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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Gas Product Name: BIG JINX ROACH & ANT KILLER CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: PESTICIDE 1.3. Name, Address, and Telephone of the Responsible Party Company Claire Manufacturing Co. 1005 S. Westgate Drive Addison, IL 60101 United States Phone: 1-630-543-7600 1.4. Emergency Telephone Number Emergency | 1-866-836-8855, 1-952-852-4646 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Sensitization,|Category 1 skin | Aspiration |Category 1 hazard | Hazardous to |Category 1 the aquatic | environment, | acute | hazard | Hazardous to |Category 1 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Health Hazard |Exclamation Mark |Environment Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. May be fatal if |swallowed and enters airways. May cause an allergic |skin reaction. Very toxic to aquatic life. Very |toxic to aquatic life with long lasting effects. Precautionary Statements |Prevention (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. Do not spray on an open flame or other |ignition source. Pressurized container: Do not |pierce or burn, even after use. Avoid breathing gas. |Contaminated work clothing must not be allowed out |of the workplace. Avoid release to the environment. |Wear protective gloves. |Response: |If swallowed: Immediately call a poison |center/doctor. If on skin: Wash with plenty of |water. Specific treatment (see this label). Do NOT |induce vomiting. If skin irritation or rash occurs: |Get medical advice/attention. Wash contaminated |clothing before reuse. Collect spillage. |Storage: |Store locked up. Protect from sunlight. Do not |expose to temperatures exceeding 50�C/122�F. |Disposal: |Dispose of contents/container in accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Distillates (Petroleum), |64742-47-8 |90 - 100| Hydrotreated Light | | | Carbon Dioxide |124-38-9 |2.5 - 10| Permethrin |52645-53-1 |0.1 - 1 | Piperonyl Butoxide |51-03-6 |0.1 - 1 | Other components below | |0.01 - | reportable levels | |0.1 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If inhalation of gas/fume/vapor/dust/mist from the material is excessive (air concentration is greater than the TLV or health effects are noticed), immediately remove the affected person(s) to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention immediately. First-aid Measures After Skin Contact: Remove and isolate contaminated clothing and shoes. Get medical attention immediately. Get medical attention if irritation develops or persists. For minor skin contact, avoid spreading material on unaffected skin. Wash clothing separately before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops or persists. Continue rinsing. Get medical attention immediately. First-aid Measures After Ingestion: Get medical attention immediately. No need for first aid is anticipated if material is swallowed. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Dermatitis. Aspiration may cause pulmonary edema and pneumonitis. Rash. May cause an allergic skin reaction. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Oxygen, if needed. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information: Take off contaminated clothing and shoes immediately. Immediate medical attention is required. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Keep victim warm. Wash contaminated clothing before reuse. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Large Fires: Powder. Alcohol resistant foam. Water spray, fog or regular foam. Small Fires: Dry chemicals. Carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. Explosion Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighters should wear full protective clothing including self contained breathing apparatus. Firefighting Instructions: Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers exposed to flames with water until well after the fire is out. In the event of fire and/or explosion do not breathe fumes. Specific methods: Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers exposed to flames with water until well after the fire is out. In the event of fire and/or explosion do not breathe fumes. Protection During Firefighting: In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do it without risk. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Some of these materials, if spilled, may evaporate leaving a flammable residue. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Consider initial downwind evacuation for at least 500 meters (1/3 mile). Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Refer to special instructions/safety data sheets. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Use water spray to reduce vapors or divert vapor cloud drift. Isolate area until gas has dispersed. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. After removal flush contaminated area thoroughly with water. This material and its container must be disposed of as hazardous waste. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Vapors may form explosive mixtures with air. Pressurized container: Do not pierce or burn even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Use only in area provided with appropriate exhaust ventilation. Wear appropriate personal protective equipment. Wash thoroughly after handling. Avoid release to the environment. Use appropriate container to avoid environmental contamination. Observe good industrial hygiene practices. Hygiene Measures: When using do not smoke. Avoid contact with eyes. Avoid contact with skin. Avoid contact with clothing. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 3 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50�C/122 �F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store away from incompatible materials (see Section 10 of the SDS). Level 3 Aerosol. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Carbon Dioxide (CAS 124-38-9) PEL 9000 mg/m3 US. ACGIH Threshold Limit Values Components Type Value Carbon Dioxide (CAS 124-38-9) STEL 30000 ppm TWA 5000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Carbon Dioxide (CAS 124-38-9) STEL 54000 mg/m3 30000 ppm TWA 9000 mg/m3 5000 ppm Biological limit values: No biological exposure limits noted for the ingredient(s). 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear appropriate chemical resistant gloves. Eye Protection |Face shield is recommended. Face-shield. Avoid |contact with eyes. Skin and Body Protection |Avoid contact with the skin. Wear chemical |protective equipment that is specifically |recommended by the manufacturer. Use of an |impervious apron is recommended. It may provide |little or no thermal protection. Respiratory Protection |If permissible levels are exceeded use NIOSH |mechanical filter / organic vapor cartridge or an |air-supplied respirator. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Gas. Form Aerosol. Appearance | Odor |fruity Odor Threshold |Not available. pH |Not applicable estimated Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |Not available. Flash Point |228.2 �F (109.0 �C) estimated Auto-ignition Temperature |421 �F (216.11 �C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |70 - 80 psig @70F estimated Relative Vapor Density at 20 �C | Relative Density |Not available. Specific Gravity |0.849 estimated estimated Solubility |Not available Partition coefficient: |Not available n-octanol/water | Viscosity |Not available Lower Flammable Limit |0.5 % estimated Upper Flammable Limit |Not available. 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Risk of explosion. Risk of ignition. Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions Hazardous polymerization does not occur. 10.4 Conditions to Avoid Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5 Incompatible Materials None known. 10.6 Hazardous Decomposition Products May include oxides of nitrogen. May include oxides of phosphorus. No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Acute LD50: 1969 mg/kg, Rat, Dermal Acute LC50: 5 mg/l/4h, Rat, Inhalation May be fatal if swallowed and enters airways. May cause an allergic skin reaction This product has no known adverse effect on human health. Skin Corrosion/Irritation: Not expected to be hazardous by OSHA criteria. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: May cause an allergic skin reaction. Germ Cell Mutagenicity: Not expected to be hazardous by OSHA criteria. Not expected to be hazardous by WHMIS criteria. Carcinogenicity: Not expected to be hazardous by WHMIS criteria. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive Toxicity: Not expected to be hazardous by OSHA criteria. Not expected to be hazardous by WHMIS criteria. Specific Target Organ Toxicity (Single Exposure): Not classified. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: May be fatal if swallowed and enters airways. Dermatitis. Aspiration may cause pulmonary edema and pneumonitis. Rash. May cause an allergic skin reaction. Symptoms/Injuries After Inhalation: Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: May cause an allergic skin reaction. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Chronic Symptoms: Hazardous by OSHA criteria. Prolonged inhalation may be harmful. Prolonged or repeated exposure may cause lung injury. Prolonged exposure may cause chronic effects. Not expected to be hazardous by WHMIS criteria. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity LC50: 46.61 mg/L, Fish, 96.00 Hours Very toxic to aquatic life with long lasting effects. Product Species Test Results BIG JINX ROACH & ANT KILLER (CAS Mixture) Aquatic Fish LC50 Fish 46.605 mg/L, 96 Hours Components Species Test Results Distillates (Petroleum), Hydrotreated Light (CAS 64742-47-8) Aquatic Fish LC50 Rainbow trout,donaldson 2.9 mg/l, 96 hours Trout (Oncorhynchus mykiss) Permethrin (CAS 52645-53-1) Aquatic Crustacea EC50 Water flea (Daphnia magna) 0.0006 - 0.0025 mg/l, 48 hours Fish LC50 Apache trout (Oncorhynchus 0.0013 - 0.0022 mg/l, 96 hours gilae apache) Piperonyl Butoxide (CAS 51-03-6) Aquatic Fish LC50 Rainbow trout,donaldson trout 0.0027 - 0.0043 mg/l, 96 hours (Oncorhynchus mykiss) 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. Partition coefficient n-octanol / water (log Kow) Permethrin 6.5 Piperonyl Butoxide 4.75 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. This material and its container must be disposed of as hazardous waste. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. After recovery of solvent dispose of residue as hazardous waste. Dispose of contents/container in accordance with local/regional/national/international regulations. Additional Information: Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, (each not exceeding 1 L capacity) Hazard Class |2.1 |<PICTOGRAM PHRASE>[pic] Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes |2.1 |<PICTOGRAM PHRASE>[pic] ntification Of The | | Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable Identification Number|UN1950 |<PICTOGRAM PHRASE>[pic] Hazard Class |2.1 | Label Codes |2.1 | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Pesticides are exempt from TSCA. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. CERCLA/SARA Hazardous Substances - Not applicable. CERCLA Hazardous Substance List (40 CFR 302.4): Not listed. SARA 304 Emergency release notification: Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. SARA 302 Extremely hazardous substance: Not listed. SARA 313 (TRI reporting) Chemical name CAS number % by wt. Permethrin 52645-53-1 0.1 - 1 Piperonyl Butoxide 51-03-6 0.1 - 1 Other federal regulations: Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Safe Drinking Water Act (SDWA) : Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - No |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |One or more components are not listed on |TSCA. |TSCA Section 12(b) Export Notification (40 |CFR 707, Subpt. D): Not regulated. 15.2 US State Regulations <COMPONENT> This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. Massachusetts RTK - Substance List Carbon Dioxide (CAS 124-38-9) Permethrin (CAS 52645-53-1) US. New Jersey Worker and Community Right-to-Know Act Carbon Dioxide (CAS 124-38-9) Permethrin (CAS 52645-53-1) Piperonyl Butoxide (CAS 51-03-6) US. Pennsylvania Worker and Community Right-to-Know Law Carbon Dioxide (CAS 124-38-9) US. Rhode Island RTK Permethrin (CAS 52645-53-1) Piperonyl Butoxide (CAS 51-03-6) US. California Proposition 65: California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |01-02-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.