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Safety Data Sheet Date of Issue: 02-28-2014 |Revision Date: 03-21-2014 |Revision Number: 02 Imperial Supplies Part Number: 0066920 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: Clean-R-Carb Carburetor Cleaner (50 State Formula) CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Carburetor cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company: CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168 1.4. Emergency Telephone Number Emergency | 800-424-9300 (US), 703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Gases under |Compressed gas pressure | Serious eye |Category 2A damage/eye | irritation | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 2 the aquatic | environment, | acute hazard | Hazardous to |Category 3 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas |Health |Exclamat| | | |Cylinder|Hazard |ion Mark| | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Contains gas under |pressure; may explode if heated. May be fatal if |swallowed and enters airways. Causes serious eye |irritation. May cause drowsiness or dizziness. Toxic |to aquatic life. Harmful to aquatic life with long |lasting effects. Precautionary Statements |Prevention (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. Do not spray on an open flame or other |ignition source. Pressurized container: Do not |pierce or burn, even after use. Extinguish all |flames, pilot lights and heaters. Vapors will |accumulate readily and may ignite. Use only with |adequate ventilation; maintain ventilation during |use and until all vapors are gone. Open doors and |windows or use other means to ensure a fresh air |supply during use and while product is drying. If |you experience any symptoms listed on this label, |increase ventilation or leave the area. Avoid |breathing mist or vapor. Avoid breathing gas. Wear |eye/face protection. Wash hands thoroughly after |handling. Avoid release to the environment. |Response |If swallowed: Immediately call a poison |center/doctor. Do NOT induce vomiting. If inhaled: |Remove person to fresh air and keep comfortable for |breathing. Call a poison center/doctor if you feel |unwell. If in eyes: Rinse cautiously with water for |several minutes. Remove contact lenses, if present |and easy to do. Continue rinsing. If eye irritation |persists: Get medical attention. |Storage |Store in a well-ventilated place. Store locked up. |Protect from sunlight. Do not expose to temperatures |exceeding 50�C/122�F. Exposure to high temperature |may cause can to burst. |Disposal |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Acetone |67-64-1 |80 - 90 | Carbon dioxide |124-38-9 |5 - 10 | 3-Methylhexane |589-34-4 |1 - 3 | Methylcyclohexane |108-87-2 |1 - 3 | n-Heptane |142-82-5 |1 - 3 | Cyclohexane |110-82-7 |< 1 | Specific chemical identity and/or percentage of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Rinse skin with water/shower. Get medical attention if irritation develops and persists. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause drowsiness or dizziness. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol resistant foam. Water spray. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. General fire hazards Extremely flammable aerosol. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Avoid breathing gas. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop the flow of material, if this is without risk. Collect spillage. Dike far ahead of spill for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Prevent entry into waterways, sewer, basements or confined areas. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50�C/122 �F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep out of the reach of children. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Carbon dioxide (CAS 124-38-9) PEL 9000 mg/m3 5000 ppm Cyclohexane (CAS 110-82-7) PEL 1050 mg/m3 300 ppm Methylcyclohexane (CAS 108-87-2) PEL 2000 mg/m3 500 ppm n-Heptane (CAS 142-82-5) PEL 2000 mg/m3 500 ppm US. ACGIH Threshold Limit Values Components Type Value 3-Methylhexane (CAS 589-34-4) STEL TWA 500 ppm 400 ppm Acetone (CAS 67-64-1) STEL TWA 750 ppm 500 ppm Carbon dioxide (CAS 124-38-9) STEL TWA 30000 ppm 5000 ppm Cyclohexane (CAS 110-82-7) TWA 100 ppm Methylcyclohexane (CAS 108-87-2) STEL TWA 500 ppm 400 ppm n-Heptane (CAS 142-82-5) STEL 500 ppm US. ACGIH Threshold Limit Values Components Type Value TWA 400 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Acetone (CAS 67-64-1) TWA 590 mg/m3 250 ppm Carbon dioxide (CAS 124-38-9) STEL TWA 54000 mg/m3 30000 ppm 9000 mg/m3 5000 ppm Cyclohexane (CAS 110-82-7) TWA 1050 mg/m3 300 ppm Methylcyclohexane (CAS 108-87-2) TWA 1600 mg/m3 400 ppm n-Heptane (CAS 142-82-5) Ceiling TWA 1800 mg/m3 440 ppm 350 mg/m3 85 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Acetone (CAS 67-64-1) 50 mg/l Acetone Urine * 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Provide eyewash |station. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Nitrile. Polyvinyl |alcohol (PVA). Viton�. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection | Respiratory Protection |In case of insufficient ventilation, wear suitable |respiratory equipment. Air monitoring is needed to |determine actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Solvent. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Fast. (butylacetate=1) | Melting Point |-195.9 �F (-126.6 �C) estimated Freezing Point |-195.9 �F (-126.6 �C) estimated Boiling Point |132.9 �F (56.1 �C) estimated Flash Point |< 0 �F (< -17.8 �C) Tag Closed Cup Auto-ignition Temperature |539.6 �F (282 �C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |5061 hPa estimated Relative Vapor Density at 20 �C | Relative Density |0.84 estimated Specific Gravity | Solubility |(water) Slightly soluble. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |1.1 % estimated Upper Flammable Limit |12.8 % estimated 9.2. Other Information Percent volatile 91.5 % estimated VOC content (40 CFR 51.100(s)) 9.2 % VOC content (CA) 9.2 % VOC content (OTC) 9.2 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. Acids. Alkalies. Aluminum. Halogens. Peroxides. Oxygen. Amines. Ammonia. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. Repeated exposure may cause skin dryness or cracking. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): Narcotic effects. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected. Product Species Test Results Clean-R-Carb Carburetor Cleaner (50 State Formula) Acute Fish LC50 Fish 74.7831 mg/l, 96 hours estimated Components Species Test Results Acetone (CAS 67-64-1) Aquatic Crustacea EC50 Water flea (Daphnia magna) 21.6 - 23.9 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 4740 - 6330 mg/l, 96 hours (Oncorhynchus mykiss) Cyclohexane (CAS 110-82-7) Aquatic Fish LC50 Fathead minnow (Pimephales 23.03 - 42.07 mg/l, 96 hours promelas) Methylcyclohexane (CAS 108-87-2) Aquatic Fish LC50 Striped bass (Morone saxatilis) 5.8 mg/l, 96 hours n-Heptane (CAS 142-82-5) Aquatic Acute Fish LC50 Fathead minnow (Pimephales 2.1 - 2.98 mg/l, 96 hours promelas) 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Cyclohexane 3.44 Methylcyclohexane 3.61 n-Heptane 4.66 SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material and its container must be disposed of as hazardous waste. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways Additional Information: Hazardous waste code D001: Waste Flammable material with a flash point <140 F F003: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, Limited Quantity Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANT Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable, Limited Quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA 304 Emergency release notification US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) CERCLA Hazardous Substances: Reportable quantity Acetone (CAS 67-64-1) 5000 lbs Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 % weight/volumn DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - No |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |All components are on the U.S. EPA TSCA |Inventory List. |TSCA Section 12(b) Export Notification (40 |CFR 707, Subpt. D): Not regulated. 15.2 US State Regulations <COMPONENT> US. New Jersey RTK - Substances: Listed substance 3-Methylhexane (CAS 589-34-4) Acetone (CAS 67-64-1) Carbon dioxide (CAS 124-38-9) Cyclohexane (CAS 110-82-7) Methylcyclohexane (CAS 108-87-2) n-Heptane (CAS 142-82-5) US. Massachusetts RTK - Substance List 3-Methylhexane (CAS 589-34-4) Acetone (CAS 67-64-1) Carbon dioxide (CAS 124-38-9) Methylcyclohexane (CAS 108-87-2) n-Heptane (CAS 142-82-5) US. Pennsylvania RTK - Hazardous Substances 3-Methylhexane (CAS 589-34-4) Acetone (CAS 67-64-1) Carbon dioxide (CAS 124-38-9) Cyclohexane (CAS 110-82-7) Methylcyclohexane (CAS 108-87-2) n-Heptane (CAS 142-82-5) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexane (CAS 110-82-7) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Cumene (CAS 98-82-8) Listed: April 6, 2010 Ethanal (CAS 75-07-0) Listed: April 1, 1988 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |03-21-2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.