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SDS Sheet 0066680

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form: Aerosol                                                           
 
Product Name: DOWN & OUT II FLYING INSECT KILLER                                
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: PESTICIDE                                         
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Claire Manufacturing Co.                                                        
 
1005 S. Westgate Drive                                                          
 
Addison, IL 60101                                                               
 
United States                                                                   
 
Phone                                                                           
 


1.4.  Emergency Telephone Number
Emergency     | (US) 1-866-836-8855                                             
 
number        |Outside (US) 1-952-852-4646                                      
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flammable     | Category 1   
aerosols      |              
              |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame 
        
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |Extremely flammable aerosol.                      
 
Precautionary Statements     |Prevention:                                       
 
(GHS-US)                     |Keep away from heat/sparks/open flames/hot
surfaces.
                             |- No smoking. Do not spray on an open flame or
other
                             |ignition source. Pressurized container: Do not    
 
                             |pierce or burn, even after use.                   
 
                             |Response:                                         
 
                             |Wash hands after handling.                        
 
                             |Storage:                                          
 
                             |Protect from sunlight. Do not expose to
temperatures
                             |exceeding 50°C/122°F.                             
 
                             |Disposal:                                         
 
                             |Dispose of contents/container in accordance with  
 
                             |local/regional/national/international regulations.
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None known.               
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Butane                          |106-97-8             |2.5 - 10|                
 
Propane                         |74-98-6              |2.5 - 10|                
 
Other components below          |                     |80 - 90 |                
 
reportable levels               |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: If symptoms develop move victim to fresh
air.
Get medical attention if symptoms persist.                                      
 
First-aid Measures After Skin Contact: Wash off with soap and water. Get medical
 
attention if irritation develops and persists.                                  
 
First-aid Measures After Eye Contact: Rinse with water. Get medical attention if
 
irritation develops and persists.                                               
 
First-aid Measures After Ingestion: Rinse mouth. Get medical attention if
symptoms
occur.                                                                          
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause
temporary 
irritation.                                                                     
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms: Provide general supportive measures and treat symptomatically.
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Provide general supportive measures and treat symptomatically.                  
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Not available.                                    
 
Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this
 
will spread the fire.                                                           
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Extremely flammable aerosol.                                       
 
Explosion Hazard: Contents under pressure. Pressurized container may explode
when 
exposed to heat or flame.                                                       
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: Move containers from fire area if you can do so
without
risk. Containers should be cooled with water to prevent vapor pressure build up.
 
For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if 
 
possible. If not, withdraw and let fire burn out.                               
 
Specific methods: Use standard firefighting procedures and consider the hazards
of
other involved materials. Move containers from fire area if you can do so
without 
risk. In the event of fire and/or explosion do not breathe fumes.               
 
Protection During Firefighting: Firefighters must use standard protective       
 
equipment including flame retardant coat, helmet with                           
 
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.                
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Keep unnecessary personnel away. Keep people away from and    
 
upwind of spill/leak. Keep out of low areas. Wear appropriate protective
equipment
and clothing during clean-up. Do not touch damaged containers or spilled
material 
unless wearing appropriate protective clothing. Ventilate closed spaces before  
 
entering them. Local authorities should be advised if significant spillages.    
 
cannot be contained. For personal protection, see section 8 of the SDS.         
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
                                                                                
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up: Refer to attached safety data sheets and/or
instructions 
for use. Eliminate all ignition sources (no                                     
 
smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, 
 
paper, oil, etc.) away from spilled material. Stop leak if you can do so without
 
risk. Move the cylinder to a safe and open area if the leak is irreparable.     
 
Isolate area until gas has dispersed. Prevent entry into waterways, sewer,      
 
basements or confined areas. For waste disposal, see section 13 of the SDS.     
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Pressurized container: Do not pierce or burn,
 
even after use. Do not use if spray button is missing or defective. Do not spray
 
on a naked flame or any other incandescent material. Do not smoke while using or
 
until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind,
 
or expose containers to heat, flame, sparks, or other sources of ignition. All  
 
equipment used when handling the product must be grounded. Do not re-use empty  
 
containers. Use only in well-ventilated areas. Wear appropriate personal        
 
protective equipment. Avoid release to the environment. Observe good industrial 
 
hygiene practices.                                                              
 
Hygiene Measures: When using do not smoke. Always observe good personal hygiene 
 
measures, such as washing after handling the material and before eating,
drinking,
and/or smoking. Routinely wash work clothing and protective equipment to remove 
 
contaminants.                                                                   
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Pressurized container. Protect from sunlight and do not
expose
to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do 
 
not handle or store near an open flame, heat or other sources of ignition. This 
 
material can accumulate static charge which may cause spark and become an
ignition
source. Refrigeration recommended. Store away from incompatible materials (see  
 
Section 10 of the SDS).                                                         
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Occupational exposure limits:                                                   
 
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)               
 
Components                                                                      
 
Type                                                                            
 
Value                                                                           
 
                                                                                
 
Propane (CAS 74-98-6)                                                           
 
PEL                                                                             
 
1800 mg/m3                                                                      
 
1000 ppm                                                                        
 
                                                                                
 
US. ACGIH Threshold Limit Values                                                
 
Components                                                                      
 
Type                                                                            
 
Value                                                                           
 
                                                                                
 
Butane (CAS 106-97-8)                                                           
 
STEL                                                                            
 
1000 ppm                                                                        
 
                                                                                
 
US. NIOSH: Pocket Guide to Chemical Hazards                                     
 
Components                                                                      
 
Type                                                                            
 
Value                                                                           
 
                                                                                
 
Butane (CAS 106-97-8)                                                           
 
TWA                                                                             
 
1900 mg/m3                                                                      
 
800 ppm                                                                         
 
                                                                                
 
Propane (CAS 74-98-6)                                                           
 
TWA                                                                             
 
1800 mg/m3                                                                      
 
1000 ppm                                                                        
 
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Good general ventilation (typically 10 air changes
 
Controls                     |per hour) should be used. Ventilation rates should
 
                             |be matched to conditions. If applicable, use
process
                             |enclosures, local exhaust ventilation, or other   
 
                             |engineering controls to maintain airborne levels  
 
                             |below recommended exposure limits. If exposure    
 
                             |limits have not been established, maintain
airborne 
                             |levels to an acceptable level.                    
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Wear appropriate chemical resistant gloves.       
 
Eye Protection               |Wear safety glasses with side shields (or
goggles). 
Skin and Body Protection     |Wear suitable protective clothing.                
 
Respiratory Protection       |If permissible levels are exceeded use NIOSH      
 
                             |mechanical filter / organic vapor cartridge or an 
 
                             |air-supplied respirator.                          
 
Thermal Hazard Protection    |Wear appropriate thermal protective clothing, when
 
                             |necessary.                                        
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Gas. Form                                  
 
Appearance                          |                                           
 
Odor                                |Not available.                             
 
Odor Threshold                      |Not available.                             
 
pH                                  |Not available.                             
 
Relative Evaporation Rate           |Not available.                             
 
(butylacetate=1)                    |                                           
 
Melting Point                       |Not available.                             
 
Freezing Point                      |Not available.                             
 
Boiling Point                       |212 °F (100 °C) estimated                  
 
Flash Point                         |-156.0 °F (-104.4 °C) PROPELLANT estimated 
 
Auto-ignition Temperature           |456.8 °F (236 °C) estimated                
 
Decomposition Temperature           |Not available.                             
 
Flammability (solid, gas)           |Not available.                             
 
Vapor Pressure                      |31.22 psig @70F estimated                  
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |                                           
 
Specific Gravity                    |                                           
 
Solubility                          |Not available.                             
 
Partition coefficient:              |Not available.                             
 
n-octanol/water                     |                                           
 
Viscosity                           |Not available.                             
 
Lower Flammable Limit               |1.9 % estimated                            
 
Upper Flammable Limit               |9.5 % estimated                            
 


9.2.  Other Information
                                                                                
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
The product is stable and non-reactive under normal conditions of use, storage
and
transport.                                                                      
 


10.2      Chemical Stability
Material is stable under normal conditions.                                     
 


10.3      Possibility of Hazardous Reactions
Hazardous polymerization does not occur.                                        
 


10.4      Conditions to Avoid
Avoid temperatures exceeding the flash point. Contact with incompatible
materials.


10.5      Incompatible Materials
Strong oxidizing agents. Nitrates. Fluorine. Chlorine.                          
 


10.6      Hazardous Decomposition Products
No hazardous decomposition products are known.                                  
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation: Prolonged skin contact may cause temporary
irritation. 
Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary     
 
irritation.                                                                     
 
Respiratory or Skin Sensitization: Respiratory sensitization: Not available.    
 
Skin sensitization: This product is not expected to cause skin sensitization.   
 
Germ Cell Mutagenicity: No data available to indicate product or any components 
 
present at greater than 0.1% are mutagenic or genotoxic.                        
 
Carcinogenicity: This product is not considered to be a carcinogen by IARC,
ACGIH,
NTP, or OSHA.                                                                   
 
Reproductive Toxicity: This product is not expected to cause reproductive or    
 
developmental effects.                                                          
 
Specific Target Organ Toxicity (Single Exposure): Not classified.               
 
Specific Target Organ Toxicity (Repeated Exposure): Not classified.             
 
Aspiration Hazard: Not likely, due to the form of the product.                  
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause
temporary 
irritation.                                                                     
 
Symptoms/Injuries After Ingestion: Expected to be a low ingestion hazard.       
 
Chronic Symptoms: Direct contact with eyes may cause temporary irritation.      
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Ecotoxicity: Harmful to aquatic life with long lasting effects.                 
 


12.2. Persistence and Degradability
No data is available on the degradability of this product.                      
 


12.3. Bioaccumulative Potential
No data available.                                                              
 


12.4. Mobility in Soil
No data available.                                                              
 


12.5. Other Adverse Effects
No other adverse environmental effects (e.g. ozone depletion, photochemical
ozone 
creation potential, endocrine disruption, global warming potential) are expected
 
from this component.                                                            
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Collect and reclaim or dispose in sealed        
 
containers at licensed waste disposal site. Contents under pressure. Do not     
 
puncture, incinerate or crush. Do not allow this material to drain into         
 
sewers/water supplies. Do not contaminate ponds, waterways or ditches with      
 
chemical or used container. Dispose of contents/container in accordance with    
 
local/regional/national/international regulations.                              
 
Local disposal regulations: Dispose in accordance with all applicable
regulations.
                                                                                
 
Hazardous waste code: The waste code should be assigned in discussion between
the 
user, the producer and the waste disposal company.                              
 
Waste from residues / unused products: Dispose of in accordance with local      
 
regulations. Empty containers or liners may retain some product residues. This  
 
material and its container must be disposed of in a safe manner (see: Disposal  
 
instructions).                                                                  
 
Additional Information: Contaminated packaging Empty containers should be taken
to
an approved waste handling site for recycling or disposal. Since emptied        
 
containers may retain product residue, follow label warnings even after
container 
is emptied. Do not re-use empty containers.                                     
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Aerosols, flammable, (each not exceeding 1 L capacity)    
 
Hazard Class         |2.1                    |<PICTOGRAM PHRASE>                
 
                     |                       |[pic]                             
 
Identification Number|UN1950                 |                                  
 
Label Codes          |2.1                    |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |AEROSOLS                                                  
 
Hazard Class         |2.1                                                       
 
Identification Number|UN1950                                                    
 
Label Codes          |2.1                   |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |[pic]                              
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |F-D                   |                                   
 
EmS-No. (Spillage)   |S-U                   |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Aerosols, flammable                                       
 
Identification Number|UN1950                 |<PICTOGRAM PHRASE>                
  
                     |                       |[pic]                             
  
Hazard Class         |2.1                    |                                  
  
Label Codes          |2.1                    |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |No.                                                       
 
                     |10L                                                       
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
This product is a "Hazardous Chemical" as defined by the OSHA Hazard
Communication
Standard, 29 CFR 1910.1200.                                                     
 
All components are on the U.S. EPA TSCA Inventory List.                         
 
                                                                                
 
CERCLA Hazardous Substance List (40 CFR 302.4): Not listed.                     
 
SARA 304 Emergency release notification: Not regulated.                         
 
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed.     
 
SARA Section 311/312 Hazard Classes |Immediate Hazard - No                      
 
                                    |Delayed Hazard - No                        
 
                                    |Fire Hazard - Yes                          
 
                                    |Pressure Hazard - No                       
 
                                    |Reactivity Hazard - No                     
 
Toxic Substances Control Act (TSCA) |Not regulated.                             
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
US. Massachusetts RTK - Substance List                                          
 
Butane (CAS 106-97-8)                                                           
 
Propane (CAS 74-98-6)                                                           
 
US. New Jersey Worker and Community Right-to-Know Act                           
 
Butane (CAS 106-97-8)                                                           
 
Propane (CAS 74-98-6)                                                           
 
US. Pennsylvania Worker and Community Right-to-Know Law                         
 
Butane (CAS 106-97-8)                                                           
 
Propane (CAS 74-98-6)                                                           
 
US. Rhode Island RTK                                                            
 
Butane (CAS 106-97-8)                                                           
 
Propane (CAS 74-98-6)                                                           
 
US. California Proposition 65                                                   
 
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition
65):
This material is not known to contain                                           
 
any chemicals currently listed as carcinogens or reproductive toxins            
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |                                                               
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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