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SDS Sheet 0067190Printer Friendly View
Safety Data Sheet Date of Issue: |Revision Date: 21-Sep-2015 |Revision Number: 1 Imperial Supplies Part Number: 0067190 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: SPRAY SEALANT 9.25 OZ CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Aerosol Sealant 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Phone: 1-87-Permatex (877) 376-2839 1.4. Emergency Telephone Number Emergency | Chem - Tel: 800-255-3924 International Emergency: number |00+1+813-248-0585, Contract Number:MIS0003453 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2 damage/eye | irritation | Specific |Category 3 target organ | toxicity | (single | exposure) | Specific |Category 1 target organ | toxicity | (repeated | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark Hazard Statements (GHS-US) |Causes skin irritation |Causes serious eye irritation |Suspected of damaging fertility or the unborn child |May cause drowsiness or dizziness |Causes damage to organs through prolonged or |repeated exposure |May be fatal if swallowed and enters airways |Extremely flammable aerosol Precautionary Statements |Prevention: (GHS-US) |Obtain special instructions before use |Do not handle until all safety precautions have been |read and understood |Use personal protective equipment as required |Wash face, hands and any exposed skin thoroughly |after handling |Wear eye/ face protection |Do not breathe dust/fume/gas/mist/vapors/spray |Do not eat, drink, or smoke when using this product |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No SMOKING |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use |Response |IF exposed or concerned: Get medical/advice |attention |Specific treatment (see supplemental first aid |instructions on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water |If skin irriation occurs: get medical |advice/attention |Take off contaminated clothing and wash before reuse | |IF INHALED: Remove victim to fresh air and keep at |rest in a postion comfortable for breathing |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |Storage |Store locked up |Protect from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F |Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Not applicable - Toxic to aquatic life with long lasting effects. - The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1% w/w 1,3-butatadiene (EINECS No. 203-450-8). If the substance is not classified as a carcinogen or mutagen, at least the S-phrases (2-)9-16(Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3. 2.4. Unknown Acute Toxicity (GHS-US) 15.2% of the mixture consists of ingredient(s) of unknown toxicity SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) ACETONE |67-64-1 |15 - 40 | | |Trade | | |Secret* | TOLUENE |108-88-3 |10 - 30 | | |Trade | | |Secret* | SOLVENT NAPHTHA (PETROLEUM), |64742-88-7 |7 - 13 | MEDIUM ALIPH. | |Trade | | |Secret* | 2-PROPANOL |67-63-0 |7 - 13 | | |Trade | | |Secret* | PROPANE |74-98-6 |5 - 10 | | |Trade | | |Secret* | BUTANE |106-97-8 |5 - 10 | | |Trade | | |Secret* | XYLENE |1330-20-7 |1 - 5 | | |Trade | | |Secret* | N-HEXANE |110-54-3 |<3 Trade| | |Secret* | ETHYL BENZENE |100-41-4 |0.1-1 | | |Trade | | |Secret* | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Get medical advice/attention if you feel unwell. Self protection of the first aider: Use personal protective equipment as required. Avoid contact with skin, eyes, or clothing. First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. First-aid Measures After Skin Contact: IF ON SKIN: Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothes before reuse. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: IF SWALLOWED: Call a physician or poison control center immediately. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See section 2 for more information Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Note to physicians: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Carbon dioxide (CO2), Dry chemical, Foam Unsuitable Extinguishing Media: None. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable. Contents under pressure and can explode when exposed to heat or flames. Explosion Hazard: Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: None. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Firefighting Instructions: Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment as required. Remove all sources of ignition. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes, or clothing. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Do not flush into surface water or sanitary sewer system. See section 12 for additional ecological information. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal/ Prevention of secondary hazards: Clean contaminated objects and areas thoroughly observing environmental regulations. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Protect from sunlight. Do not expose to temperatures exceeding 50Â°C/122Â°F. Store locked up. Incompatible Materials: Strong oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Name |ACGIH TLV |OSHA PEL |NIOSH IDLH ACETONE |STEL: 750ppm |TWA: 1000ppm |IDLH: 2500 ppm 67-64-1 |TWA: 500ppm |TWA: 2400 mg/m3 |TWA: 250 ppm | |(vacated) TWA: 750 |TWA: 590 mg/m3 | |PPM | | |(vacated) TWA: 1800 | | |mg/m3 | | |(vacated) STEL: 2400| | |mg/m3 The acetone | | |STEL does not apply | | |to the cellulose | | |acetate fiber | | |industry. It is in | | |effect for all other| | |sectors | | |(vacated) STEL: 1000| | |ppm | TOLUENE |TWA: 20 ppm |TWA: 200 ppm |IDLH: 500 ppm 108-88-3 | |(vacated) TWA: 100 |TWA: 100 ppm | |ppm |TWA: 375 mg/m3 | |(vacated) TWA: 375 |STEL: 150 ppm | |mg/m3 |STEL: 560 mg/m3 | |(vacated) STEL: 150 | | |ppm | | |(vacated) STEL: 560 | | |mg/m3 | | |Ceiling: 300 ppm | 2-PROPANOL |STEL: 400 ppm |TWA: 400 ppm |IDLH: 2000 ppm 67-63-0 |TWA: 200 ppm |TWA: 980 mg/m3 |TWA: 400 ppm | |(vacated) TWA: 400 |TWA: 980 mg/m3 | |ppm |STEL: 500 ppm | |vacated) TWA: 980 |STEL: 1225 mg/m3 | |mg/m3 | | |(vacated) STEL: 500 | | |ppm | | |(vacated) STEL: 1225| | |mg/m3 | PROPANE |TWA: 1000 ppm |TWA: 1000 ppm |IDLH: 2100 ppm 74-98-6 | |TWA: 1800 mg/m3 |TWA: 1000 ppm | |(vacated) TWA: 1000 |TWA: 1800 mg/m3 | |ppm | | |(vacated) TWA: 1800 | | |mg/m3 | BUTANE |STEL: 1000 ppm |(vacated) TWA: 800 |TWA: 800 ppm 106-97-8 | |ppm |TWA: 1900 mg/m3 | |(vacated) TWA: 1900 | | |mg/m3 | XYLENE |STEL: 150 ppm |TWA: 100 ppm |- 1330-20-7 |TWA: 100 ppm |TWA: 435 mg/m3 | | |(vacated) TWA: 100 | | |ppm | | |(vacated) TWA: 435 | | |mg/m3 | | |(vacated) STEL: 150 | | |ppm | | |(vacated) STEL: 655 | | |mg/m3 | N-HEXANE |TWA: 50 ppm |TWA: 500 ppm |IDLH: 1100 ppm 110-54-3 |S* |TWA: 1800 mg/m3 |TWA: 50 ppm | |(vacated) TWA: 50 |TWA: 180 mg/m3 | |ppm | | |(vacated) TWA: 180 | | |mg/m3 | ETHYL BENZENE |TWA: 20 ppm |TWA: 100 ppm |IDLH: 800 ppm 100-41-4 | |TWA: 435 mg/m3 |TWA: 100 ppm | |(vacated) TWA: 100 |TWA: 435 mg/m3 | |ppm |STEL: 125 ppm | |(vacated) TWA: 435 |STEL: 545 mg/m3 | |mg/m3 | | |(vacated) STEL: 125 | | |ppm | | |(vacated) STEL: 545 | | |mg/m3 | 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Skin and Body Protection: Wear protective gloves and |protective clothing. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection | Respiratory Protection |Use NIOSH-approved air-purifying respirator with |organic vapor cartridge or canister, as approrpriate Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid, Aerosol Appearance |Clear Odor |Solvent Odor Threshold |No information available pH |No information available Relative Evaporation Rate |>1 Ether = 1 (butylacetate=1) | Melting Point | Freezing Point | Boiling Point |<-18 - 201Â°C/ <0 -395 Flash Point |<-18Â°C/<0Â°F Gives a flame projection at full |valve opening or flashback at any degree of |valve opening Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |36 psi@ 21Â°C Relative Vapor Density at 20 Â°C |> 1.0 Air+1 Relative Density |0.77 Specific Gravity | Solubility |No information available Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |1.0% Upper Flammable Limit |12.8% 9.2. Other Information Softening point: No information available Molecular weight: No information available VOC Content (%): 54.37% Density: No information available Bulk density: No information available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Heat, flames and sparks. Temperatures >50 Â°C / 122 Â°F. 10.5 Incompatible Materials Strong oxidizing agents 10.6 Hazardous Decomposition Products Carbon oxides SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Harmful by inhalation. Symptoms/Injuries After Skin Contact: May cause skin irritation and/or dermatitis. Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Symptoms/Injuries After Ingestion: Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chronic Symptoms: Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 4525 mg/kg ATEmix (dermal) 8568 mg/kg ATEmix (inhalation-gas) 1796133 mg/l ATEmix (inhalation-dust/mist) 20.5 mg/l ATEmix (inhalation-vapor) 2035200 mg/l SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 30.2 % of the mixture consists of components(s) of unknown hazards to the aquatic environment 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil No information available. Chemical Name |Partition Coefficient ACETONE |-0.24 67-64-1 | TOLUENE |2.65 108-88-3 | 2-PROPANOL |0.05 67-63-0 | PROPANE |2.3 74-98-6 | BUTANE |2.89 106-97-8 | XYLENE |2.77 - 3.55 1330-20-7 | ETHYL BENZENE |3.118 100-41-4 | 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Additional Information: Contaminated packaging: Do not reuse container. US EPA Waste Number: D001 SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes | | ERG Number |126 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 Identification Number|UN 1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Consumer commodity Identification Number|UN 8000 |<PICTOGRAM PHRASE> Hazard Class |9 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |9L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances TOLUENE 108-88-3 1000 lb X X X XYLENE 1330-20-7 100 lb - - - ETHYL BENZENE 100-41-4 1000 lb X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302). Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ TOLUENE 108-88-3 1 lb - RQ 1 lb final RQ RQ 0.454 kg final RQ XYLENE 1330-20-7 100 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ N-HEXANE 110-54-3 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ ETHYL BENZENE 100-41-4 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ SARA Section 311/312 Hazard Classes |Acute health hazard: Yes |Chronic Health Hazard: Yes |Fire hazard: Yes |Sudden release of pressure hazard: No |Reactive Hazard: No Toxic Substances Control Act (TSCA) |Complies 15.2 US State Regulations <COMPONENT> SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federa Regulations, Part 372. Chemical Name SARA 313 - Threshold Values % TOLUENE - 108-88-3 1.0 2-PROPANOL - 67-63-0 1.0 XYLENE - 1330-20-7 1.0 N-HEXANE - 110-54-3 1.0 ETHYL BENZENE - 100-41-4 0.1 California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 TOLUENE - 108-88-3 Developmental Female Reproductive ETHYL BENZENE - 100-41-4 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ACETONE 67-64-1 X X X TOLUENE 108-88-3 X X X SOLVENT NAPHTHA (PETROLEUM), MEDIUM ALIPH. 64742-88-7 X - - 2-PROPANOL 67-63-0 X X X PROPANE 74-98-6 X X X BUTANE 106-97-8 X X X XYLENE 1330-20-7 X X X N-HEXANE 110-54-3 X X X ETHYL BENZENE 100-41-4 X X X U.S. EPA Label Information: EPA Pesticide Registration Number Not applicable. WHMIS Hazard Class B2 - Flammable liquid D2A - Very toxic materials D2B - Toxic materials SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |21-Sep-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.