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SDS Sheet 0066690

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SECTION 1: IDENTIFICATION                                                       

1.1.  Product Identifier
Product Form: Gas. Form                                                         
Product Name: BUG BUSTER INSECT KILLER                                          
CAS No:                                                                         

1.2.  Intended Use of the Product
Use of the substance/mixture: PESTICIDE                                         

1.3.  Name, Address, and Telephone of the Responsible Party
Claire Manufacturing Co.                                                        
1005 S. Westgate Drive                                                          
Addison, IL 60101 United States                                                 
Phone: 1-630-543-7600                                                           

1.4.  Emergency Telephone Number
Emergency     | 1-866-836-8855,  telephone outside US: 1-952-852-4646           
number        |                                                                 

SECTION 2: HAZARDS IDENTIFICATION                                               

2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flammable     |Category 1    
aerosols      |              

2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame 
Signal Word (GHS-US)         |Danger                                            
Hazard Statements (GHS-US)   |Extremely flammable aerosol.                      
Precautionary Statements     |Prevention:                                       
(GHS-US)                     |Keep away from heat/sparks/open flames/hot
                             |- No smoking. Do not spray on an open flame or
                             |ignition source. Pressurized container: Do not    
                             |pierce or burn, even after use. Avoid release to
                             |Response: Collect spillage.                       
                             |Protect from sunlight. Do not expose to
                             |exceeding 50°C/122°F.                             
                             |Dispose of contents/container in accordance with  
                             |local/regional/national/international regulations.

2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Static accumulating       
flammable liquid can become electrostatically charged even in bonded and
equipment. Sparks may ignite liquid and vapor. May cause flash fire or

2.4.  Unknown Acute Toxicity (GHS-US)


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
                                |                     |        |(GHS-US)        
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                
                                |                     |        |                

Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
                                |                     |        |(GHS-US)        
Butane                          |106-97-8             |2.5 - 10|                
Propane                         |74-98-6              |2.5 - 10|                
Piperonyl Butoxide              |51-03-6              |1 - 2.5 |                
Pyrethrins                      |8003-34-7            |0.1 - 1 |                
Other components below          |                     |60 - 80 |                
reportable levels               |                     |        |                

*Designates that a specific chemical identity and/or percentage of
composition has been withheld as a trade secret.

SECTION 4: FIRST AID MEASURES                                                   

4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
First-aid Measures After Inhalation: If symptoms develop move victim to fresh
Get medical attention if symptoms persist.                                      
First-aid Measures After Skin Contact: Wash off with soap and water. Get medical
attention if irritation develops and persists.                                  
First-aid Measures After Eye Contact: Rinse with water. Get medical attention if
irritation develops and persists.                                               
First-aid Measures After Ingestion: In the unlikely event of swallowing contact
physician or poison control center.                                             

4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries After Inhalation:                                             
Symptoms/Injuries After Skin Contact:                                           
Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause
Symptoms/Injuries After Ingestion:                                              
Chronic Symptoms:                                                               

4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Provide general supportive measures and treat symptomatically.                  
General information: Ensure that medical personnel are aware of the material(s) 
involved, and take precautions to protect themselves.                           

SECTION 5: FIRE-FIGHTING MEASURES                                               

5.1.  Extinguishing Media
Suitable Extinguishing Media: Water fog. Foam. Carbon dioxide (CO2). Dry
powder, carbon dioxide, sand or earth may be used for small fires only.         
Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this
will spread the fire.                                                           

5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Contents under pressure. Pressurized container may explode when    
exposed to heat or flame. This product is a poor conductor of electricity and
become electrostatically charged. If sufficient charge is accumulated, ignition
flammable mixtures can occur. To reduce potential for static discharge, use
bonding and grounding procedures. This liquid may accumulate static electricity 
when filling properly grounded containers. Static electricity accumulation may
significantly increased by the presence of small quantities of water or other   
contaminants. Material will float and may ignite on surface of water.           
Explosion Hazard: Extremely flammable aerosol.                                  

5.3.  Advice for Firefighters
Precautionary Measures Fire: Firefighters must use standard protective equipment
including flame retardant coat, helmet with face shield, gloves, rubber boots,
in enclosed spaces, SCBA.                                                       
Firefighting Instructions:  Move containers from fire area if you can do so     
without risk. Containers should be cooled with water to prevent vapor pressure  
build up. For massive fire in cargo area, use unmanned hose holder or monitor   
nozzles, if possible. If not, withdraw and let fire burn out.                   
Specific methods: Use standard firefighting procedures and consider the hazards
other involved materials. Move containers from fire area if you can do so
risk. In the event of fire and/or explosion do not breathe fumes.               
Protection During Firefighting: Use standard firefighting procedures and
the hazards of other involved materials. Move                                   
containers from fire area if you can do so without risk. In the event of fire   
and/or explosion do not breathe fumes.                                          

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          

6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Keep unnecessary personnel away. Keep people away from and    
upwind of spill/leak. Keep out of low areas. Remove all possible sources of     
ignition in the surrounding area. Wear appropriate protective equipment and     
clothing during clean-up. Do not touch damaged containers or spilled material   
unless wearing appropriate protective clothing. Ventilate closed spaces before  
entering them. Use appropriate containment to avoid environmental contamination.
Transfer by mechanical means such as vacuum truck to a salvage tank or other    
suitable container for recovery or safe disposal. Local authorities should be   
advised if significant spillages cannot be contained. For personal protection,
section 8 of the SDS.                                                           

6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
Emergency Procedures:                                                           

6.1.2.      For Emergency Responders
Protective Equipment:                                                           
Emergency Procedures:                                                           

6.2.  Environmental Precautions
Avoid release to the environment. Inform appropriate managerial or supervisory  
personnel of all environmental releases. Prevent further leakage or spillage if 
safe to do so. Avoid discharge into drains, water courses or onto the ground.
appropriate containment to avoid environmental contamination.                   

6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
Methods for Cleaning Up: Refer to attached safety data sheets and/or
for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames
immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled   
material. Stop leak if you can do so without risk. Move the cylinder to a safe
open area if the leak is irreparable. Cover with plastic sheet to prevent       
spreading. Absorb in vermiculite, dry sand or earth and place into containers.  
Prevent entry into waterways, sewer, basements or confined areas. Following     
product recovery, flush area with water.                                        
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean
thoroughly to remove residual contamination. For waste disposal, see section 13
the SDS.                                                                        

6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      

SECTION 7: HANDLING AND STORAGE                                                 

7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Minimize fire risks from flammable and       
combustible materials (including combustible dust and static accumulating
or dangerous reactions with incompatible materials. Handling operations that can
promote accumulation of static charges include but are not limited to: mixing,  
filtering, pumping at high flow rates, splash filling, creating mists or sprays,
tank and container filling, tank cleaning, sampling, gauging, switch loading,   
vacuum truck operations. Pressurized container: Do not pierce or burn, even
use. Do not use if spray button is missing or defective. Do not spray on a naked
flame or any other incandescent material. Do not smoke while using or until     
sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or   
expose containers to heat, flame, sparks, or other sources of ignition. All     
equipment used when handling the product must be grounded. Do not re-use empty  
containers. Use only in well-ventilated areas. Wear appropriate personal        
protective equipment. Avoid release to the environment. Observe good industrial 
hygiene practices.                                                              
For additional information on equipment bonding and grounding, refer to the     
Canadian Electrical Code in Canada, (CSA C22.1), or the American Petroleum      
Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising
out of Static, Lightning, and Stray Currents" or National Fire Protection       
Association (NFPA) 77, "Recommended Practice on Static Electricity" or National 
Fire Protection Association (NFPA) 70, "National Electrical Code".              
Hygiene Measures: When using do not smoke. Always observe good personal hygiene 
measures, such as washing after handling the material and before eating,
and/or smoking. Routinely wash work clothing and protective equipment to remove 

7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
Storage Conditions: Level 1 Aerosol.                                            
Pressurized container. Protect from sunlight and do not expose to temperatures  
exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or   
store near an open flame, heat or other sources of ignition. This material can  
accumulate static charge which may cause spark and become an ignition source.   
Avoid spark promoters. Ground/bond container and equipment. These alone may be  
insufficient to remove static electricity. Refrigeration recommended. Store away
from incompatible materials (see Section 10 of the SDS).                        

7.3.  Specific End Use(s)


8.1.  Control Parameters
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)               
Propane (CAS 74-98-6)                                                           
1800 mg/m3                                                                      
1000 ppm                                                                        
Pyrethrins (CAS 8003-34-7)                                                      
5 mg/m3                                                                         
US. ACGIH Threshold Limit Values                                                
Butane (CAS 106-97-8)                                                           
1000 ppm                                                                        
Pyrethrins (CAS 8003-34-7)                                                      
5 mg/m3                                                                         
US. NIOSH: Pocket Guide to Chemical Hazards                                     
Butane (CAS 106-97-8)                                                           
1900 mg/m3                                                                      
800 ppm                                                                         
Propane (CAS 74-98-6)                                                           
1800 mg/m3                                                                      
1000 ppm                                                                        
Pyrethrins (CAS 8003-34-7)                                                      
5 mg/m3                                                                         

8.2.  Exposure Controls
Appropriate Engineering      |Good general ventilation (typically 10 air changes
Controls                     |per hour) should be used. Ventilation rates should
                             |be matched to conditions. If applicable, use
                             |enclosures, local exhaust ventilation, or other   
                             |engineering controls to maintain airborne levels  
                             |below recommended  exposure limits. If exposure   
                             |limits have not been established, maintain
                             |levels to a acceptable level.                     
Personal Protective Equipment|                                                  
Materials for Protective     |                                                  
Clothing                     |                                                  
Hand Protection              |Wear appropriate chemical resistant gloves.       
Eye Protection               |Wear safety glasses with side shields (or
Skin and Body Protection     |Skin protection: Other: Wear suitable protective  
Respiratory Protection       |If permissible levels are exceeded use NIOSH      
                             |mechanical filter / organic vapor cartridge or an 
                             |air-supplied respirator.                          
Thermal Hazard Protection    |Wear appropriate thermal protective clothing, when

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     

9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Gas.                                       
Appearance                          |Aerosol. Color                             
Odor                                |Not available.                             
Odor Threshold                      |Not available.                             
pH                                  |Not available.                             
Relative Evaporation Rate           |Not available.                             
(butylacetate=1)                    |                                           
Melting Point                       |Not available.                             
Freezing Point                      |Not available.                             
Boiling Point                       |212 °F (100 °C) estimated                  
Flash Point                         |-156.0 °F (-104.4 °C) PROPELLANT estimated 
Auto-ignition Temperature           |421 °F (216.11 °C) estimated               
Decomposition Temperature           |Not available.                             
Flammability (solid, gas)           |Not available.                             
Vapor Pressure                      |30.85 psig @70F estimated                  
Relative Vapor Density at 20 °C     |                                           
Relative Density                    |Not available.                             
Specific Gravity                    |0.888 estimated                            
Solubility                          |Not available.                             
Partition coefficient:              |Not available.                             
n-octanol/water                     |                                           
Viscosity                           |Not available.                             
Lower Flammable Limit               |1.5 % estimated                            
Upper Flammable Limit               |9.5 % estimated                            

9.2.  Other Information

SECTION 10: STABILITY AND REACTIVITY                                            

10.1      Reactivity
The product is stable and non-reactive under normal conditions of use, storage

10.2      Chemical Stability
Material is stable under normal conditions.                                     

10.3      Possibility of Hazardous Reactions
Hazardous polymerization does not occur.                                        

10.4      Conditions to Avoid
Avoid temperatures exceeding the flash point. Contact with incompatible

10.5      Incompatible Materials
Strong oxidizing agents. Nitrates. Fluorine. Chlorine.                          

10.6      Hazardous Decomposition Products
No hazardous decomposition products are known.                                  

SECTION 11: TOXICOLOGICAL INFORMATION                                           

11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
Skin Corrosion/Irritation: Prolonged skin contact may cause temporary
Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary     
Respiratory or Skin Sensitization: Respiratory sensitization: Not available.    
Skin sensitization: This product is not expected to cause skin sensitization.   
Germ Cell Mutagenicity: No data available to indicate product or any components 
present at greater than 0.1% are mutagenic or genotoxic.                        
Carcinogenicity: Risk of cancer cannot be excluded with prolonged exposure.     
Reproductive Toxicity: This product is not expected to cause reproductive or    
developmental effects.                                                          
Specific Target Organ Toxicity (Single Exposure): Not classified.               
Specific Target Organ Toxicity (Repeated Exposure): Not classified.             
Aspiration Hazard: Not classified.                                              
Symptoms/Injuries After Inhalation: No adverse effects due to inhalation are    
Symptoms/Injuries After Skin Contact: No adverse effects due to skin contact are
Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause
Symptoms/Injuries After Ingestion: Expected to be a low ingestion hazard.       
Chronic Symptoms: Prolonged exposure may cause chronic effects.                 

SECTION 12: ECOLOGICAL INFORMATION                                              

12.1. Toxicity
Very toxic to aquatic life with long lasting effects                            
Components                                                    Species           
Test Results                                                                    
Piperonyl Butoxide (CAS 51-03-6)                                                
Fish                                     LC50          Rainbow trout,donaldson  
trout        0.0027 - 0.0043 mg/l, 96 hours                                     
(Oncorhynchus mykiss)                                                           
Pyrethrins (CAS 8003-34-7)                                                      
Crustacea                         EC50          Water flea (Daphnia)            
0.018 - 0.032 mg/l, 48 hours                                                    
Fish                                    LC50          Brown trout (Salmo trutta)
0.0165 - 0.0229 mg/l, 96 hours                                                  
* Estimates for product may be based on additional component data not shown.    

12.2. Persistence and Degradability
No data is available on the degradability of this product.                      

12.3. Bioaccumulative Potential
No data available.                                                              
Partition coefficient n-octanol / water (log Kow)                               
Butane                                         2.89                             
Piperonyl Butoxide                   4.75                                       
Propane                                      2.36                               

12.4. Mobility in Soil
No data available.                                                              

12.5. Other Adverse Effects
No other adverse environmental effects (e.g. ozone depletion, photochemical
creation potential, endocrine disruption, global warming potential) are expected
from this component.                                                            

13.1. Waste treatment methods
Waste Disposal Recommendations: Collect and reclaim or dispose in sealed        
containers at licensed waste disposal site. Contents under pressure. Do not     
puncture, incinerate or crush. Do not allow this material to drain into         
sewers/water supplies. Do not contaminate ponds, waterways or ditches with      
chemical or used container. Dispose of contents/container in accordance with    
local/regional/national/international regulations.                              
Additional Information:                                                         
Local disposal regulations: Dispose in accordance with all applicable
Hazardous waste code: The waste code should be assigned in discussion between
user, the producer and the waste disposal company.                              
Waste from residues / unused products:  Dispose of in accordance with local     
regulations. Empty containers or liners may retain some product residues. This  
material and its container must be disposed of in a safe manner (see: Disposal  
Contaminated packaging: Empty containers should be taken to an approved waste   
handling site for recycling or disposal. Since emptied containers may retain    
product residue, follow label warnings even after container is emptied. Do not  
re-use empty containers.                                                        

SECTION 14: TRANSPORT INFORMATION                                               

14.1 In Accordance with DOT
Proper Shipping Name |Aerosols, flammable, (each not exceeding 1 L capacity)    
Hazard Class         |2.1                    |<PICTOGRAM PHRASE>[pic]           
Identification Number|UN1950                 |                                  
Label Codes          |2.1                    |                                  
ERG Number           |                                                          

14.2 In Accordance with IMDG
Proper Shipping Name |AEROSOLS                                                  
Hazard Class         |2.1                                                       
Identification Number|UN1950                                                    
Label Codes          |2.1                   |<PICTOGRAM PHRASE>[pic]            
ntification Of The   |                      |                                   
Substance/m          |                      |                                   
EmS-No. (Fire)       |F-D                   |                                   
EmS-No. (Spillage)   |  S-U                 |                                   

14.3 In Accordance with IATA
Proper Shipping Name |Aerosols, flammable                                       
Identification Number|UN1950                 |<PICTOGRAM PHRASE>[pic]           
Hazard Class         |2.1                    |                                  
Label Codes          |2.1                    |                                  
ntification Of The   |                       |                                  
Substance/m          |                       |                                  
ERG Code (IATA)      |10L                                                       

SECTION 15: REGULATORY INFORMATION                                              

15.1      US Federal Regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard
Standard, 29 CFR 1910.1200.                                                     
CERCLA Hazardous Substance List (40 CFR 302.4):                                 
Pyrethrins (CAS 8003-34-7)                  Listed.                             
SARA 304 Emergency release notification: Not regulated.                         
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed.     
SARA 302 Extremely hazardous substance: Not listed.                             
SARA 313 (TRI reporting):                                                       
Chemical name                  CAS number                        % by wt.       
Piperonyl Butoxide           51-03-6                                 1 - 2.5    
Other federal regulations: Clean Air Act (CAA) Section 112 Hazardous Air        
Pollutants (HAPs) List: Not regulated.                                          
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8)                                                           
Propane (CAS 74-98-6)                                                           
Safe Drinking Water Act (SDWA): Not regulated.                                  
SARA Section 311/312 Hazard Classes | Immediate Hazard - No                     
                                    |Delayed Hazard - No                        
                                    |Fire Hazard - Yes                          
                                    |Pressure Hazard - No                       
                                    |Reactivity Hazard - No                     
Toxic Substances Control Act (TSCA) |One or more components are not listed on   
                                    |TSCA Section 12(b) Export Notification (40 
                                    |CFR 707, Subpt. D): Not regulated.         

15.2      US State Regulations
US. Massachusetts RTK - Substance List                                          
Butane (CAS 106-97-8)                                                           
Propane (CAS 74-98-6)                                                           
Pyrethrins (CAS 8003-34-7)                                                      
US. New Jersey Worker and Community Right-to-Know Act                           
Butane (CAS 106-97-8)                                                           
Piperonyl Butoxide (CAS 51-03-6)                                                
Propane (CAS 74-98-6)                                                           
Pyrethrins (CAS 8003-34-7)                                                      
US. Pennsylvania Worker and Community Right-to-Know Law                         
Butane (CAS 106-97-8)                                                           
Propane (CAS 74-98-6)                                                           
Pyrethrins (CAS 8003-34-7)                                                      
US. Rhode Island RTK                                                            
Butane (CAS 106-97-8)                                                           
Piperonyl Butoxide (CAS 51-03-6)                                                
Propane (CAS 74-98-6)                                                           
Pyrethrins (CAS 8003-34-7)                                                      
US. California Proposition 65                                                   
WARNING: This product contains a chemical known to the State of California to   
cause cancer.                                                                   
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance        
Diethanolamine (CAS 111-42-2) Listed: June 22, 2012                             


Revision date   |                                                               
Other           |This document has been prepared in accordance with the SDS     
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
GHS Full Text Phrases:                                                          
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Grainger disclaimer.

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.