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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 3-36Â® Multi-Purpose Lubricant & Corrosion Inhibitor CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Multi-purpose lubricant 1.3. Name, Address, and Telephone of the Responsible Party Company: CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168 1.4. Emergency Telephone Number Emergency |800-424-9300 (US), 703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Gases under |Compressed gas pressure | Skin |Category 2 corrosion/irri| tation | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 2 the aquatic | environment, | acute hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Contains gas under |pressure; may explode if heated. May be fatal if |swallowed and enters airways. Causes skin |irritation. May cause drowsiness or dizziness. Precautionary Statements |Prevention: (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. Do not spray on an open flame or other |ignition source. Do not apply while equipment is |energized. Pressurized container: Do not pierce or |burn, even after use. Extinguish all flames, pilot |lights and heaters. Vapors will accumulate readily |and may ignite. Use only with adequate ventilation; |maintain ventilation during use and until all vapors |are gone. Open doors and windows or use other means |to ensure a fresh air supply during use and while |product is drying. If you experience any symptoms |listed on this label, increase ventilation or leave |the area. Avoid breathing gas, mist or vapor. Wear |protective gloves. Wash hands thoroughly after |handling. |Response : |If swallowed: Immediately call a poison |center/doctor. Do NOT induce vomiting. If on skin: |Wash with plenty of water. If skin irritation |occurs: Get medical attention. Take off contaminated |clothing and wash before reuse. If inhaled: Remove |person to fresh air and keep comfortable for |breathing. Call a poison center/doctor if you feel |unwell. |Storage : |Store in a well-ventilated place. Store locked up. |Protect from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. Exposure to high temperature |may cause can to burst. |Disposal: |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Distillates (petroleum), |64742-47-8 |60 - 70 | Hydrotreated Light | | | Distillates (petroleum), |64741-88-4 |10 - 20 | Solvent-refined Heavy Paraffinic| | | n-Butyl stearate |123-95-5 |3 - 5 | Carbon dioxide |124-38-9 |1 - 3 | Fatty Acids, C18-unsatd., Dimers|61788-89-4 |1 - 3 | Petrolatum |8009-03-8 |1 - 3 | d-Limonene |5989-27-5 |< 0.2 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. If you feel unwell, seek medical advice (show the label where possible). Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing. Wash off with soap and plenty of water. If skin irritation occurs: Get medical advice/attention. First-aid Measures After Eye Contact: Rinse with water. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause drowsiness or dizziness. Irritant effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol resistant foam. Water. Water spray. Dry powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. Explosion Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Use water spray to reduce vapors or divert vapor cloud drift. Following product recovery, flush area with water. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 3 Aerosol. Store in a well-ventilated place. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Keep away from heat, sparks and open flame. This material can accumulate static charge which may cause spark and become an ignition source. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters U.S. - OSHA Components Type Value Form Fatty Acids, C18-unsatd., Dimers (CAS 61788-89-4) TWA 5 mg/m3 Respirable US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Form Carbon dioxide (CAS 124-38-9) PEL 9000 mg/m3 5000 ppm Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) PEL 5 mg/m3 2000 mg/m3 500 ppm Mist. Petrolatum (CAS 8009-03-8) PEL 5 mg/m3 Mist. ACGIH Components Type Value Form Fatty Acids, C18-unsatd., Dimers (CAS 61788-89-4) STEL TWA 10 mg/m3 5 mg/m3 Respirable Respirable US. ACGIH Threshold Limit Values Components Type Value Form Carbon dioxide (CAS 124-38-9) STEL TWA 30000 ppm 5000 ppm Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) TWA 5 mg/m3 Inhalable fraction. n-Butyl stearate (CAS 123 95-5) TWA 10 mg/m3 Petrolatum (CAS 8009-03-8) TWA 5 mg/m3 Inhalable fraction. US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form Carbon dioxide (CAS 124-38-9) STEL TWA 54000 mg/m3 30000 ppm 9000 mg/m3 5000 ppm Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) TWA 100 mg/m3 Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4) STEL TWA 10 mg/m3 5 mg/m3 Mist. Mist. Petrolatum (CAS 8009-03-8) STEL TWA 10 mg/m3 5 mg/m3 Mist. Mist. US. AIHA Workplace Environmental Exposure Level (WEEL) Guides Components Type Value d-Limonene (CAS 5989-27-5) TWA 165.5 mg/m3 30 ppm 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as neoprene or nitrile. Eye Protection |Wear eye/face protection. Wear safety glasses with |side shields (or goggles). Skin and Body Protection |Wear appropriate chemical resistant clothing. Respiratory Protection |Wear positive pressure self-contained breathing |apparatus (SCBA). Air monitoring is needed to |determine actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Pleasant. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Slow (butylacetate=1) | Melting Point |-72.4 Â°F (-58 Â°C) estimated Freezing Point |-72.4 Â°F (-58 Â°C) estimated Boiling Point |380 Â°F (193.3 Â°C) estimated Flash Point |192 Â°F (88.9 Â°C) Tag Closed Cup Auto-ignition Temperature |456.8 Â°F (236 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |1431 hPa estimated Relative Vapor Density at 20 Â°C | Relative Density |0.84 estimated Specific Gravity | Solubility |Negligible. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |0.6 % estimated Upper Flammable Limit |5.5 % estimated 9.2. Other Information Percent volatile: 88.6 % estimated SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides. Sulfur oxides. Hydrocarbons. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Narcotic effects. Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: Not available. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity d-Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): Narcotic effects. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways. Chronic Symptoms: Prolonged exposure may cause chronic effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Product Species Test Results 3-36Â® Multi-Purpose Lubricant & Corrosion Inhibitor Acute Fish LC50 Fish 4916.4028 ppm, 96 hours estimated Components Species Test Results Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) Aquatic Acute Fish LC50 Bluegill (Lepomis macrochirus) 2.2 mg/l, 96 hours d-Limonene (CAS 5989-27-5) Aquatic Crustacea EC50 Water flea (Daphnia pulex) 69.6 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) 0.619 - 0.796 mg/l, 96 hours Fatty Acids, C18-unsatd., Dimers (CAS 61788-89-4) Acute Crustacea NOEL Daphnia 1000 mg/l, 48 hours loading rate WAF Fish NOEL Fish 1000 mg/l, 96 hours loading rate WAF 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national regulations. Additional Information: Contaminated packaging: Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, limited quantity Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY Hazard Class |2 Identification Number| Label Codes |UN1950 |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable, limited quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |2L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA 304 Emergency release notification: Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance: Not listed. CERCLA Hazardous Substance List (40 CFR 302.4): Not listed. CERCLA Hazardous Substances: Reportable quantity: Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - No |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. New Jersey RTK - Substances: Listed substance Carbon dioxide (CAS 124-38-9) US. Massachusetts RTK - Substance List Carbon dioxide (CAS 124-38-9) US. Pennsylvania RTK - Hazardous Substances Carbon dioxide (CAS 124-38-9) Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8) US. Rhode Island RTK: None. US. California Proposition 65: California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.