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SDS Sheet 0066860Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Heavy Duty Clear Penetrating Grease CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Penetrating grease 1.3. Name, Address, and Telephone of the Responsible Party Company; CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168 1.4. Emergency Telephone Number Emergency | 800-424-9300 (US) number |703-527-3887 (International) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Gases under |Liquefied gas pressure | Serious eye |Category 2B damage/eye | irritation | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Contains gas under |pressure; may explode if heated. Causes eye |irritation. May cause drowsiness or dizziness. Precautionary Statements |Prevention: (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. Do not spray on an open flame or other |ignition source. Do not apply while equipment is |energized. Pressurized container: Do not pierce or |burn, even after use. Extinguish all flames, pilot |lights an heaters. Vapors will accumulate readily |and may ignite. Use only with adequate ventilation; |maintain ventilation during use and until all vapors |are gone. Open doors and windows or use other means |to ensure a fresh air supply during use and while |product is drying. If you experience any symptoms |listed on this label, increase ventilation or leave |the area. Avoid breathing gas, mist or vapor. Wash |hands thoroughly after handling. |Response: |If inhaled: Remove person to fresh air and keep |comfortable for breathing. Call a poison |center/doctor if you feel unwell. If in eyes: Rinse |cautiously with water for several minutes. Remove |contact lenses, if present and easy to do. Continue |rinsing. If eye irritation persists: Get medical |attention. |Storage: |Store in a well-ventilated place. Store locked up. |Protect from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. Exposure to high temperature |may cause can to burst. |Disposal: |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Heptane, branched, cyclic and |426260-76-6 |20 - 30 | linear | | | Liquefied Petroleum Gas |68476-85-7 |20 - 30 | Polybutene |9003-29-6 |20 - 30 | Distillates (petroleum), |64742-47-8 |5 - 10 | hydrotreated light | | | Distillates (petroleum), |64742-65-0 |5 - 10 | solvent-dewaxed heavy paraffinic| | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If breathing is difficult, give oxygen. Call a POISON CENTER or doctor/physician. First-aid Measures After Skin Contact: Wash off with soap and water. Get medical attention if irritation develops and persists. Take off contaminated clothing and wash before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Do not induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Exposed individuals may experience eye tearing, redness, and discomfort. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause drowsiness or dizziness. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Foam. Dry chemicals. Carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. Explosion Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Protection During Firefighting: Wear self-contained breathing apparatus and protective clothing. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Avoid breathing gas. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Dike far ahead of spill for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Prevent entry into waterways, sewer, basements or confined areas. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact with skin and eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep out of the reach of children. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0) PEL 5 mg/m3 2000 mg/m3 500 ppm Mist. Liquefied Petroleum Gas (CAS 68476-85-7) PEL 1800 mg/m3 1000 ppm US. ACGIH Threshold Limit Values Components Type Value Form Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0) TWA 5 mg/m3 Inhalable fraction. US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form Distillates (petroleum), hydrotreated light (CAS 64742-47-8) TWA 100 mg/m3 Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0) STEL TWA 10 mg/m3 5 mg/m3 Mist. Mist. Liquefied Petroleum Gas (CAS 68476-85-7) TWA 1800 mg/m3 1000 ppm 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Provide eyewash |station. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Nitrile. Neoprene. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear appropriate chemical resistant clothing. Respiratory Protection |In case of insufficient ventilation, wear suitable |respiratory equipment. Air monitoring is needed to |determine actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Characteristic. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Fast. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |175 Â°F (79.4 Â°C) Flash Point |< 20 Â°F (< -6.7 Â°C) Tag Closed Cup Auto-ignition Temperature |410 Â°F (210 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |2343.9 hPa estimated Relative Vapor Density at 20 Â°C | Relative Density |0.72 Specific Gravity | Solubility |Negligible. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |0.5 % estimated Upper Flammable Limit |6.7 % estimated 9.2. Other Information VOC content (40 CFR 51.100(s)): 73 % VOC content (CA) 45 % VOC content (OTC) 45 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. Amines. Chlorine. Nitric plus acetic acids. Nitric plus sulfuric acids. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Narcotic effects. Causes eye irritation. Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. Serious Eye Damage/Irritation: Causes eye irritation. Respiratory or Skin Sensitization: Not available. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): Narcotic effects. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: If aspirated (liquid enters the lungs), it may be rapidly absorbed through the lungs and result in injury to other body systems. May also cause gastro-intestinal distress. Symptoms/Injuries After Inhalation: Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Prolonged or excessive inhalation may cause respiratory tract irritation. Symptoms/Injuries After Skin Contact: Prolonged contact may cause irritation and defatting of skin. Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Expected to be a low ingestion hazard. Chronic Symptoms: Prolonged inhalation may be harmful. Repeated and prolonged overexposure to solvents may lead to permanent brain and nervous system damage. Eye watering, headaches, nausea, dizziness, and loss of coordination are signs that solvent levels are too high. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Product Species Test Results Heavy Duty Clear Penetrating Grease Acute Crustacea EC50 Daphnia 5000 mg/l, 48 hours estimated Fish LC50 Fish 3452.6113 mg/l, 96 hours estimated Components Species Test Results Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Acute EC50 Invertebrate (saltwater) 4720 mg/l, 96 hours Aquatic Acute Fish LC50 Bluegill (Lepomis macrochirus) 1740 mg/l, 96 hours Fathead minnow (Pimephales promelas) 45 mg/l, 96 hours Polybutene (CAS 9003-29-6) Acute Crustacea EC50 Daphnia > 1000 mg/l, 48 hours Fish LC50 Fish > 1000 mg/l, 96 hours (similar material) 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material and its container must be disposed of as hazardous waste. If discarded, this product is considered a RCRA ignitable waste, D001. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Empty container can be recycled. Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, Limited Quantity Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |Not available. | EmS-No. (Spillage) |Not available. | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable, Limited Quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. SARA 304 Emergency release notification: Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance: Not listed. CERCLA Hazardous Substance List (40 CFR 302.4): Not listed. CERCLA Hazardous Substances: Reportable quantity: Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - No |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. New Jersey RTK - Substances: Listed substance Liquefied Petroleum Gas (CAS 68476-85-7) US. Massachusetts RTK - Substance List Liquefied Petroleum Gas (CAS 68476-85-7) US. Pennsylvania RTK - Hazardous Substances Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Liquefied Petroleum Gas (CAS 68476-85-7) US. Rhode Island RTK: None. US. California Proposition 65: California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.