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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: I-Chem Battery Cleaner Protectant 16net15 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Phone: 404-352-1680 1.4. Emergency Telephone Number Emergency |For SDS Information: number |Compliance Services 1-877-428-9937 |For a Medical Emergency: |877-541-2016 Toll Free - All Calls Recorded |For a Transportation Emergency: |CHEMTREC: 800-424-9300 - All Calls Recorded. |In the District of Columbia 202-483-7616 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Gases under |Liquefied gas pressure | Skin corrosion|Category 1A Serious eye |Category 1 damage | Skin |Category 1 sensitisation | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas Cylinder |Corrosion |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H280 Contains gas under pressure; may explode if |heated. |H314 Causes severe skin burns and eye damage. |H317 May cause an allergic skin reaction. Precautionary Statements |Prevention: (GHS-US) |P260 Do not breathe dust or mist. |P264 Wash skin thoroughly after handling. |P272 Contaminated work clothing should not be |allowed out of the workplace. |P280 Wear protective gloves/ protective clothing/ |eye protection/ face protection. | |Response: |P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT |induce vomiting. |P303 + P361 + P353 IF ON SKIN (or hair): Remove/ |Take off immediately all contaminated clothing. |Rinse skin with water/ shower. |P304 + P340 + P310 IF INHALED: Remove victim to |fresh air and keep at rest in a position comfortable |for breathing. Immediately call a POISON CENTER or |doctor/ physician. |P305 + P351 + P338 + P310 IF IN EYES: Rinse |cautiously with water for several minutes. Remove |contact lenses, if present and easy to do. Continue |rinsing. Immediately call a POISON CENTER or doctor/ |physician. |P333 + P313 If skin irritation or rash occurs: Get |medical advice/ attention. |P363 Wash contaminated clothing before reuse. | |Storage: |P405 Store locked up. |P410 + P403 Protect from sunlight. Store in a |well-ventilated place. | |Disposal: |P501 Dispose of contents/container in accordance |with local regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Butane |106-97-8 |>= 1 - <| | |5 | Sodium carbonate |497-19-8 |>= 1 - <| | |5 | Alcohols, C9-11, ethoxylated |68439-46-3 |>= 1 - <| | |5 | Propane |74-98-6 |>= 1 - <| | |5 | 2-Diethylaminoethanol |100-37-8 |>= 0.1 -| | |< 1 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. First-aid Measures After Inhalation: If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. First-aid Measures After Skin Contact: Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. First-aid Measures After Eye Contact: Small amounts splashed into eyes can cause irreversible tissue damage and blindness. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes. First-aid Measures After Ingestion: Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Take victim immediately to hospital. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water spray Carbon dioxide (CO2) Dry powder Foam Unsuitable Extinguishing Media: High volume water jet 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Do not allow run-off from fire fighting to enter drains or water courses. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Emergency Procedures: 6.2. Environmental Precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Methods for Cleaning Up: Sweep up or vacuum up spillage and collect in suitable container for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Do not breathe vapours or spray mist. Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 �C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Observe label precautions. Keep in a dry, cool and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid: Oxidizing agents. Do not store near acids. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Butane 106-97-8 TWA 800 ppm 1,900 mg/m3 NIOSH REL TWA 800 ppm 1,900 mg/m3 OSHA P0 Propane 74-98-6 TWA 1,000 ppm ACGIH TWA 1,000 ppm 1,800 mg/m3 NIOSH REL TWA 1,000 ppm 1,800 mg/m3 OSHA Z-1 TWA 1,000 ppm 1,800 mg/m3 OSHA P0 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |The suitability for a specific workplace should be |discussed with the producers of the protective |gloves. Eye Protection |Eye wash bottle with pure water. Tightly fitting |safety goggles. Wear face-shield and protective suit |for abnormal processing problems. Skin and Body Protection |Impervious clothing. Choose body protection |according to the amount and concentration of the |dangerous substance at the work place. Respiratory Protection |In case of insufficient ventilation, wear suitable |respiratory equipment. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Aerosol containing a liquefied gas Odor |amine-like Odor Threshold | pH |11.8 - 12.4 Relative Evaporation Rate |no data available (butylacetate=1) | Melting Point |no data available Freezing Point |no data available Boiling Point |no data available Flash Point |no data available Auto-ignition Temperature |not determined Decomposition Temperature | Flammability (solid, gas) | Vapor Pressure |no data available Relative Vapor Density at 20 �C |1.038 g/cm3 Relative Density | Specific Gravity | Solubility |Completely soluble (Water) Partition coefficient: |no data available n-octanol/water | Viscosity |no data available Lower Flammable Limit |no data available Upper Flammable Limit |no data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Vapours may form explosive mixture with air. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials Acids Strong oxidizing agents 10.6 Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Product: Acute oral toxicity: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: butane: Acute inhalation toxicity: LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 1,355 mg/l sodium carbonate: Acute oral toxicity: LD50 Oral rat: 4,090 mg/kg Acute inhalation toxicity: LC50 rat: 5,750 mg/l Exposure time: 2 h Alcohols, C9-11, ethoxylated: Acute oral toxicity: LD50 Oral rat: 1,400 mg/kg propane: Acute inhalation toxicity: LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 658 mg/l Exposure time: 4 h LC50 rat: 1,355 mg/l Skin Corrosion/Irritation: Remarks: Extremely corrosive and destructive to tissue. Serious Eye Damage/Irritation: Remarks: May cause irreversible eye damage. Respiratory or Skin Sensitization: Remarks: Causes sensitisation. Germ Cell Mutagenicity: no data available Carcinogenicity: no data available Reproductive Toxicity: no data available. butane: sodium carbonate: Alcohols, C9-11, ethoxylated: propane: 2-diethylaminoethanol: Specific Target Organ Toxicity (Single Exposure): no data available Specific Target Organ Toxicity (Repeated Exposure): no data available Aspiration Hazard: no data available Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity no data available 12.2. Persistence and Degradability no data available 12.3. Bioaccumulative Potential Product: Partition coefficient: n-octanol/water : Remarks: no data available Components: Components: butane : Partition coefficient: n-octanol/water : Pow: 2.89 12.4. Mobility in Soil no data available 12.5. Other Adverse Effects no data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information: no data available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, NON-FLAMMABLE Hazard Class |2.2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, NON-FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.2 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes |Sudden Release of Pressure Hazard |Acute Health Hazard Toxic Substances Control Act (TSCA) |On TSCA Inventory 15.2 US State Regulations California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |04/30/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.