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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: MULTI-KILL FLYING INSECT KILLER CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Insecticide 1.3. Name, Address, and Telephone of the Responsible Party Company Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Phone: 1-630-543-7600 1.4. Emergency Telephone Number Emergency | 1-866-836-8855, 1-952-852-4646 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Hazardous to |Category 1 the aquatic | environment, | acute hazard | Hazardous to |Category 1 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Environment Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Very toxic to aquatic |life. Very toxic to aquatic life with long lasting |effects. Precautionary Statements |Prevention (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. Do not spray on an open flame or other |ignition source. Pressurized container: Do not |pierce or burn, even after use. Avoid release to the |environment. |Response |Collect spillage. |Storage |Protect from sunlight. Do not expose to temperatures |exceeding 50�C/122�F. |Disposal |Dispose of contents/container in accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 2.4. Unknown Acute Toxicity (GHS-US) Supplemental information: 20.78% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 20.78% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Butane |106-97-8 |10 - 20 | Petroleum distillates, |64742-47-8 |2.5 - 10| hydrotreated light | | | Propane |74-98-6 |2.5 - 10| Piperonyl Butoxide |51-03-6 |0.1 - 1 | Prallethrin |23031-36-9 |0.1 - 1 | Other components below | |60 - 80 | reportable levels | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. First-aid Measures After Inhalation: Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Call a physician or Poison Control Center immediately. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician if symptoms develop or persist. First-aid Measures After Skin Contact: Take off immediately all contaminated clothing. Remove and isolate contaminated clothing and shoes. Immediately flush skin with plenty of water. Call a physician or Poison Control Center immediately. Get medical attention if irritation develops and persists. For minor skin contact, avoid spreading material on unaffected skin. Wash clothing separately before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO NOT delay irrigation or attempt to remove the lens. Continue rinsing. Call a physician or Poison Control Center immediately. First-aid Measures After Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse mouth thoroughly. Never give anything by mouth to a victim who is unconscious or is having convulsions. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. Fire may produce irritating, corrosive and/or toxic gases. Extremely flammable aerosol. Explosion Hazard: Specific methods: Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers exposed to flames with water until well after the fire is out. In the event of fire and/or explosion do not breathe fumes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighters should wear full protective clothing including self contained breathing apparatus. Structural firefighters protective clothing will only provide limited protection. Firefighting Instructions: In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Some of these materials, if spilled, may evaporate leaving a flammable residue. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Consider initial downwind evacuation for at least 500 meters (1/3 mile). Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Refer to attached safety data sheets and/or instructions for use. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Methods for Cleaning Up: Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. This material and its container must be disposed of as hazardous waste. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Vapors may form explosive mixtures with air. May be ignited by open flame. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not breathe mist or vapor. Do not get this material in contact with eyes. Do not get this material in contact with skin. Avoid prolonged exposure. Do not get this material on clothing. Do not use in areas without adequate ventilation. Wear appropriate personal protective equipment. Wash thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For additional information on equipment bonding and grounding, refer to the Canadian Electrical Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National Fire Protection Association (NFPA) 70, "National Electrical Code". Hygiene Measures: Do not get in eyes. When using, do not eat, drink or smoke. Do not get this material in contact with skin. Avoid contact with skin. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 1 Aerosol. Keep locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50�C/122 �F. The pressure in sealed containers can increase under the influence of heat. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Refrigeration recommended. Keep away from food, drink and animal feedingstuffs. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). Level 1 Aerosol (NFPA 30B). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Propane (CAS 74-98-6) PEL 1800 mg/m3 1000 ppm US. ACGIH Threshold Limit Values Components Type Value Butane (CAS 106-97-8) STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Butane (CAS 106-97-8) TWA 1900 mg/m3 800 ppm Propane (CAS 74-98-6) TWA 1800 mg/m3 1000 ppm Biological limit values: No biological exposure limits noted for the ingredient(s). 8.2. Exposure Controls Appropriate Engineering |Provide adequate ventilation. Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear appropriate chemical resistant gloves. Eye Protection |Wear tight-fitting goggles or face shield. Wear |safety glasses with side shields (or goggles). Skin and Body Protection |Other: Wear chemical protective equipment that is |specifically recommended by the manufacturer. It may |provide little or no thermal protection. Respiratory Protection |If permissible levels are exceeded use NIOSH |mechanical filter / organic vapor cartridge or an |air-supplied respirator. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance |Clear. Odor |Odorless. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |166.8 �F (74.89 �C) estimated Flash Point |-156.0 �F (-104.4 �C) Propellant estimated Auto-ignition Temperature |456.8 �F (236 �C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |25.7 psig @70F estimated Relative Vapor Density at 20 �C | Relative Density |Not available. Specific Gravity |0.808 estimated Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |Not available. Upper Flammable Limit |Not available. 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Risk of ignition. Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions Hazardous polymerization does not occur. 10.4 Conditions to Avoid Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. Nitrates. Fluorine. Chlorine. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. Serious Eye Damage/Irritation: Harmful in contact with eyes. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: Risk of cancer cannot be excluded with prolonged exposure. IARC Monographs. Overall Evaluation of Carcinogenicity: Piperonyl Butoxide (CAS 51-03-6) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): Not classified. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Not available. Symptoms/Injuries After Inhalation: No adverse effects due to inhalation are expected. Skin. Symptoms/Injuries After Skin Contact: No adverse effects due to skin contact are expected. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Expected to be a low ingestion hazard. Chronic Symptoms: Hazardous by OSHA criteria. Repeated absorption may cause disorder of central nervous system, liver, kidneys and blood. Prolonged exposure may cause chronic effects. Further information: Symptoms may be delayed. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Very toxic to aquatic life with long lasting effects. Product Species Test Results MULTI-KILL FLYING INSECT KILLER (CAS Mixture) Aquatic Algae IC50 Algae 13388 mg/L, 72 Hours Crustacea EC50 Daphnia 72278 mg/L, 48 Hours Fish LC50 Fish 541 mg/L, 96 Hours Components Species Test Results Petroleum distillates, hydrotreated light (CAS 64742-47-8) Aquatic Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 2.9 mg/l, 96 hours Piperonyl Butoxide (CAS 51-03-6) Aquatic Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 0.0027 - 0.0043 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. Partition coefficient n-octanol / water (log Kow) Butane 2.89 2.89 Piperonyl Butoxide 4.75 4.75 Propane 2.36 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. This material and its container must be disposed of as hazardous waste. Incinerate the material under controlled conditions in an approved incinerator. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: D001: Waste Flammable material with a flash point <140 F. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable Hazard Class |2.1 |<PICTOGRAM PHRASE> | |[pic] Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes |2.1 |<PICTOGRAM PHRASE> ntification Of The | |[pic] Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable Identification Number|UN1950 |<PICTOGRAM PHRASE> | |[pic] Hazard Class |2.1 | Label Codes |2.1 | ntification Of The | | Substance/m | | ERG Code (IATA) |Yes |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Pesticides are exempt from TSCA. All components are on the U.S. EPA TSCA Inventory List. CERCLA Hazardous Substance List (40 CFR 302.4): Not listed. SARA 304 Emergency release notification: Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. SARA 302 Extremely hazardous substance: Not listed. SARA 313 (TRI reporting): Chemical name CAS number % by wt. Piperonyl Butoxide 51-03-6 0.1 - 1 Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - No |Delayed Hazard - No |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. Massachusetts RTK - Substance List: Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act: Butane (CAS 106-97-8) Piperonyl Butoxide (CAS 51-03-6) Propane (CAS 74-98-6) US. Pennsylvania Worker and Community Right-to-Know Law: Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. Rhode Island RTK: Butane (CAS 106-97-8) Piperonyl Butoxide (CAS 51-03-6) Propane (CAS 74-98-6) US. California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.