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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 19 OZ SPRAYWAY GLASS CLEANER LT 12PK CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States Phone: 1-630-628-3000 1.4. Emergency Telephone Number Emergency | 1-866-836-8855, 1-952-852-4646 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Gases under |Liquefied gas pressure | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Gas Cylinder Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |Contains gas under pressure; may explode if heated. Precautionary Statements |Prevention: Observe good industrial hygiene (GHS-US) |practices. |Response: Wash hands after handling. |Storage: Protect from sunlight. Store in a |well-ventilated place. |Disposal: Dispose of waste and residues in |accordance with local authority requirements. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) 2-Butoxyethanol |111-76-2 |2.5 - 10| Ethyl Alcoho |64-17-5 |2.5 - 10| Butane |106-97-8 |1 - 2.5 | Propane |74-98-6 |1 - 2.5 | Other components below | |90 - 100| reportable levels | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. First-aid Measures After Inhalation: Move to fresh air. Get medical attention if symptoms persist. First-aid Measures After Skin Contact: Get medical attention if irritation develops and persists. First-aid Measures After Eye Contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Rinse mouth. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. During fire, gases hazardous to health may be formed. No unusual fire or explosion hazards noted. Explosion Hazard: Use standard firefighting procedures and consider the hazards of other involved materials. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Use standard firefighting procedures and consider the hazards of other involved materials. Protection During Firefighting: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. See Section 8 of the SDS for Personal Protective Equipment. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers when transferring material. Do not re-use empty containers. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Keep containers tightly closed in a dry, cool and well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000): Components Type Value 2-Butoxyethanol (CAS 111-76-2) PEL 240 mg/m3 50 ppm Ethyl Alcohol (CAS 64-17-5) PEL 1900 mg/m3 1000 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3 1000 ppm US. ACGIH Threshold Limit Values: Components Type Value 2-Butoxyethanol (CAS 111-76-2) TWA 20 ppm Butane (CAS 106-97-8) STEL 1000 ppm Ethyl Alcohol (CAS 64-17-5) STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards: Components Type Value 2-Butoxyethanol (CAS 111-76-2) TWA 24 mg/m3 5 ppm Butane (CAS 106-97-8) TWA 1900 mg/m3 800 ppm Ethyl Alcohol (CAS 64-17-5) TWA 1900 mg/m3 1000 ppm Propane (CAS 74-98-6) TWA 1800 mg/m3 1000 ppm Biological limit values: ACGIH Biological Exposure Indices: Components Value Determinant Specimen Sampling Time 2-Butoxyethanol (CAS 111-76-2) 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine * * - For sampling details, please see the source document. Exposure guidelines: US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |For prolonged or repeated skin contact use suitable |protective gloves. Eye Protection |If contact is likely, safety glasses with side |shields are recommended. Skin and Body Protection |Other: Wear suitable protective clothing. Respiratory Protection |If engineering controls do not maintain airborne |concentrations below recommended exposure limits |(where applicable) or to an acceptable level (in |countries where exposure limits have not b been |established), an approved respirator must be worn. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Gas. Appearance |Clear. Odor |Characteristic. Odor Threshold |Not available. pH |9.1 - 10.1 estimated Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |212 Â°F (100 Â°C) estimated Flash Point |-156.0 Â°F (-104.4 Â°C) Propellant estimated Auto-ignition Temperature |Not available. Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |80 - 100 psig @70F estimated Relative Vapor Density at 20 Â°C | Relative Density |Not available. Specific Gravity |0.977 - 0.997 Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |Not available. Upper Flammable Limit |Not available. 9.2. Other Information Aerosol spray enclosed space Deflagration density: > 2.52 g/cm3 Tested Aerosol spray ignition Distance :< 15 cm Tested estimated SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. 10.4 Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Expected to be a low hazard for usual industrial or commercial handling by trained personnel. May be harmful if swallowed. May be harmful in contact with skin. May be harmful if inhaled. Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. May be irritating to the skin. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. May be irritating to eyes. Respiratory or Skin Sensitization: Respiratory sensitization: Not a respiratory sensitizer. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity: 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): Not classified. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Not an aspiration hazard. Not likely, due to the form of the product. Symptoms/Injuries After Inhalation: Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: No adverse effects due to skin contact are expected. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Expected to be a low ingestion hazard. Chronic Symptoms: Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Harmful to aquatic life. Not expected to be harmful to aquatic organisms. Product Species Test Results 19 OZ SPRAYWAY GLASS CLEANER LT 12PK (CAS Mixture) Aquatic Crustacea EC50 Daphnia 46283.3398 mg/l, 48 hours estimated Components Species Test Results 2-Butoxyethanol (CAS 111-76-2) Aquatic Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours Ethyl Alcohol (CAS 64-17-5) Aquatic Crustacea EC50 Water flea (Daphnia magna) 7700 - 11200 mg/l, 48 hours Components Species Test Results Fish LC50 Fathead minnow (Pimephales promelas) > 100.1 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Ethyl Alcohol -0.31 Propane 2.36 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal instructions Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Additional Information: Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols Hazard Class |2.2 |<PICTOGRAM PHRASE> | |[pic] Identification Number|UN1950 | Label Codes |2.2 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.2 Identification Number|UN1950 Label Codes |2.2 |<PICTOGRAM PHRASE> ntification Of The | |[pic] Substance/m | | EmS-No. (Fire) |Not available. | EmS-No. (Spillage) |Not available. | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, non-flammable Identification Number|UN1950 |<PICTOGRAM PHRASE> | |[pic] Hazard Class |2.2 | Label Codes |2.2 | ntification Of The | | Substance/m | | ERG Code (IATA) |2L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. CERCLA Hazardous Substance List (40 CFR 302.4): Not listed. SARA 304 Emergency release notification: Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. SARA 302 Extremely hazardous substance Not listed. SARA 313 (TRI reporting) Not regulated. Other federal regulations: Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - No |Delayed Hazard - No |Fire Hazard - No |Pressure Hazard - Yes |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. Massachusetts RTK - Substance List: 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act: 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Pennsylvania Worker and Community Right-to-Know Law: 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) Propane (CAS 74-98-6) US. Rhode Island RTK Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65: California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |02-25-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.