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SDS Sheet 0067430

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: NON-CHLORINATED BRAKE & PARTS CLEANER 14.5OZ                      
 
CAS No:                                                                         
 
Synonyms: None                                                                  
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Aerosol Brake Cleaner                             
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
ITW Permatex                                                                    
 
10 Columbus Blvd.                                                               
 
Hartford, CT 06106 USA                                                          
 
Phone: (877) 376-2839                                                           
 


1.4.  Emergency Telephone Number
Emergency     | Chem-Tel: 800-255-3924,  International Emergency: 00+1+         
 
number        |813-248-0585                                                     
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Category 2    
corrosion/irri|              
tation        |              
Serious eye   |Category 2    
damage/eye    |              
irritation    |              
Specific      |Category 3    
target organ  |              
toxicity      |              
(single       |              
exposure)     |              
Aspiration    |Category 1    
toxicity      |              
Flammable     |Category 2    
aerosols      |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamation Mark |Health Hazard |Flame
        
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |Causes skin irritation                            
 
                             |Causes serious eye irritation                     
 
                             |May cause drowsiness or dizziness                 
 
                             |May be fatal if swallowed and enters airways      
 
                             |Extremely flammable aerosol                       
 
Precautionary Statements     |Prevention:                                       
 
(GHS-US)                     |Wash face, hands and any exposed skin thoroughly  
 
                             |after handling                                    
 
                             |Wear protective gloves/protective clothing/eye    
 
                             |protection/face protection                        
 
                             |Avoid breathing dust/fume/gas/mist/vapors/spray   
 
                             |Use only outdoors or in a well-ventilated area    
 
                             |Keep away from heat/sparks/open flames/hot
surfaces.
                             |- No smoking                                      
 
                             |Do not spray on an open flame or other ignition   
 
                             |source                                            
 
                             |Pressurized container: Do not pierce or burn, even
 
                             |after use                                         
 
                             |Response:                                         
 
                             |Specific treatment (see supplemental first aid    
 
                             |instructions on this label)                       
 
                             |IF IN EYES: Rinse cautiously with water for
several 
                             |minutes. Remove contact lenses, if present and
easy 
                             |to do. Continue rinsing                           
 
                             |If eye irritation persists: Get medical           
 
                             |advice/attention                                  
 
                             |If skin irritation occurs: Get medical            
 
                             |advice/attention                                  
 
                             |IF ON SKIN (or hair): Remove/Take off immediately 
 
                             |all contaminated clothing. Rinse skin with        
 
                             |water/shower                                      
 
                             |Wash contaminated clothing before reuse           
 
                             |IF INHALED: Remove victim to fresh air and keep at
 
                             |rest in a position comfortable for breathing      
 
                             |Call a POISON CENTER or doctor/physician if you
feel
                             |unwell                                            
 
                             |IF SWALLOWED: Immediately call a POISON CENTER or 
 
                             |doctor/physician                                  
 
                             |Do NOT induce vomiting                            
 
                             |Storage:                                          
 
                             |Store locked up                                   
 
                             |Protect from sunlight. Do not expose to
temperatures
                             |exceeding 50 °C/122 °F                            
 
                             |Disposal:                                         
 
                             |Dispose of contents/container to an approved waste
 
                             |disposal plant.                                   
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Not applicable            
 


2.4.  Unknown Acute Toxicity (GHS-US)
15 % of the mixture consists of ingredient(s) of unknown toxicity               
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US) / Trade
 
                                |                     |        |Secret          
 
ACETONE                         |67-64-1              |60 - 100|*               
 
HEPTANE                         |142-82-5             |7 - 13  |*               
 
CARBON DIOXIDE                  |124-38-9             |5 - 10  |*               
 


*The exact percentage (concentration) of composition has been withheld as a
trade secret.

SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General: Get medical advice/attention if you feel unwell.    
 
First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and 
 
keep at rest in a position comfortable for breathing. If symptoms persist, call
a 
physician.                                                                      
 
First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and
water.
If skin irritation persists, call a physician. Wash contaminated clothing before
 
reuse.                                                                          
 
First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water
for 
several minutes. Remove contact lenses, if present and easy to do. Continue     
 
rinsing. If eye irritation persists: Get medical advice/attention.              
 
First-aid Measures After Ingestion: IF SWALLOWED:. Call a physician or poison   
 
control center immediately. Do NOT induce vomiting.                             
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: See section 2 for more information.                          
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Note to physicians: Treat symptomatically.                                      
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Carbon dioxide (CO2), Dry chemical, Foam          
 
Unsuitable Extinguishing Media: None.                                           
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Extremely flammable aerosol. In a fire or if heated, a pressure    
 
increase will occur and the container may burst, with the risk of a subsequent  
 
explosion.                                                                      
 
Explosion Hazard:                                                               
 
Sensitivity to Mechanical Impact: None.                                         
 
Sensitivity to Static Discharge: None.                                          
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: As in any fire, wear self-contained breathing   
 
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective
gear.                                                                           
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Ensure adequate ventilation, especially in confined areas.
Avoid
contact with skin, eyes or clothing. Use personal protective equipment as       
 
required. Contents under pressure. Do not puncture or incinerate cans. Remove
all 
sources of ignition.                                                            
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
See Section 12 for additional ecological information. Do not flush into surface 
 
water or sanitary sewer system.                                                 
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Prevent further leakage or spillage if safe to do so.          
 
Methods for Cleaning Up: Eliminate all ignition sources if safe to do so. Ensure
 
adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel
 
into suitable containers for disposal.                                          
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Handle in accordance with good industrial    
 
hygiene and safety practice. Avoid breathing vapors or mists. Wash contaminated 
 
clothing before reuse. Wash thoroughly after handling. Avoid contact with skin, 
 
eyes or clothing. Use personal protective equipment as required. Keep away from 
 
heat/sparks/open flames/hot surfaces. - No smoking.                             
 
Hygiene Measures: Handle in accordance with good industrial hygiene and safety  
 
practice. Regular cleaning of equipment, work area and clothing is recommended. 
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Protect from sunlight. Do not expose to temperatures
exceeding
50 °C/122 °F. Store locked up.                                                  
 
Incompatible materials: Strong oxidizing agents, Amines, Acids                  
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Exposure Guidelines                                                             
 
Chemical Name                                                                   
 
ACGIH TLV                                                                       
 
OSHA PEL                                                                        
 
NIOSH IDLH                                                                      
 
                                                                                
 
ACETONE                                                                         
 
67-64-1                                                                         
 
STEL: 750 ppm                                                                   
 
TWA: 500 ppm                                                                    
 
TWA: 1000 ppm                                                                   
 
TWA: 2400 mg/m3                                                                 
 
(vacated) TWA: 750 ppm                                                          
 
(vacated) TWA: 1800 mg/m3                                                       
 
(vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose     
 
acetate fiber industry. It is in effect for all other sectors (vacated) STEL:
1000
ppm                                                                             
 
IDLH: 2500 ppm                                                                  
 
TWA: 250 ppm                                                                    
 
TWA: 590 mg/m3                                                                  
 
                                                                                
 
HEPTANE                                                                         
 
142-82-5                                                                        
 
STEL: 500 ppm                                                                   
 
TWA: 400 ppm                                                                    
 
TWA: 500 ppm                                                                    
 
TWA: 2000 mg/m3                                                                 
 
(vacated) TWA: 400 ppm                                                          
 
(vacated) TWA: 1600 mg/m3                                                       
 
(vacated) STEL: 500 ppm                                                         
 
(vacated) STEL: 2000 mg/m3                                                      
 
IDLH: 750 ppm                                                                   
 
Ceiling: 440 ppm 15 min                                                         
 
Ceiling: 1800 mg/m3 15 min                                                      
 
TWA: 85 ppm                                                                     
 
TWA: 350 mg/m3                                                                  
 
                                                                                
 
CARBON DIOXIDE                                                                  
 
124-38-9                                                                        
 
STEL: 30000 ppm                                                                 
 
TWA: 5000 ppm                                                                   
 
TWA: 5000 ppm                                                                   
 
TWA: 9000 mg/m3                                                                 
 
(vacated) TWA: 10000 ppm                                                        
 
(vacated) TWA: 18000 mg/m3                                                      
 
(vacated) STEL: 30000 ppm                                                       
 
(vacated) STEL: 54000mg/m3                                                      
 
IDLH: 40000 ppm                                                                 
 
TWA: 5000 ppm                                                                   
 
TWA: 9000 mg/m3                                                                 
 
STEL: 30000 ppm                                                                 
 
STEL: 54000 mg/m3                                                               
 
                                                                                
 
NIOSH IDLH Immediately Dangerous to Life or Health                              
 
Other Information: Vacated limits revoked by the Court of Appeals decision in   
 
AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Showers                                           
 
Controls                     |Eyewash stations                                  
 
                             |Ventilation systems                               
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Wear safety glasses with side shields (or
goggles). 
Skin and Body Protection     |Wear protective gloves and protective clothing.   
 
Respiratory Protection       |Use NIOSH-approved air-purifying respirator with  
 
                             |organic vapor cartridge or canister, as
appropriate.
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid; Aerosol                            
 
Appearance                          |Clear                                      
 
Odor                                |Solvent                                    
 
Odor Threshold                      |No information available                   
 
pH                                  |No information available                   
 
Relative Evaporation Rate           |> 1                                        
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No information available                   
 
Freezing Point                      |No information available                   
 
Boiling Point                       |> 54 °C / >130 °F                          
 
Flash Point                         |-20 °C / -4 °F Gives a flame projection at 
 
                                    |full valve opening or flashback at any
degree
                                    |of valve opening                           
 
Auto-ignition Temperature           |No information available                   
 
Decomposition Temperature           |No information available                   
 
Flammability (solid, gas)           |No information available                   
 
Vapor Pressure                      |No information available                   
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |0.8                                        
 
Specific Gravity                    |                                           
 
Solubility                          |Slightly soluble (water)                   
 
Partition coefficient:              |No information available                   
 
n-octanol/water                     |                                           
 
Viscosity                           |No information available                   
 
Lower Flammable Limit               |No information available                   
 
Upper Flammable Limit               |No information available                   
 


9.2.  Other Information
Softening point: No information available                                       
 
Molecular weight: No information available                                      
 
VOC Content (%): <10%                                                           
 
Density: No information available                                               
 
Bulk density: No information available                                          
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No data available                                                               
 


10.2      Chemical Stability
Stable under recommended storage conditions.                                    
 


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   
 


10.4      Conditions to Avoid
Heat, flames and sparks. Temperatures >50 °C / 122 °F.                          
 


10.5      Incompatible Materials
Strong oxidizing agents, Amines, Acids                                          
 


10.6      Hazardous Decomposition Products
Carbon oxides                                                                   
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation: May cause skin irritation and/or dermatitis.         
 
Serious Eye Damage/Irritation: Contact with eyes may cause irritation. May cause
 
redness and tearing of the eyes.                                                
 
Respiratory or Skin Sensitization: May cause irritation of respiratory tract.
May 
cause drowsiness or dizziness.                                                  
 
Germ Cell Mutagenicity: No information available.                               
 
Carcinogenicity: No information available.                                      
 
Reproductive Toxicity:                                                          
 
Specific Target Organ Toxicity (Single Exposure): Central nervous system,
Central 
Vascular System (CVS), Eyes, Respiratory system, Skin.                          
 
Specific Target Organ Toxicity (Repeated Exposure):                             
 
Aspiration Hazard:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion: Harmful if swallowed. Potential for
aspiration 
if swallowed. Aspiration may cause pulmonary edema and pneumonitis.             
 
Chronic Symptoms: No information available.                                     
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Ecotoxicity:                                                                    
 
15 % of the mixture consists of components(s) of unknown hazards to the aquatic 
 
environment                                                                     
 
Chemical Name                                                                   
 
Algae/aquatic plants                                                            
 
Fish                                                                            
 
Crustacea                                                                       
 
                                                                                
 
ACETONE                                                                         
 
67-64-1                                                                         
 
-                                                                               
 
4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 6210 - 8120: 96 h Pimephales    
 
promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50              
 
10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 -                      
 
12700: 48 h Daphnia magna mg/L EC50                                             
 
                                                                                
 
HEPTANE                                                                         
 
142-82-5                                                                        
 
                                                                                
 
375.0: 96 h Cichlid fish mg/L LC50                                              
 
10: 24 h Daphnia magna mg/L                                                     
 
EC50                                                                            
 
                                                                                
 


12.2. Persistence and Degradability
No information available.                                                       
 


12.3. Bioaccumulative Potential
No information available.                                                       
 


12.4. Mobility in Soil
No information available.                                                       
 
Chemical Name                                                                   
 
Partition coefficient                                                           
 
                                                                                
 
ACETONE                                                                         
 
67-64-1                                                                         
 
-0.24                                                                           
 
                                                                                
 
HEPTANE                                                                         
 
142-82-5                                                                        
 
4.66                                                                            
 
                                                                                
 


12.5. Other Adverse Effects
No information available                                                        
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: This material, as supplied, is a hazardous waste
 
according to federal regulations (40 CFR 261).                                  
 
Additional Information: Contaminated packaging: Do not reuse container.         
 
US EPA Waste Number: D001                                                       
 
US EPA Waste Number D001                                                        
 
RCRA                                                                            
 
RCRA - Basis for Listing                                                        
 
RCRA - D Series Wastes                                                          
 
RCRA - U Series Wastes                                                          
 
                                                                                
 
ACETONE                                                                         
 
67-64-1                                                                         
 
-                                                                               
 
Included in waste stream:                                                       
 
F039                                                                            
 
-                                                                               
 
U002                                                                            
 
                                                                                
 
                                                                                
 
This product contains one or more substances that are listed with the State of  
 
California as a hazardous waste.                                                
 
Chemical Name                                                                   
 
California Hazardous Waste Status                                               
 
                                                                                
 
ACETONE                                                                         
 
67-64-1                                                                         
 
Ignitable                                                                       
 
                                                                                
 
HEPTANE                                                                         
 
142-82-5                                                                        
 
Toxic                                                                           
 
Ignitable                                                                       
 
                                                                                
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Aerosols, Limited Quantity (LQ)                           
 
Hazard Class         |2.1                    |<PICTOGRAM PHRASE>                
 
Identification Number|1950                   |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |126                                                       
 


14.2 In Accordance with IMDG
Proper Shipping Name |Aerosols, Limited Quantity (LQ)                           
 
Hazard Class         |2.1                                                       
 
Identification Number|1950                                                      
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |F-D                   |                                   
 
EmS-No. (Spillage)   |S-U                   |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Consumer commodity                                        
 
Identification Number|ID 8000                |<PICTOGRAM PHRASE>                
  
Hazard Class         |9                      |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |9L                                                        
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA 313: Section 313 of Title III of the Superfund Amendments and
Reauthorization
Act of 1986 (SARA). This product does not contain any chemicals which are
subject 
to the reporting requirements of the Act and Title 40 of the Code of Federal    
 
Regulations, Part 372                                                           
 
                                                                                
 
CWA (Clean Water Act):                                                          
 
This product does not contain any substances regulated as pollutants pursuant to
 
the Clean Water Act (40 CFR 122.21 and 40                                       
 
CFR 122.42)                                                                     
 
                                                                                
 
CERCLA:                                                                         
 
This material, as supplied, contains one or more substances regulated as a      
 
hazardous substance under the Comprehensive Environmental Response Compensation 
 
and Liability Act (CERCLA) (40 CFR 302)                                         
 
                                                                                
 
Chemical Name                                                                   
 
Hazardous Substances RQs                                                        
 
CERCLA/SARA RQ                                                                  
 
Reportable Quantity (RQ)                                                        
 
                                                                                
 
ACETONE                                                                         
 
67-64-1                                                                         
 
5000 lb                                                                         
 
-                                                                               
 
RQ 5000 lb final RQ                                                             
 
RQ 2270 kg final RQ                                                             
 
                                                                                
 
SARA Section 311/312 Hazard Classes |Acute health hazard: Yes                   
 
                                    |Chronic Health Hazard: No                  
 
                                    |Fire hazard : Yes                          
 
                                    |Sudden release of pressure hazard: No      
 
                                    |Reactive Hazard: No                        
 
Toxic Substances Control Act (TSCA) |Complies                                   
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Proposition 65:                                                      
 
This product does not contain any Proposition 65 chemicals                      
 
                                                                                
 
U.S. State Right-to-Know Regulations                                            
 
Chemical Name                                                                   
 
New Jersey                                                                      
 
Massachusetts                                                                   
 
Pennsylvania                                                                    
 
                                                                                
 
ACETONE                                                                         
 
67-64-1                                                                         
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
HEPTANE                                                                         
 
142-82-5                                                                        
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
CARBON DIOXIDE                                                                  
 
124-38-9                                                                        
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
                                                                                
 
U.S. EPA Label Information                                                      
 
EPA Pesticide Registration Number: Not applicable                               
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |19-Jun-2015                                                    
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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