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Material Safety Data Sheet | | Date of issue: |Revision Date: |Revision Number: 2010-01-20 | | Imperial Supplies Part Number: 0067200 1. PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Chemtool Incorporated P.O.Box 538, 8200 Ridgefield Rd. Crystal Lake, IL 60039-0538, USA Telephone: +01(815) 288 - 3344 Emergency Phone: CHEMTREC (800) 424-9300 - Outside the US (703) 527-3887 Product Name: LUBRIMATIC 5TH WHEEL TRAILER GREASE (11745-11746) Product Code(s): CLK2904000 Recommended Use: Lubricating Grease UN-Number: Product Type: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Exposure to vapors generated at high temperatures may cause respiratory irritation. For further information, please refer to section 11. Appearance: |Physical State: |Odor: Potential Health Effects: Principle Routes of Exposure: Inhalation. Skin and/or eye contact. Ingestion. Acute Effects: Eyes |Irritating. Skin |Repeated or prolonged contact can result in drying |of the skin. Inhalation |Heating can generate vapors that may cause |respiratory irritation, nausea and headaches. |Inhalation hazard at room temperature is unlikely |due to the low volatility of this product. Ingestion |Can cause stomach ache and vomiting. Main hazard, if |ingested, is aspiration into the lungs and |subsequent pneumonitis. Notes: Chronic Effects: Eyes | Skin | Inhalation | Ingestion | Notes: Aggravated Medical Conditions: MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE. Environmental Hazard 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical/Ingredient Name |CAS-No |Weight% |ACGIH, |OSHA-PE|Other | | |TLV-TWA |L | LUBRICATING OILS, |Mixture(2) |40-60 | | | PETROLEUM, BASE OILS, | | | | | HIGHLY REFINED (IP346 | | | | | DMSO Extracts <3%) | | | | | GRAPHITE |7782-42-5 |20-40 | | | PETROLEUM RESINS |64742-16-1 |7-13 | | | OCTADECANOIC ACID, |Mixture |7-13 | | | 12-HYDROXY-, CALCIUM & | | | | | LITHIUM SALTS (3159-62-4 | | | | | & 7620-77-1) | | | | | MOLYBDENUM SULFIDE (MoS2)|1317-33-5 |1-2 | | | SILICA, CRYSTALLINE |14808-60-7A|0.8-1.6 | | | (QUARTZ FROM NATURAL | | | | | GRAPHITE) | | | | | | | | | | Notes: This chemical(s) is hazardous according to OSHA/WHIMIS criteria. COMPOSITION COMMENTS Refer to section eight (8) for exposure limits on ingredients. Chemical ingredients not regulated by OSHA or SARA are treated confidentially. 4. FIRST AID MEASURES General Advice Eyes |Rinse the eye with water immediately. Continue to |rinse for at least 15 minutes. Contact physician if |discomfort continues. Skin |Remove contaminated clothing. Wash skin thoroughly |with soap and water. Get medical attention if any |discomfort continues. Inhalation |Vapor inhalation under ambient conditions is normally |not a problem. If overcome by vapor of hot product, |immediately remove from source of exposure. Move the |exposed person to fresh air at once. For breathing |difficulties oxygen may be necessary. Get medical |attention if any discomfort continues. Ingestion |DO NOT INDUCE VOMITING! Get medical attention |immediately! Notes to Physician | Protection of | First-aiders | Notes | 5. FIRE-FIGHTING MEASURES Flammability/Flammable |N/D properties | Flash point |224 (435�F) Cd OC (Cleveland open cup). Recommended Extinguishing |Use: Carbon dioxide (CO2). Dry chemicals, Media |sand, dolomite etc. Alcohol resistant foam. |Water spray, fog or mist. Special Fire-Fighting |Use water to keep fire exposed containers cool Procedures |and disperse vapors. Water spray may be used |to flush spills away from exposures and dilute |spills to non-flammable mixtures. Avoid water |in straight hose stream; will scatter and |spread fire. Keep run-off water out of sewers |and water sources. Dike for water control. | Explosion Data |Pressure will increase in over heated, closed |containers. Sensitivity to Mechanical | Impact | Sensitivity to Static | Discharge | | Specific Hazards from | Chemical | | Protective Equipment | NFPA |Health Hazard: |Flammability: 1|Instability:|Physical Hazard |1 | |0 | HMIS |Health Hazard: |Flammability: 1|Physical |PPE: B |1 | |Hazard: 0 | 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Minimize skin contact. Environmental Precautions: Keep product out of sewers and watercourses by drinking or impounding. Advise authorities if product has entered or may enter sewers, watercourses or extensive land areas. Assure conformity with applicable government regulations. Methods for Containment Methods for Cleaning Up: Keep all sources of ignition and hot metal surfaces away from spill. Avoid contact with eyes or skin. Place leaking containers in well ventilated area. If fire potential exists, blanket spill with foam or use water spray to disperse vapors. Contain spill to minimize contaminated area and facilitate salvage or disposal. To clean up spill, flush area sparingly with water or use absorbent material. Avoid discharge to natural water ways. Notes 7. HANDLING AND STORAGE Handling: Keep away from heat, sparks and open flame. Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Do not reuse container. Keep lid closed when not in use. Do not store or mix with strong oxidizers. Avoid spilling, skin and eye contact. Eye wash and emergency shower must be available at the work place. Storage: Store separate from strong acids and oxidizers. Keep away from heat, sparks and open flame. Storage Criteria: Chemical storage. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name |ACGIH TLV |OSHA PEL |NIOSH IDLH |OTHER LUBRICATING OILS,|TWA 5 mg/m3|TWA 5 mg/m3 as | | PETROLEUM, BASE |as oil mist|oil mist | | OILS, HIGHLY | | | | REFINED (IP346 |STEL 10 | | | DMSO Extracts |mg/m3 as | | | <3%) |oil mist | | | GRAPHITE |TWA 2 mg/m3|TWA 15 mppcf |TWA 2 mg/m3 | |(resp) | |(resp) | |STEL except| | | |graphite | | | |fibers | | | PETROLEUM RESINS |TWA 5 mg/m3|TWA 5 mg/m3 (oil| | |(oil mist) |mist) | | |STEL 10 | | | |mg/m3 (oil | | | |mist) | | | MOLYBDENUM |TWA 3 mg/m3|TWA N/E | | SULFIDE (MoS2) |(resp) as | | | |Mo | | | |10 mg/m3 | | | |(ihl) as Mo| | | SILICA, |TWA 0.05 |TWA 0.3 mg/m3 |TWA 0.05 mg/m3 | CRYSTALLINE |mg/m3 |(total) 0.1 |STEL Ca | (QUARTZ FROM |(resp) |mg/m3 (resp) | | NATURAL GRAPHITE)|STEL A2 | | | | | | | | | | | Engineering Measures: Use engineering controls to reduce air contamination to permissible exposure level. Personal Protective Equipment Eyes/Face |Wear splash-proof eye goggles to prevent any Protection |possibility of eye contact. Skin and Body |Protective Gloves: Chemical resistant gloves Protection |recommended to prevent prolonged or repeated contact. | |Protective Clothing: Wear appropriate clothing to |prevent repeated or prolonged skin contact. Respiratory |No specific recommendation made, but respiratory Protection |protection may still be required under exceptional |circumstances when excessive air contamination |exists. Ventilation/Other |No specific ventilation requirements noted, but |forced ventilation may still be required if air |contamination exceeds acceptable level. Hygiene Measures: Wash at the end of each work shift and before eating, smoking and using the toilet. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance |Grease |Odor |Mild (or faint). | | |Petroleum Odor Threshold | |Physical State |Grease Color |Black |Viscosity | pH |N/A |Percent Volatile, | | |wt. % | Flash Point | |Auto-ignition | | |Temperature | Decomposition | |Boiling Point/ Range| Temp | | | Melting | |Freezing Point | Point/Range | | | Flammability | |Explosion Limits | Specific Gravity | |Water Solubility | Solubility |Insoluble in |Evaporation Rate |< 0.01 BuAc=1 |water | | Vapor Pressure |< 0.1 mmHg |Vapor Density |> 5 |(�C) 20 | | |(68�F) | | VOC content, wt. | | | % | | | | | | Notes 10. STABILITY AND REACTIVITY Chemical Stability |Normally stable. Incompatible Products | Conditions to avoid |Avoid contact with acids and oxidizing |substances. Hazardous Decomposition |Oxides of: Carbon. Sulfur. Products | Hazardous Polymerization |Will not occur. Notes 11. TOXICOLOGY INFORMATION Acute Toxicity Product | Information | Inhalation | Eye Contact | Skin Contact | Ingestion | Chemical Name |LD50 Oral |LD50 Dermal |LC50 Inhalation LUBRICATING |> 5000 mg/kg |> 2000 mg/kg |No Information OILS, PETROLEUM,| | |Available BASE OILS, | | | HIGHLY REFINED | | | (IP346 | | | DMSO Extracts | | | <3%) | | | GRAPHITE |> 2,000 mg/kg | |No Information | | |Available PETROLEUM RESINS|7,000 mg/kg | |No Information | | |Available OCTADECANOIC |No Information |No Information |No Information ACID, |Available |Available |Available 12-HYDROXY-, | | | CALCIUM & | | | LITHIUM SALTS | | | (3159-62-4 & | | | 7620-77-1) | | | SILICA, |N/A. |N/A. |N/A. CRYSTALLINE | | | (QUARTZ FROM | | | NATURAL | | | GRAPHITE) | | | | | | Chronic Toxicity| Chemical Name |ACGIH |IARC |NTP |OSHA | | | | | | | | Target Organ Effects 12. ECOLOGICAL INFORMATION Ecotoxicity: There is no ecological data on the product itself. The Environmental impact of this product has been fully investigated Chemical Name|Toxicity to |Toxicity to |Tox, to |Daphnia Magna |Algea |Fish |Microorganisms|(water flea) | | | | | | | | | | | | Notes: ECOLOGICAL INFORMATION: There is no ecological data on the product itself. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Spilled material, unused contents and empty containers must be disposed of in accordance with local, state and federal regulations. Contaminated Packaging US EPA Waste number Notes 14. TRANSPORTATION INFORMATION DOT UN-Number | Proper Shipping name|Not regulated. Hazard Class | Packing Group | Description | Emergency Response | Guide Number | TDG UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | MEX | UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | ICAO UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | IATA: Not regulated. UN-Number | Proper Shipping name| Hazard Class | Packing Group | ERG Code | Description | IMDG/IMO: Not regulated. UN-Number | Proper Shipping name| Hazard Class | Packing Group | EmS No. | Description | RID UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADR UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADN UN-Number Proper Shipping name Hazard Class Packing Group Classification Code Special Provisions Description Hazard Labels Limited Quantity 15. REGULATORY INFORMATION International Inventories TSCA: All components in this product are listed on the US Toxic Substances Control Act (TSCA) Inventory or are exempt from TSCA Inventory requirements. DSL: All components in this product are listed on the Canada Domestic Substances List (DSL) or are exempt from DSL requirements. EINECS: All components in this product are listed on the European Inventory of New and Existing Chemical Substances (EINECS), the European LIst of Notified Chemical Substances (ELINCS), or the No Longer Polymers (NLP) list, or are exempt from EU listing requirements. ENCS: All components in this product are listed on the Japan Inventory of Existing and New Chemical Substances (ENCS) or are exempt from ENCS requirements. IECSC: All components in this product are listed on the China Inventory of Existing Chemical Substances (IECS) or are exempt from IECS requirements. PICCS: All components in this product are listed on the Philippines Inventory of Chemicals and Chemical Substances (PICCS) or are exempt from PICCS requirements. AICS: All components in this product are listed on the Australian Inventory of Chemical Substances (AICS) or are exempt from AICS requirements. U.S. Federal Regulations: COMPONENT SARA 302 CERCLA SARA 313 LUBRICATING OILS, PETROLEUM, BASE OILS, HIGHLY REFINED (IP346 DMSO No No No Extracts <3%) GRAPHITE No No No PETROLEUM RESINS No No No OCTADECANOIC ACID, 12-HYDROXY-, CALCIUM & LITHIUM SALTS (3159-62-4 & 7620-77-1) No No No MOLYBDENUM SULFIDE (MoS2) No No No SILICA, CRYSTALLINE (QUARTZ FROM NATURAL GRAPHITE) No No No SARA 313 SARA 311/312 Hazard Categories: None. Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act CERCLA U.S. State Regulations: COMPONENT CA MA FL MN NJ PA RI LUBRICATING OILS, PETROLEUM, BASE OILS, HIGHLY REFINED (IP346 DMSO Extracts <3%) No No No No No No No GRAPHITE No No No No Yes Yes No PETROLEUM RESINS No No No No No No No MOLYBDENUM SULFIDE (MoS2) No No Yes No No No No SILICA, CRYSTALLINE (QUARTZ FROM NATURAL GRAPHITE) C No No No Yes Yes No STATE REGULATORY STATUS CALIFORNIA PROPOSITION 65: This product may contain the following chemical(s) considered by the State of California's Safe Drinking Water and Toxic Enforcement Act of 1986 as causing cancer or reproductive toxicity, and for which warnings are now required: Crystalline silica, cancer hazard, CAS# 14808-60-7, see sec. #2. U.S. State Right-to-Know Regulations International Regulations: GLOBAL INVENTORIES COMPONENT CAN US EU AUS JAP KOR PHLP CHN SILICA, CRYSTALLINE (QUARTZ FROM NATURAL GRAPHITE) DSL Yes EINECS Yes Yes Yes Yes Yes LUBRICATING OILS, PETROLEUM, BASE OILS, HIGHLY REFINED (IP346 DMSO Extracts <3%) DSL Yes EINECS Yes Yes Yes Yes Yes GRAPHITE DSL Yes EINECS Yes Exmpt Yes Yes Yes PETROLEUM RESINS DSL Yes EINECS Yes Yes Yes Yes Yes OCTADECANOIC ACID, 12-HYDROXY-, CALCIUM & LITHIUM SALTS (3159-62-4 & 7620-77-1) DSL Yes EINECS Yes Yes Yes Yes Yes MOLYBDENUM SULFIDE (MoS2) DSL Yes EINECS Yes PRTR1 Yes Yes Yes Canada: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHMIS This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION Prepared By: Chemtool Incorporated Revision Date: 2010-01-20 Company: Chemtool Incorporated Revision number Telephone number: (800) 424-9300, (703) 527-3887 Notes Other Information Disclaimer information: While the information and recommendations set forth herein are believed to be accurate as of the date thereof, the company makes no warranty with respect thereto and disclaims all liability from reliance therein. END OF MATERIAL SAFETY DATA SHEET
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.