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SDS Sheet 0066760Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol Product Name: QDÂ® Electronic Cleaner CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Electronic cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168, 800-272-4620 1.4. Emergency Telephone Number Emergency | 800-424-9300 (US), 703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Gases under |Liquefied gas pressure | Skin |Category 2 corrosion/irri| tation | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 3 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Contains gas under |pressure; may explode if heated. May be fatal if |swallowed and enters airways. Causes skin |irritation. May cause drowsiness or dizziness. |Harmful to aquatic life with long lasting effects. Precautionary Statements |Prevention: (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. Do not spray on an open flame or other |ignition source. Do not apply while equipment is |energized. Pressurized container: Do not pierce or |burn, even after use. Extinguish all flames, pilot |lights and heaters. Vapors will accumulate readily |and may ignite. Use only with adequate ventilation; |maintain ventilation during use and until all vapors |are gone. Open doors and windows or use other means |to ensure a fresh air supply during use and while |product is drying. If you experience any symptoms |listed on this label, increase ventilation or leave |the area. Avoid breathing mist or vapor. Wash |thoroughly after handling. Wear protective gloves. |Avoid release to the environment. | |Response: |If swallowed: Immediately call a poison |center/doctor. Do NOT induce vomiting. If on skin: |Wash with plenty of water. If skin irritation |occurs: Get medical attention. Take off contaminated |clothing and wash before reuse. If inhaled: Remove |person to fresh air and keep comfortable for |breathing. Call a poison center/doctor if you feel |unwell. | |Storage: |Store in a well-ventilated place. Store locked up. |Protect from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. Exposure to high temperature |may cause can to burst. | |Disposal: |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting effects. 2.4. Unknown Acute Toxicity (GHS-US) 96.1% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Naphtha (petroleum), |64742-49-0 |70 - 80 | hydrotreated light | | | 1,1-Difluoroethane |75-37-6 |20 - 30 | n-Hexane |110-54-3 |3 - 5 | 2,2-Dimethylbutane |75-83-2 |< 0.2 | 2-Methylpentane |107-83-5 |< 0.2 | Specific chemical identity and/or percentage of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Rinse with water. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Symptoms/Injuries After Skin Contact: Skin irritation. May cause redness and pain. Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Aspiration may cause pulmonary edema and pneumonitis. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Explosion Hazard: Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Many vapors are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Prevent product from entering drains. Methods for Cleaning Up: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. For product usage instructions, please see the product label. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value n-Hexane (CAS 110-54-3) PEL 1800 mg/m3 500 ppm US. ACGIH Threshold Limit Values Components Type Value 2,2-Dimethylbutane (CAS 75-83-2) STEL TWA 1000 ppm 500 ppm 2-Methylpentane (CAS 107-83-5) STEL TWA 1000 ppm 500 ppm n-Hexane (CAS 110-54-3) TWA 50 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2,2-Dimethylbutane (CAS 75-83-2) Ceiling TWA 1800 mg/m3 510 ppm 350 mg/m3 100 ppm 2-Methylpentane (CAS 107-83-5) Ceiling TWA 1800 mg/m3 510 ppm 350 mg/m3 100 ppm n-Hexane (CAS 110-54-3) TWA 180 mg/m3 50 ppm US. AIHA Workplace Environmental Exposure Level (WEEL) Guides Components Type Value 1,1-Difluoroethane (CAS 75-37-6) TWA 2700 mg/m3 1000 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time n-Hexane (CAS 110-54-3) 0.4 mg/l 2,5-Hexanedion, without hydrolysis Urine * * - For sampling details, please see the source document. Exposure guidelines: US - California OELs: Skin designation n-Hexane (CAS 110-54-3): Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation n-Hexane (CAS 110-54-3): Can be absorbed through the skin. 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Nitrile. Polyvinyl |chloride (PVC). VitonÂ®. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Other: Wear appropriate chemical resistant clothing. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Alcoholic. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Very fast. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |123 Â°F (50.6 Â°C) estimated Flash Point |< 0 Â°F (< -17.8 Â°C) Tag Closed Cup Auto-ignition Temperature |489.2 Â°F (254 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |175 mmHg (68 Â°F (20 Â°C)) Relative Vapor Density at 20 Â°C |> 1 (air = 1) Relative Density |0.72 estimated Specific Gravity | Solubility |Negligible. (water) Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |1.1 % estimated Upper Flammable Limit |19 % estimated 9.2. Other Information Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)): 75 % Consumer products(40 CFR 59, Subpt. C): Not regulated State Consumer products: This product is regulated as an Electronic Cleaner. This product is compliant for use in all 50 states. VOC content (CA) 75 % VOC content (OTC) 75 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Narcotic effects. Product: QDÂ® Electronic Cleaner Acute Species Test Results Dermal LD50 Rabbit 2696 mg/kg estimated Inhalation LC50 Rat 26392 ppm, 4 hours estimated 27 mg/l, 4 hours estimated Oral LD50 Rat 19828 mg/kg estimated Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not a respiratory sensitizer. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: Risk of cancer cannot be excluded with prolonged exposure. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Symptoms/Injuries After Inhalation: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Chronic Symptoms: Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Harmful to aquatic life with long lasting effects. Product: QDÂ® Electronic Cleaner Aquatic Species Test Results Fish LC50 Fish 1553.8115 mg/l, 96 hours estimated Acute Crustacea EC50 Daphnia 1754.8054 mg/l, 48 hours estimated n-Hexane (CAS 110-54-3) Aquatic Species Test Results Fish LC50 Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/l, 96 hours 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential Partition coefficient n-octanol / water (log Kow) 1,1-Difluoroethane 0.75 2,2-Dimethylbutane 3.82 2-Methylpentane 3.74 n-Hexane 3.9 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose in accordance with all applicable regulations. Additional Information: Hazardous waste code: D001: Waste Flammable material with a flash point <140 F Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, Limited Quantity, MARINE POLLUTANT |(Hexanes) Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANT Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable, Limited Quantity Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance n-Hexane (CAS 110-54-3) CERCLA Hazardous Substance List (40 CFR 302.4) n-Hexane (CAS 110-54-3) Listed. CERCLA Hazardous Substances: Reportable quantity n-Hexane (CAS 110-54-3) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List n-Hexane (CAS 110-54-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) 1,1-Difluoroethane (CAS 75-37-6) Safe Drinking Water Act (SDWA): Not regulated. Food and Drug Administration (FDA): Not regulated. SARA 302 Extremely hazardous substance: No SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - No |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Naphtha (petroleum), hydrotreated light (CAS 64742-49-0) n-Hexane (CAS 110-54-3) US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act 1,1-Difluoroethane (CAS 75-37-6) n-Hexane (CAS 110-54-3) Ethanol (CAS 64-17-5) US. Massachusetts RTK - Substance List 1,1-Difluoroethane (CAS 75-37-6) n-Hexane (CAS 110-54-3) US. Pennsylvania Worker and Community Right-to-Know Law Isopropyl alcohol (CAS 67-63-0) Methanol (CAS 67-56-1) n-Hexane (CAS 110-54-3) US. Rhode Island RTK 1,1-Difluoroethane (CAS 75-37-6) n-Hexane (CAS 110-54-3) US. California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Methyl isobutyl ketone (CAS 108-10-1) Listed: November 4, 2011 US - California Proposition 65 - CRT: Listed date/Developmental toxin Methanol (CAS 67-56-1) Listed: March 16, 2012 Methyl isobutyl ketone (CAS 108-10-1) Listed: March 28, 2014 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.