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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol Product Name: Brakleen� Brake Parts Cleaner CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Brake cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168, 800-272-4620 1.4. Emergency Telephone Number Emergency | 800-424-9300 (US), 800-424-9300 (US), 703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Gases under |Compressed gas pressure | Skin |Category 2 corrosion/irri| tation | Carcinogenicit|Category 1B y | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Hazardous to |Category 2 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas Cylinder |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Contains gas under pressure; may explode if heated. |Causes skin irritation. May cause drowsiness or |dizziness. May cause cancer. Toxic to aquatic life |with long lasting effects. Precautionary Statements |Prevention: (GHS-US) |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Do not puncture or incinerate |container. Do not expose to heat or store at |temperatures above 49�C/120�F. Use with adequate |ventilation. Open doors and windows or use other |means to ensure a fresh air supply during use and |while product is drying. If you experience any |symptoms listed on this label, increase ventilation |or leave the area. Avoid breathing mist or vapor. |Avoid breathing gas. Wash thoroughly after handling. |Wear protective gloves/protective clothing/eye |protection/face protection. Avoid release to the |environment. |Response: |If on skin: Wash with plenty of water. If skin |irritation occurs: Get medical attention. Take off |contaminated clothing and wash before reuse. If |inhaled: Remove person to fresh air and keep |comfortable for breathing. Call a poison |center/doctor if you feel unwell. If exposed or |concerned: Get medical attention. Collect spillage. |Storage: Store locked up. Protect from sunlight. |Store in a well-ventilated place. Exposure to high |temperature may cause can to burst. |Disposal: |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen chloride and possibly phosgene. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Tetrachloroethylene |127-18-4 |90 - 100| Carbon dioxide |124-38-9 |1 - 5 | | | | | | | Specific chemical identity | | | and/or percentage of composition| | | has been withheld as a trade | | | secret. | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Rinse with water. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of eyes and mucous membranes. Irritation of nose and throat. Skin irritation. May cause redness and pain. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Dry chemical, CO2, or water spray. Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Exposure to high temperature may cause can to burst. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen chloride and possibly phosgene. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Protection During Firefighting: In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Avoid breathing gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Stop the flow of material, if this is without risk. Collect spillage. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 1 Aerosol. Contents under pressure. Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 49 �C/120 �F. Do not handle or store near an open flame, heat or other sources of ignition. Exposure to high temperature may cause can to burst. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Carbon dioxide (CAS 124-38-9) PEL 9000 mg/m3 5000 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) Components Type Value Tetrachloroethylene (CAS 127-18-4) Ceiling 200 ppm TWA 100 ppm US. ACGIH Threshold Limit Values Components Type Value Carbon dioxide (CAS 124-38-9) STEL 30000 ppm TWA 5000 ppm Tetrachloroethylene (CAS 127-18-4) STEL 100 ppm TWA 25 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Carbon dioxide (CAS 124-38-9) STEL 54000 mg/m3 30000 ppm TWA 9000 mg/m3 5000 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Tetrachloroethylene (CAS 127-18-4) 0.5 mg/l Tetrachloroethylene Blood * 3 ppm Tetrachloroethylene End-exhaled air * * - For sampling details, please see the source document. Exposure guidelines US - Minnesota Haz Subs: Skin designation applies Tetrachloroethylene (CAS 127-18-4) Skin designation applies. 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Viton�. Polyvinyl |alcohol (PVA). Nitrile. Silver Shield�. |Wear appropriate chemical resistant clothing. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Other: Wear appropriate chemical resistant clothing. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Irritating. Odor Threshold |50 ppm pH |Not available. Relative Evaporation Rate |Very fast. (butylacetate=1) | Melting Point |-8.1 �F (-22.3 �C) estimated Freezing Point |-8.1 �F (-22.3 �C) estimated Boiling Point |250.3 �F (121.3 �C) estimated Flash Point |None (Tag Closed Cup) Auto-ignition Temperature |Not available. Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |1352.4 hPa estimated Relative Vapor Density at 20 �C | Relative Density |1.62 Specific Gravity | Solubility |(water) 0.02 % (77 �F (25 �C)) Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |Not available. Upper Flammable Limit |Not available. 9.2. Other Information Partition coefficient (oil/water) : 2.88 Volatile organic compounds (VOC) regulations EPA: VOC content (40 CFR 51.100(s)): 0 % Consumer products (40 CFR 59, Subpt. C): Not regulated State Consumer products: This product is regulated as a Brake Cleaner. This product is not compliant to be sold for use in California and New Jersey. This product is compliant in all other states. VOC content (CA) 0 % VOC content (OTC) 0 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat, flames and sparks. Contact with incompatible materials. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen chloride and possibly phosgene. 10.5 Incompatible Materials Strong oxidizing agents. Strong acids. Strong bases. 10.6 Hazardous Decomposition Products Hydrogen chloride. Trace amounts of chlorine and phosgene. Carbon oxides. Halogenated materials. Carbonyl halides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Narcotic effects. Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: Not available. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: May cause cancer. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: May be an aspiration hazard. Symptoms/Injuries After Inhalation: Prolonged inhalation may be harmful. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Toxic to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected. Product: Brakleen� Brake Parts Cleaner Aquatic Species Test Results Fish LC50 Fish 19.1805 mg/l, 96 hours estimated Tetrachloroethylene (CAS 127-18-4) Aquatic Species Test Results Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 4.73 - 5.27 mg/l, 96 hours 12.2. Persistence and Degradability Not available. 12.3. Bioaccumulative Potential Not available. Partition coefficient n-octanol / water (log Kow) Tetrachloroethylene 2.88 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material and its container must be disposed of as hazardous waste. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Additional Information: Hazardous waste code D039: Waste Tetrachloroethylene F001: Waste Halogenated Solvent - Spent Halogenated Solvent Used in Degreasing F002: Waste Halogenated Solvent - Spent Halogenated Solvent US RCRA Hazardous Waste U List: Reference Tetrachloroethylene (CAS 127-18-4) U210 Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, poison, Limited Quantity, MARINE POLLUTANT Hazard Class |2.2 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes |2.2, 6.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, MARINE POLLUTANT Hazard Class |2 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, non-flammable Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |containing substances | |in Division 6.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA 304 Emergency release notification: Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance: Tetrachloroethylene (CAS 127-18-4) CERCLA Hazardous Substance List (40 CFR 302.4): Tetrachloroethylene (CAS 127-18-4) CERCLA Hazardous Substances: Reportable quantity: Tetrachloroethylene (CAS 127-18-4) 100 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Tetrachloroethylene (CAS 127-18-4) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Safe Drinking Water Act (SDWA): Not regulated. Food and Drug Administration (FDA): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - No |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Carbon dioxide (CAS 124-38-9) Tetrachloroethylene (CAS 127-18-4) US. Massachusetts RTK - Substance List Carbon dioxide (CAS 124-38-9) Tetrachloroethylene (CAS 127-18-4) US. Pennsylvania Worker and Community Right-to-Know Law Tetrachloroethylene (CAS 127-18-4) Carbon dioxide (CAS 124-38-9) US. Rhode Island RTK Tetrachloroethylene (CAS 127-18-4) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Tetrachloroethylene (CAS 127-18-4) Listed: April 1, 1988 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |08-07-2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.