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SDS Sheet 0067780Printer Friendly View
SECTION 1: IDENTIFICATION | |1.1. Product Identifier Product Form: Product Name: LSPR GENERAL DEGREASER CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: General Purpose Degreaser 1.3. Name, Address, and Telephone of the Responsible Party Company Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Phone 1.4. Emergency Telephone Number Emergency | 24 Hour Hotline: 847-367-7700 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |category 1 Aerosol | Flammable |Category 1 Liquid | Acute |Category 5 Toxicity, Oral| Acute |Category 5 Toxicity, | Dermal | Skin |Category 2 Irritation | Eye Irritation|Category 2 Acute |Category 4 Toxicity, | Inhalation | STOT, single |Category 3, exposure |RTI STOT, single |Category 3, NE exposure | Aspiration |Category 2 Hazard | Eye Irritation|Category 2B Flammable |Category 1 Aerosol | Acute |Category 1 Toxicity, | Dermal | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Skull and Crossbones |Flame |Health Hazard Hazard Statements (GHS-US) |H222 Extremely flammable aerosol. |H224 Extremely flammable liquid and vapour. |H303 May be harmful if swallowed. |H313 May be harmful in contact with skin. |H315 Causes skin irritation. |H319 Causes serious eye irritation. |H332 Harmful if inhaled. |H335 May cause respiratory irritation. |H336 May cause drowsiness or dizziness. |H305 May be harmful if swallowed and enters airways. | |H320 Causes eye irritation. |H280 Contains gas under pressure; may explode if |heated |H310 Fatal in contact with skin. Precautionary Statements |P211 Do not spray on an open flame or other ignition (GHS-US) |source. |P220 Keep/Store away from clothing/.../combustible |materials. |P235 Keep cool. |P251 Pressurized container: Do not pierce or burn, |even after use. |P375 Fight fire remotely due to the risk of |explosion. |P102 Keep out of reach of children. |P103 Read label before use. |P202 Do not handle until all safety precautions have |been read and understood. |P234 Keep only in original container. |P260 Do not breathe |dust/fume/gas/mist/vapours/spray. |P261 Avoid breathing |dust/fume/gas/mist/vapours/spray. |P262 Do not get in eyes, on skin, or on clothing. |P264 Wash ... thoroughly after handling. |P270 Do not eat, drink or smoke when using this |product. |P271 Use only outdoors or in a well-ventilated area. | |P273 Avoid release to the environment. |P280 Wear protective gloves/protective clothing/eye |protection/face protection. |P281 Use personal protective equipment as required. |P285 In case of inadequate ventilation wear |respiratory protection. |P312 Call a POISON CENTER or doctor/physician if you |feel unwell. |P351 Rinse cautiously with water for several |minutes. |P374 Fight fire with normal precautions from a |reasonable distance. |P402 Store in a dry place. |P210 Keep away from heat/sparks/open flames/hot |surfaces. - No smoking. |P410+P412 Protect from sunlight. Do no expose to |temperatures exceeding 50Â°C/ 122Â°F. |P240 Ground/bond container and receiving equipment. |P241 Use explosion-proof |electrical/ventilating/lighting/.../ equipment. |P242 Use only non-sparking tools. |P243 Take precautionary measures against static |discharge. |P303+P361+P353 IF ON SKIN (or hair): Remove/Take off |immediately all contaminated clothing. Rinse skin |with water/shower. |P370+P378 In case of fire: Use ... for extinction. |P403+P235 Store in a well-ventilated place. Keep |cool. |P501 Dispose of contents/container to ... |P321 Specific treatment (see ... on this label). |P352 Wash with plenty of soap and water. |P362 Take off contaminated clothing and wash before |reuse. |P332+P313 If skin irritation occurs: Get medical |advice/attention. |P305+P351+P338 IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P337+P313 If eye irritation persists: Get medical |advice/attention. |P304+P340 IF INHALED: Remove victim to fresh air and |keep at rest in a position comfortable for |breathing. |P405 Store locked up. |P403+P233 Store in a well-ventilated place. Keep |container tightly closed. |P310 Immediately call a POISON CENTER or |doctor/physician. |P322 Specific measures (see ... on this label). |P361 Remove/Take off immediately all contaminated |clothing. |P363 Wash contaminated clothing before reuse. |P302+P350 IF ON SKIN: Gently wash with plenty of |soap and water. | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Hydrotreated Light Distillate |64742-47-8 |25-50 |GHS06 H331 Difluoroethane |75-37-6 |10-25 | Liquefied Petroleum Gas |68476-86-8 |10-25 | D-Limonene |5989-27-5 |10-25 |GHS02-GHS06 | | |H226-310 | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. First-aid Measures After Skin Contact: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed. First-aid Measures After Ingestion: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: FLASH POINT IS LESS THAN 20 Â°. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR! Water spray may be ineffective. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode when exposed to extreme heat due to buildup of steam. No unusual fire or explosion hazards noted. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Evacuate area and fight fire from a safe distance. Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and nonsparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 Â° F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Contents under pressure. Do not expose to heat or store above 120 Â° F. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Use process enclosures, local exhaust ventilation, Controls |or other engineering controls to control airborne |levels below recommended exposure limits. Use |explosion-proof ventilation equipment. Prevent |build-up of vapors by opening all doors and windows |to achieve cross-ventilation. Provide general |dilution of local exhaust ventilation in volume and |pattern to keep TLV of hazardous ingredients below |acceptable limits. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Use safety eyewear designed to protect against |splash of liquids. Skin and Body Protection |Use impervious gloves to prevent skin contact and |absorption of this material through the skin. |Nitrile or Neoprene gloves may afford adequate skin |protection. Use gloves to prevent prolonged skin |contact. Respiratory Protection |A respiratory protection program that meets OSHA |1910.134 and ANSI Z88.2 requirements must be |followed whenever workplace conditions warrant a |respirator's use. A NIOSH/MSHA approved air |purifying respirator with organic vapor cartridge or |canister may be permissible under certain |circumstances where airborne concentrations are |expected to exceed exposure limits. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Aerosolized Mist Odor |Vinegar Like Odor Threshold |N.E. pH |N.A. Relative Evaporation Rate |Faster than Ether (butylacetate=1) | Melting Point | Freezing Point |N.D Boiling Point |-34 - 310 Deg C Flash Point |-105 Deg C Auto-ignition Temperature |No Information Decomposition Temperature | Flammability (solid, gas) |Supports Combustion Vapor Pressure |N.D. Relative Vapor Density at 20 Â°C |Heavier than Air Relative Density |0.754 Specific Gravity | Solubility |Negligible Partition coefficient: |No Information n-octanol/water | Viscosity |N.D. Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information VOLATILE ORGANIC COMPOUNDS, g/L: 595 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability This product is stable under normal storage conditions. 10.3 Possibility of Hazardous Reactions 10.4 Conditions to Avoid Avoid temperatures above 120 Â° F. Avoid all possible sources of ignition. Avoid contact with strong acid and strong bases. 10.5 Incompatible Materials Incompatible with strong oxidizing agents, strong acids and strong alkalies. 10.6 Hazardous Decomposition Products By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Prolonged or excessive inhalation may cause respiratory tract irritation. Causes nose and throat irritation. Breathing small amounts during normal handling is not likely to cause harmful effects; breathing large amounts may be harmful. Symptoms of overexposure include nose, throat and respiratory tract irritation. Pre-existing lung disorders, e.g. asthma-like conditions, may be aggravated by exposure to this material. Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Symptoms/Injuries After Skin Contact: Substance may cause slight skin irritation. Prolonged or repeated contact may cause skin irritation. May cause skin irritation. Allergic reactions are possible. Symptoms/Injuries After Eye Contact: Can cause severe eye irritation. Causes Serious Eye Irritation Symptoms/Injuries After Ingestion: Aspiration hazard if swallowed; can enter lungs and cause damage. Harmful if swallowed. Chronic Symptoms: Contains d-Limonene, which is an IARC Group 3 agent: "probably not carcinogenic to humans". D-Limonene is NOT classified as a carcinogen by OSHA, NTP nor ACGIH. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Product is a mixture of listed components. Product is a mixture of listed components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Paint Products in |Limited Quantities Hazard Class |N.A. |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols Hazard Class |2.1 Identification Number|1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols Identification Number|1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes |Fire Hazard, Pressure Hazard, Acute Health |Hazard Toxic Substances Control Act (TSCA) |This product contains the following chemical |substances subject to the reporting |requirements of TSCA 12(B) if exported from |the United States: No TSCA components exist |in this product. 15.2 US State Regulations Sara Section 313: Sara Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. Difluoroethane 75-37-6 CALIFORNIA PROPOSITION 65: Warning: This products contains a substance known to the State of California to cause cancer. No Proposition 65 Carcinogens exist in this product. CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive harm. No Proposition 65 Reproductive Toxins exist in this product. International Regulations: CANADIAN WHMIS: This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. CANADIAN WHMIS CLASS: B2 D2B SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |9/15/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|[pic]GHS02 |H226 Flammable liquid and vapour. -- | | ----|[pic]GHS06 |H310 Fatal in contact with skin. -- | | ----| |H331 Toxic if inhaled. -- | | ----| | -- | | ----| | -- | | Grainger disclaimer. Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust- Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users' consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.