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MSDS Sheet 0067200

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Material Safety Data Sheet | |
Date of issue:      |Revision Date:               |Revision Number:       
2010-01-20          |                             |                       
Imperial Supplies Part Number: 0067200                                    
1. PRODUCT AND COMPANY IDENTIFICATION                                     
Manufacturer:                                                             
Chemtool Incorporated                                                     
P.O.Box 538, 8200 Ridgefield Rd.                                          
Crystal Lake, IL 60039-0538, USA                                          
Telephone: +01(815) 288 - 3344                                            
Emergency  Phone: CHEMTREC (800) 424-9300 - Outside the US (703) 527-3887 
                                                                          
                                                                          
Product Name: LUBRIMATIC 5TH WHEEL TRAILER GREASE (11745-11746)           
Product Code(s): CLK2904000                                               
Recommended Use: Lubricating Grease                                       
UN-Number:                                                                
Product Type:                                                             
                                                                          
2.  HAZARDS IDENTIFICATION                                                
                                                                          
EMERGENCY OVERVIEW: Exposure to vapors generated at high temperatures may 
cause respiratory irritation. For further information, please refer to    
section 11.                                                               
                                                                          
Appearance:          |Physical State:          |Odor:                     
                                                                          
Potential Health Effects:                                                 
Principle Routes of Exposure: Inhalation. Skin and/or eye contact.        
Ingestion.                                                                
                                                                          
Acute Effects:                                                            
Eyes                 |Irritating.                                         
Skin                 |Repeated or prolonged contact can result in drying  
                     |of the skin.                                        
Inhalation           |Heating can generate vapors that may cause          
                     |respiratory irritation, nausea and headaches.       
                     |Inhalation hazard at room temperature is unlikely   
                     |due to the low volatility of this product.          
Ingestion            |Can cause stomach ache and vomiting. Main hazard, if
                     |ingested, is aspiration into the lungs and          
                     |subsequent pneumonitis.                             
Notes:                                                                    
                                                                          
Chronic Effects:                                                          
Eyes                 |                                                    
Skin                 |                                                    
Inhalation           |                                                    
Ingestion            |                                                    
Notes:                                                                    
                                                                          
Aggravated Medical Conditions: MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE. 
                                                                          
Environmental Hazard                                                      
                                                                          
3.  COMPOSITION/INFORMATION ON INGREDIENTS                                
                                                                          
Chemical/Ingredient Name |CAS-No     |Weight%   |ACGIH,    |OSHA-PE|Other 
                         |           |          |TLV-TWA   |L      |      
LUBRICATING OILS,        |Mixture(2) |40-60     |          |       |      
PETROLEUM, BASE OILS,    |           |          |          |       |      
HIGHLY REFINED (IP346    |           |          |          |       |      
DMSO Extracts <3%)       |           |          |          |       |      
GRAPHITE                 |7782-42-5  |20-40     |          |       |      
PETROLEUM RESINS         |64742-16-1 |7-13      |          |       |      
OCTADECANOIC ACID,       |Mixture    |7-13      |          |       |      
12-HYDROXY-, CALCIUM &   |           |          |          |       |      
LITHIUM SALTS (3159-62-4 |           |          |          |       |      
& 7620-77-1)             |           |          |          |       |      
MOLYBDENUM SULFIDE (MoS2)|1317-33-5  |1-2       |          |       |      
SILICA, CRYSTALLINE      |14808-60-7A|0.8-1.6   |          |       |      
(QUARTZ FROM NATURAL     |           |          |          |       |      
GRAPHITE)                |           |          |          |       |      
                         |           |          |          |       |      
Notes: This chemical(s) is hazardous according to OSHA/WHIMIS criteria.   
COMPOSITION COMMENTS Refer to section eight (8) for exposure limits on    
ingredients. Chemical ingredients not regulated by OSHA or SARA are       
treated confidentially.                                                   
                                                                          
4.  FIRST AID MEASURES                                                    
                                                                          
General Advice                                                            
Eyes               |Rinse the eye with water immediately. Continue to    
                   |rinse for at least 15 minutes. Contact physician if  
                   |discomfort continues.                                
Skin               |Remove contaminated clothing. Wash skin thoroughly   
                   |with soap and water. Get medical attention if any    
                   |discomfort continues.                                
Inhalation         |Vapor inhalation under ambient conditions is normally
                   |not a problem. If overcome by vapor of hot product,  
                   |immediately remove from source of exposure. Move the 
                   |exposed person to fresh air at once. For breathing   
                   |difficulties oxygen may be necessary. Get medical    
                   |attention if any discomfort continues.               
Ingestion          |DO NOT INDUCE VOMITING! Get medical attention        
                   |immediately!                                         
Notes to Physician |                                                     
Protection of      |                                                     
First-aiders       |                                                     
Notes              |                                                     
                                                                          
5.  FIRE-FIGHTING MEASURES                                                
                                                                          
Flammability/Flammable     |N/D                                           
properties                 |                                              
Flash point                |224 (435°F) Cd OC (Cleveland open cup).       
Recommended Extinguishing  |Use: Carbon dioxide (CO2). Dry chemicals,     
Media                      |sand, dolomite etc. Alcohol resistant foam.   
                           |Water spray, fog or mist.                     
Special  Fire-Fighting     |Use water to keep fire exposed containers cool
Procedures                 |and disperse vapors. Water spray may be used  
                           |to flush spills away from exposures and dilute
                           |spills to non-flammable mixtures. Avoid water 
                           |in straight hose stream; will scatter and     
                           |spread fire. Keep run-off water out of sewers 
                           |and water sources. Dike for water control.    
                           |                                              
Explosion Data             |Pressure will increase in over heated, closed 
                           |containers.                                   
Sensitivity to Mechanical  |                                              
Impact                     |                                              
Sensitivity to Static      |                                              
Discharge                  |                                              
                           |                                              
Specific Hazards from      |                                              
Chemical                   |                                              
                           |                                              
Protective Equipment       |                                              
                                                                          
NFPA |Health Hazard: |Flammability: 1|Instability:|Physical Hazard        
     |1              |               |0           |                       
                                                                          
HMIS |Health Hazard: |Flammability: 1|Physical      |PPE: B               
     |1              |               |Hazard: 0     |                     
                                                                          
6.  ACCIDENTAL RELEASE MEASURES                                           
                                                                          
Personal Precautions: Minimize skin contact.                              
Environmental Precautions: Keep product out of sewers and watercourses by 
drinking or impounding. Advise authorities if product has entered or may  
enter sewers, watercourses or extensive land areas. Assure conformity with
applicable government regulations.                                        
Methods for Containment                                                   
Methods for Cleaning Up: Keep all sources of ignition and hot metal       
surfaces away from spill. Avoid contact with eyes or skin. Place leaking  
containers in well ventilated area. If fire potential exists, blanket     
spill with foam or use water spray to disperse vapors. Contain spill to   
minimize contaminated area and facilitate salvage or disposal. To clean up
spill, flush area sparingly with water or use absorbent material. Avoid   
discharge to natural water ways.                                          
Notes                                                                     
                                                                          
7.  HANDLING AND STORAGE                                                  
                                                                          
Handling: Keep away from heat, sparks and open flame. Ventilate well,     
avoid breathing vapors. Use approved respirator if air contamination is   
above accepted level. Do not reuse container. Keep lid closed when not in 
use. Do not store or mix with strong oxidizers. Avoid spilling, skin and  
eye contact. Eye wash and emergency shower must be available at the work  
place.                                                                    
Storage: Store separate from strong acids and oxidizers. Keep away from   
heat, sparks and open flame.                                              
Storage Criteria: Chemical storage.                                       
                                                                          
8.  EXPOSURE CONTROLS/PERSONAL PROTECTION                                 
                                                                          
Exposure Guidelines                                                       
                                                                          
Chemical Name    |ACGIH TLV  |OSHA PEL        |NIOSH IDLH     |OTHER      
LUBRICATING OILS,|TWA 5 mg/m3|TWA 5 mg/m3 as  |               |           
PETROLEUM, BASE  |as oil mist|oil mist        |               |           
OILS, HIGHLY     |           |                |               |           
REFINED (IP346   |STEL 10    |                |               |           
DMSO Extracts    |mg/m3 as   |                |               |           
<3%)             |oil mist   |                |               |           
GRAPHITE         |TWA 2 mg/m3|TWA 15 mppcf    |TWA 2 mg/m3    |           
                 |(resp)     |                |(resp)         |           
                 |STEL except|                |               |           
                 |graphite   |                |               |           
                 |fibers     |                |               |           
PETROLEUM RESINS |TWA 5 mg/m3|TWA 5 mg/m3 (oil|               |           
                 |(oil mist) |mist)           |               |           
                 |STEL 10    |                |               |           
                 |mg/m3 (oil |                |               |           
                 |mist)      |                |               |           
MOLYBDENUM       |TWA 3 mg/m3|TWA N/E         |               |           
SULFIDE (MoS2)   |(resp) as  |                |               |           
                 |Mo         |                |               |           
                 |10 mg/m3   |                |               |           
                 |(ihl) as Mo|                |               |           
SILICA,          |TWA 0.05   |TWA 0.3 mg/m3   |TWA 0.05 mg/m3 |           
CRYSTALLINE      |mg/m3      |(total) 0.1     |STEL Ca        |           
(QUARTZ FROM     |(resp)     |mg/m3 (resp)    |               |           
NATURAL GRAPHITE)|STEL A2    |                |               |           
                 |           |                |               |           
                 |           |                |               |           
                                                                          
Engineering Measures: Use engineering controls to reduce air contamination
to permissible exposure level.                                            
                                                                          
Personal Protective Equipment                                             
Eyes/Face          |Wear splash-proof eye goggles to prevent any         
Protection         |possibility of eye contact.                          
Skin and Body      |Protective Gloves: Chemical resistant gloves         
Protection         |recommended to prevent prolonged or repeated contact.
                   |                                                     
                   |Protective Clothing: Wear appropriate clothing to    
                   |prevent repeated or prolonged skin contact.          
Respiratory        |No specific recommendation made, but respiratory     
Protection         |protection may still be required under exceptional   
                   |circumstances when excessive air contamination       
                   |exists.                                              
Ventilation/Other  |No specific ventilation requirements noted, but      
                   |forced ventilation may still be required if air      
                   |contamination exceeds acceptable level.              
Hygiene Measures: Wash at the end of each work shift and before eating,   
smoking and using the toilet.                                             
                                                                          
9.  PHYSICAL AND CHEMICAL PROPERTIES                                      
                                                                          
Appearance       |Grease       |Odor                |Mild (or faint).    
                 |             |                    |Petroleum           
Odor Threshold   |             |Physical State      |Grease              
Color            |Black        |Viscosity           |                    
pH               |N/A          |Percent  Volatile,  |                    
                 |             |wt. %               |                    
Flash Point      |             |Auto-ignition       |                    
                 |             |Temperature         |                    
Decomposition    |             |Boiling Point/ Range|                    
Temp             |             |                    |                    
Melting          |             |Freezing Point      |                    
Point/Range      |             |                    |                    
Flammability     |             |Explosion Limits    |                    
Specific Gravity |             |Water Solubility    |                    
Solubility       |Insoluble in |Evaporation Rate    |< 0.01 BuAc=1       
                 |water        |                    |                    
Vapor Pressure   |< 0.1 mmHg   |Vapor Density       |> 5                 
                 |(°C) 20      |                    |                    
                 |(68°F)       |                    |                    
VOC content, wt. |             |                    |                    
%                |             |                    |                    
                 |             |                    |                    
Notes                                                                     
                                                                          
10. STABILITY AND REACTIVITY                                              
                                                                          
Chemical Stability        |Normally stable.                               
Incompatible Products     |                                               
Conditions to avoid       |Avoid contact with acids and oxidizing         
                          |substances.                                    
Hazardous Decomposition   |Oxides of: Carbon. Sulfur.                     
Products                  |                                               
Hazardous Polymerization  |Will not occur.                                
Notes                                                                     
                                                                          
11. TOXICOLOGY INFORMATION                                                
                                                                          
Acute Toxicity                                                            
                                                                          
Product          |                                                        
Information      |                                                        
Inhalation      |                                                        
Eye Contact     |                                                        
Skin Contact    |                                                        
Ingestion       |                                                        
                                                                          
Chemical Name   |LD50 Oral      |LD50 Dermal       |LC50 Inhalation      
LUBRICATING     |> 5000 mg/kg   |> 2000 mg/kg      |No Information       
OILS, PETROLEUM,|               |                  |Available            
BASE OILS,      |               |                  |                     
HIGHLY REFINED  |               |                  |                     
(IP346          |               |                  |                     
DMSO Extracts   |               |                  |                     
<3%)            |               |                  |                     
GRAPHITE        |> 2,000 mg/kg  |                  |No Information       
                |               |                  |Available            
PETROLEUM RESINS|7,000 mg/kg    |                  |No Information       
                |               |                  |Available            
OCTADECANOIC    |No Information |No Information    |No Information       
ACID,           |Available      |Available         |Available            
12-HYDROXY-,    |               |                  |                     
CALCIUM &       |               |                  |                     
LITHIUM SALTS   |               |                  |                     
(3159-62-4 &    |               |                  |                     
7620-77-1)      |               |                  |                     
SILICA,         |N/A.           |N/A.              |N/A.                 
CRYSTALLINE     |               |                  |                     
(QUARTZ FROM    |               |                  |                     
NATURAL         |               |                  |                     
GRAPHITE)       |               |                  |                     
                |               |                  |                     
                                                                          
Chronic Toxicity|                                                        
                                                                          
Chemical Name   |ACGIH            |IARC      |NTP          |OSHA          
                |                 |          |             |              
                |                 |          |             |              
                                                                          
Target Organ Effects                                                      
                                                                          
12.  ECOLOGICAL INFORMATION                                               
                                                                          
Ecotoxicity: There is no ecological data on the product itself.           
The Environmental impact of this product has been fully investigated      
                                                                          
Chemical Name|Toxicity to    |Toxicity to  |Tox, to       |Daphnia Magna   
             |Algea          |Fish         |Microorganisms|(water flea)    
             |               |             |              |                
             |               |             |              |                
             |               |             |              |                
                                                                          
Notes: ECOLOGICAL INFORMATION: There is no ecological data on the product 
itself.                                                                   
                                                                          
13.  DISPOSAL CONSIDERATIONS                                              
                                                                          
Waste Disposal Methods: Spilled material, unused contents and empty       
containers must be disposed of in accordance with local, state and federal
regulations.                                                              
                                                                          
Contaminated Packaging                                                    
                                                                          
US EPA Waste number                                                       
                                                                          
Notes                                                                     
                                                                          
                                                                          
14.  TRANSPORTATION INFORMATION                                           
                                                                          
DOT                                                                       
UN-Number           |                                                     
Proper Shipping name|Not regulated.                                       
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
Emergency Response  |                                                     
Guide Number        |                                                     
                                                                          
TDG                                                                       
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
MEX                 |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
ICAO                                                                      
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
IATA: Not regulated.                                                      
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
ERG Code            |                                                     
Description         |                                                     
                                                                          
IMDG/IMO: Not regulated.                                                  
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
EmS No.             |                                                     
Description         |                                                     
                                                                          
RID                                                                       
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |                                                     
ADR/RID-Labels     |                                                     
                                                                          
ADR                                                                       
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |                                                     
ADR/RID-Labels     |                                                     
                                                                          
ADN                                                                       
UN-Number                                                                 
Proper Shipping name                                                      
Hazard Class                                                              
Packing Group                                                             
Classification Code                                                       
Special Provisions                                                        
Description                                                               
Hazard Labels                                                             
Limited Quantity                                                          
                                                                          
15.  REGULATORY INFORMATION                                               
                                                                          
International Inventories                                                 
TSCA: All components in this product are listed on the US Toxic Substances
Control Act (TSCA) Inventory or are exempt from TSCA Inventory            
requirements.                                                             
DSL: All components in this product are listed on the Canada Domestic     
Substances List (DSL) or are exempt from DSL requirements.                
EINECS: All components in this product are listed on the European         
Inventory of New and Existing Chemical Substances (EINECS), the European  
LIst of Notified Chemical Substances (ELINCS), or the No Longer Polymers  
(NLP) list, or are exempt from EU listing requirements.                   
ENCS: All components in this product are listed on the Japan Inventory of 
Existing and New Chemical Substances (ENCS) or are exempt from ENCS       
requirements.                                                             
IECSC: All components in this product are listed on the China Inventory of
Existing Chemical Substances (IECS) or are exempt from IECS requirements. 
PICCS: All components in this product are listed on the Philippines       
Inventory of Chemicals and Chemical Substances (PICCS) or are exempt from 
PICCS requirements.                                                       
AICS: All components in this product are listed on the Australian         
Inventory of Chemical Substances (AICS) or are exempt from AICS           
requirements.                                                             
                                                                          
U.S. Federal Regulations:                                                 
COMPONENT                                                                 
SARA 302                  CERCLA                   SARA 313               
LUBRICATING OILS, PETROLEUM, BASE OILS,                                   
HIGHLY REFINED (IP346 DMSO                                                
No                              No                            No          
Extracts <3%)                                                             
GRAPHITE                                                                  
No                              No                            No          
PETROLEUM RESINS                                                          
No                              No                            No          
OCTADECANOIC ACID, 12-HYDROXY-, CALCIUM                                   
& LITHIUM SALTS (3159-62-4 & 7620-77-1)                           No      
No                             No                                         
MOLYBDENUM SULFIDE (MoS2)                                              No 
No                             No                                         
SILICA, CRYSTALLINE (QUARTZ FROM NATURAL                                  
GRAPHITE)                                                                 
No                              No                             No         
SARA 313                                                                  
SARA 311/312 Hazard Categories: None.                                     
Acute Health Hazard                                                       
Chronic Health Hazard                                                     
Fire Hazard                                                               
Sudden Release of Pressure Hazard                                         
Reactive Hazard                                                           
                                                                          
Clean Water Act                                                           
                                                                          
CERCLA                                                                    
                                                                          
U.S. State Regulations:                                                   
COMPONENT                                                                 
CA              MA            FL           MN        NJ         PA        
RI                                                                        
LUBRICATING OILS, PETROLEUM, BASE OILS,                                   
HIGHLY REFINED (IP346 DMSO Extracts <3%)           No              No     
No          No        No         No      No                               
GRAPHITE                                                                  
No              No             No          No        Yes        Yes     No
                                                                          
PETROLEUM RESINS                                                       No 
No              No          No        No         No     No                
MOLYBDENUM SULFIDE (MoS2)                                  No             
No             Yes          No        No         No     No                
SILICA, CRYSTALLINE (QUARTZ FROM NATURAL                                  
GRAPHITE)                                                                 
C                 No              No          No        Yes        Yes    
No                                                                        
                                                                          
STATE REGULATORY STATUS CALIFORNIA PROPOSITION 65: This product may       
contain the following chemical(s) considered by the State of California's 
Safe Drinking Water and Toxic Enforcement Act of 1986 as causing cancer or
reproductive toxicity, and for which warnings are now required:           
Crystalline silica, cancer hazard, CAS# 14808-60-7, see sec. #2.          
                                                                          
U.S. State Right-to-Know Regulations                                      
                                                                          
International Regulations:                                                
GLOBAL INVENTORIES                                                        
COMPONENT                                                            CAN  
US        EU       AUS      JAP     KOR     PHLP   CHN                    
SILICA, CRYSTALLINE (QUARTZ FROM                                          
NATURAL GRAPHITE)                                                DSL      
Yes       EINECS  Yes      Yes     Yes      Yes      Yes                  
LUBRICATING OILS, PETROLEUM,                                              
BASE OILS, HIGHLY REFINED                                                 
(IP346 DMSO Extracts <3%)                                     DSL         
Yes        EINECS  Yes     Yes       Yes     Yes      Yes                 
GRAPHITE                                                                  
DSL              Yes       EINECS   Yes     Exmpt  Yes    Yes     Yes     
PETROLEUM RESINS                                                  DSL     
Yes        EINECS   Yes    Yes        Yes    Yes     Yes                  
OCTADECANOIC ACID, 12-HYDROXY-, CALCIUM                                   
& LITHIUM SALTS (3159-62-4 & 7620-77-1)          DSL              Yes     
EINECS   Yes     Yes        Yes    Yes   Yes                              
MOLYBDENUM SULFIDE (MoS2)                             DSL                 
Yes        EINECS   Yes     PRTR1   Yes   Yes   Yes                       
                                                                          
Canada: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHMIS          
This product has been classified in accordance with the hazard criteria of
the Controlled Products Regulations and the MSDS contains all the         
information required by the Controlled Products Regulations.              
                                                                          
                                                                          
                                                                          
16.  OTHER INFORMATION                                                    
                                                                          
Prepared By: Chemtool Incorporated                                        
Revision Date: 2010-01-20                                                 
Company: Chemtool Incorporated                                            
Revision number                                                           
Telephone number: (800) 424-9300, (703) 527-3887                          
                                                                          
Notes                                                                     
                                                                          
Other Information                                                         
                                                                          
Disclaimer information: While the information and recommendations set     
forth herein are believed to be accurate as of the date thereof, the      
company makes no warranty with respect thereto and disclaims all liability
from reliance therein.                                                    
                                                                          
                                                                          
END OF MATERIAL SAFETY DATA SHEET                                         


    

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.

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