                                                            
 
                                                                                
 
^^ACGIH® Notice of Intended Changes (2014) = 10 mg/m3 (8hr TWA); inhalable      
 
fraction and vapor.                                                             
 


8.2.  Exposure Controls
Appropriate Engineering      |Ensure adequate ventilation.                      
 
Controls                     |                                                  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Wear protective eyewear (goggles, face shield, or 
 
                             |safety glasses).                                  
 
Skin and Body Protection     |Wear suitable gloves if prolonged skin contact is 
 
                             |likely (Butyl rubber).                            
 
Respiratory Protection       |Normally no personal respiratory protection is    
 
                             |necessary. In case of insufficient ventilation,
wear
                             |suitable respiratory equipment. Check with        
 
                             |protective equipment manufacturer's data.         
 
Thermal Hazard Protection    |Not normally required. Use gloves with insulation 
 
                             |for thermal protection, when needed.              
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |                                           
 
Appearance                          |Aerosol spray                              
 
Odor                                |Methanol / Alcohol-like                    
 
Odor Threshold                      | Not available                             
 
pH                                  |Not available                              
 
Relative Evaporation Rate           |Not available                              
 
(butylacetate=1)                    |                                           
 
Melting Point                       |~ -50ºC (-58ºF)                            
 
Freezing Point                      |  ~ -50ºC (-58ºF)                          
 
Boiling Point                       |~77ºC (170ºF)                              
 
Flash Point                         |~23ºC (73ºF)                               
 
Auto-ignition Temperature           |Not available                              
 
Decomposition Temperature           |Not available                              
 
Flammability (solid, gas)           |Extremely flammable                        
 
Vapor Pressure                      |Not available                              
 
Relative Vapor Density at 20 °C     |1.11 (Methanol)                            
 
Relative Density                    |                                           
 
Specific Gravity                    |                                           
 
Solubility                          |(Water)                      Miscible      
 
                                    |Solubility (Other)     Not available       
 
Partition coefficient:              |Not available                              
 
n-octanol/water                     |                                           
 
Viscosity                           |Not available                              
 
Lower Flammable Limit               |                                           
 
Upper Flammable Limit               |                                           
 


9.2.  Other Information
Not available                                                                   
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
Stable under normal conditions.                                                 
 


10.2      Chemical Stability
Stable.                                                                         
 


10.3      Possibility of Hazardous Reactions
None anticipated.                                                               
 


10.4      Conditions to Avoid
Avoid contact with heat and ignition sources.                                   
 


10.5      Incompatible Materials
This product should be stored away from sources of strong heat or oxidizing     
 
chemicals.                                                                      
 


10.6      Hazardous Decomposition Products
Carbon monoxide, Carbon dioxide, Other, Acrid smoke.                            
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Methanol (CAS# 67-56-1)                                                         
 
LD50 (oral, monkey): 7000 mg/kg-bw                                              
 
LD0 (oral, rat): > 2528 mg/kg-bw                                                
 
LC50 (inhal., cat, 6-hours): 43.68 mg/L                                         
 
LC50 (inhal., monkey, 4-hours): 52 mg/L                                         
 
Ingestion may damage the optic nerve.                                           
 
May cause dizziness and drowsiness.                                             
 
Skin Corrosion/Irritation:                                                      
 
Serious Eye Damage/Irritation: May cause eye irritation.                        
 
Respiratory or Skin Sensitization: It is not a skin sensitiser.                 
 
Germ Cell Mutagenicity:                                                         
 
Carcinogenicity:                                                                
 
NTP                                                                             
 
IARC                                                                            
 
ACGIH                                                                           
 
OSHA                                                                            
 
NIOSHNo.                                                                        
 
                                                                                
 
No.                                                                             
 
No.                                                                             
 
No.                                                                             
 
No.                                                                             
 
No.                                                                             
 
                                                                                
 
Other information: * ATE (oral) = 100 mg/kg                                     
 
* ATE (dermal) = 300 mg/kg                                                      
 
* ATE (inhalation) = 3 mg/L                                                     
 
*ATE = Acute Toxicity Estimate for purposes of classification                   
 
Reproductive Toxicity: Negative. Not a specific reproductive toxin.             
 
Specific Target Organ Toxicity (Single Exposure):                               
 
Specific Target Organ Toxicity (Repeated Exposure):                             
 
Aspiration Hazard:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Methanol (CAS# 67-56-1)                                                         
 
Short term                                              LC50 (96 hour): 15400
mg/L
(Lepomis macrochirus)                                                           
 
EC50 (48 hour): 18260 mg/L (Daphnia magna, mobility)                            
 
EC50 (96 hour): 22000 mg/L (Pseudokirchnerella subcapitata)                     
 
                                                                                
 
Long Term                                              NOEC (28 days) 446.7 mg/l
 
(Fish) QSAR                                                                     
 
NOEC (21 days): 208 mg/l (Daphnia magna) QSAR                                   
 


12.2. Persistence and Degradability
                                                                                
 


12.3. Bioaccumulative Potential
                                                                                
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
                                                                                
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Disposal should be in accordance with local,
state
or national legislation. Consult an accredited waste disposal contractor or the 
 
local authority for advice.                                                     
 
Additional Information:                                                         
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Aerosols, flammable                                       
 
Hazard Class         |2.1                    |<PICTOGRAM PHRASE>                
 
Identification Number|1950                   |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |Aerosols, flammable                                       
 
Hazard Class         |2.1                                                       
 
Identification Number|1950                                                      
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Aerosols, flammable                                       
 
Identification Number|1950                   |<PICTOGRAM PHRASE>                
  
Hazard Class         |2.1                    |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA 313 - Toxic Chemicals (40 CFR 372):                                        
 
Chemical Name                                                                   
 
CAS No.                                                                         
 
Typical %wt.                                                                    
 
                                                                                
 
Methanol                                                                        
 
67-56-1                                                                         
 
30 - 60                                                                         
 
                                                                                
 
Ethylene Glycol                                                                 
 
107-21-1                                                                        
 
2 - 10                                                                          
 
                                                                                
 
                                                                                
 
SARA 302 - Extremely Hazardous Substances(40 CFR 355):                          
 
Chemical Name                                                                   
 
CAS No.                                                                         
 
Typical %wt.                                                                    
 
TPQ (pounds)                                                                    
 
                                                                                
 
None                                                                            
 
----                                                                            
 
----                                                                            
 
----                                                                            
 
                                                                                
 
SARA Section 311/312 Hazard Classes |X  Fire                                    
 
                                    |X  Sudden Release                          
 
                                    |Reactivity                                 
 
                                    |X  Immediate (acute)                       
 
                                    |X  Chronic (delayed)                       
 
Toxic Substances Control Act (TSCA) - Inventory Status: All components listed or
 
polymer exempt.                                                                 
 
Designated Hazardous Substances and Reportable Quantities (40 CFR 302.4):       
 
Chemical Name    |CAS No.           |Typical %wt.          |RQ (Pounds)         
 
Methanol         |67-56-1           |30 - 60               |5000                
 
Ethylene Glycol  |107-21-1          |2 - 10                |5000                
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Proposition 65 List:                                                 
 
Chemical Name                                                                   
 
CAS No.                                                                         
 
Type of Toxicity                                                                
 
                                                                                
 
Methanol                                                                        
 
67-56-1                                                                         
 
Developmental                                                                   
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |June 5, 2015                                                   
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
----|H225                           |Highly flammable liquid and vapour.        
 
--  |                               |                                           
 
----|H226                           |Flammable liquid and vapour.               
 
--  |                               |                                           
 
----|H280                           |Contains gas under pressure; may  explode
if 
--  |                               |heated.                                    
 
----|H301                           |Toxic if swallowed.                        
 
--  |                               |                                           
 
----|H302                           |Harmful if swallowed.                      
 
--  |                               |                                           
 
    |H311                           |Toxic in contact with skin.                
 
    |H331                           |Toxic if inhaled.                          
 
    |H370                           |Causes damage to organs:                   
 
    |H373                           |May cause damage to organs <state all
organs 
    |                               |affected if known> through prolonged or    
 
    |                               |repeated exposure.                         
 


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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