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SECTION 1: IDENTIFICATION | |1.1. Product Identifier Product Form: Product Name: 6731 NON-FLAMMABLE CONTACT CLEANER CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Contact Cleaner. 1.3. Name, Address, and Telephone of the Responsible Party Company Manufactured For: American Jetway Corporation Imperial Supplies LLC 34136 Myrtle Street 789 Armed Forces Drive Wayne, MI 48184-0126 P.O. Box 11008 Phone Green Bay, WI 54304 1.4. Emergency Telephone Number Emergency | Chemtrec 1-800-262-8200 ID 1195, 734-721-5930 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2 damage/eye | irritation | Carcinogenicit|Category 2 y | Reproductive |Category 1B Toxicity | Specific |Category 3 target organ | toxicity | (single | exposure) | Specific |Category 2 target organ | toxicity | (repeated | exposure) | Gases under |Compressed Gas pressure | Flammable |Category 3 aerosols | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Gas Cylinder Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Causes skin irritation |Causes serious eye irritation |Suspected of causing cancer |May damage fertility or the unborn child |May cause respiratory irritation |May cause damage to organs (central nervous system, |lungs, kidneys, and liver) through prolonged or |repeated exposure. |Contains gas under pressure; may explode if heated Precautionary Statements |Obtain special instructions before use (GHS-US) |Do not handle until all safety precautions have been |read and understood |Wash face, hands and any exposed skin thoroughly |after handling |Wear eye/face protection |Do not breathe dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Pressurized container: Do not pierce or burn, even |after use | |Precautionary Statements - Response |If exposed or concerned: Get medical |advice/attention |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water |If skin irritation occurs: Get medical |advice/attention |Take off contaminated clothing and wash before reuse | |IF INHALED: Remove victim to fresh air and keep at |rest in a position comfortable for breathing |Call a POISON CENTER or doctor/physician if you feel |unwell | |Precautionary Statements - Storage |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F | |Precautionary Statements - Disposal |Dispose of contents/container to an approved waste |disposal plant | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None 2.4. Unknown Acute Toxicity (GHS-US) Harmful to aquatic life with long lasting effects 32.95271% of the mixture consists of ingredient(s) of unknown toxicity SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) N-PROPYL BROMIDE, STABILIZED |106-94-5 |85-95 | CARBON DIOXIDE |124-38-9 |1-10 | 1,2-BUTYLENE OXIDE |106-88-7 |0.1-1.0 | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Avoid contact with skin, eyes, and clothing. Avoid breathing, vapors, mist, or gas. First-aid Measures After Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Get medical attention immediately if symptoms occur. First-aid Measures After Eye Contact: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek immediate medical attention/advice. First-aid Measures After Ingestion: Do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. Risk of product entering the lungs on vomiting after ingestion. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: Not applicable. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: water fog. Dry chemical. Carbon dioxide (CO2). Cool containers / tanks with water spray. Unsuitable Extinguishing Media: Do not use a solid water stream as it may scatter and spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Sensitivity to Mechanical Impact none. Sensitivity to Static Discharge Yes. Reactivity: Containers may explode when heated. 5.3. Advice for Firefighters Precautionary Measures Fire: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Use shielding to protect fire-fighters from bursting containers. Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Use shielding to protect fire-fighters from bursting containers. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use with adequate ventilation to keep the exposure levels below the OELS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Report spills as required by local and federal regulations. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Contain liquid and collect with an inter, non-combustible material. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Avoid skin contact. Use with adequate ventilation. Keep container away from heat, flames, and all other sources of ignition. Keep can away from all sources of electricity such as electric motors and batteries. Do not spray on hot surfaces. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Keep containers tightly closed in a dry, cool and well-ventilated place. Storage Conditions: Store away from strong oxidizers and acids. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Ventilation systems. Use adequate ventilation to Controls |keep the exposure levels below the OELs. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Aerosol Appearance |Clear Odor |Solvent Odor Threshold |No information available PH |No information available Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |no flash point Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity | Solubility |No information available Partition coefficient: | n-octanol/water | Viscosity |No information available Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information VOC Content(%) 92.08 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Store away from strong oxidizers and acids. 10.6 Hazardous Decomposition Products Carbon oxides. Fumes. Hydrocarbons. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. May cause mild irritation. Irritating to skin. Prolonged or repeated exposure may cause dermatitis. Not acutely toxic. Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Numerical measures of toxicity - Product Information Unknown Acute Toxicity 32.95271% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document. ATEmix (oral) 10656 mg/kg ATEmix (dermal) 4262 mg/kg ATEmix (inhalation-dust/mist) 34.4 mg/l Skin Corrosion/Irritation: Irritating to skin. Serious Eye Damage/Irritation: Irritating to eyes. Respiratory or Skin Sensitization: Germ Cell Mutagenicity: No information available. Carcinogenicity: Reproductive Toxicity: May damage fertility or the unborn child. Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Exposure to high vapour concentrations may cause nervous systems effects such as headache, nausea, and dizziness. Symptoms/Injuries After Skin Contact: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis.. Symptoms/Injuries After Eye Contact: May cause slight irritation. Symptoms/Injuries After Ingestion: Not acutely toxic. Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Chronic Symptoms: Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac arrest. Prolonged skin contact may defat the skin and produce dermatitis. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Dispose of in accordance with federal, state, and local regulations. Additional Information: Contaminated packaging: Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D |or |LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, NON-FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.2 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name Cas no Weight% SARA 313 Threshold Values% 1,2-BUTYLENE OXIDE - 106-88-7 0.1-1.0 0.1 SARA Section 311/312 Hazard Classes |Acute Health Hazard: Yes |Chronic Health Hazard: Yes |Fire Hazard: no |Sudden Release of Pressure Hazard: Yes |Reactive Hazard: no Toxic Substances Control Act (TSCA) |N-PROPYL |BROMIDE, |STABILIZED Yes | |CARBON DIOXIDE Yes | |1,2-BUTYLENE |OXIDE Yes | 15.2 US State Regulations Clean Water Act: This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA: This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. Chemical Name Hazardous Substances Rqs Extremely Hazardous Substances Rqs RQ 1,2-BUTYLENE OXIDE 100 lb RQ 100 lb final RQ 106-88-7 RQ 45.4 kg final RQ California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name California Prop. 65 N-PROPYL BROMIDE, STABILIZED - 106-94-5 Developmental Female Reproductive Male Reproductive Chemical Name New Jersey Massachusetts Pennsylvania N-PROPYL BROMIDE, STABILIZED Yes Yes Yes 106-94-5 CARBON DIOXIDE Yes Yes Yes 124-38-9 1,2-BUTYLENE OXIDE Yes Yes Yes 106-88-7 Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |20-Aug-2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.