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SDS Sheet 0066280Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol Product Name: SP856 Insect Repellant II Aerosol CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Not applicable. 1.3. Name, Address, and Telephone of the Responsible Party Company: Sprayon Products Cleveland, OH 44115 Phone: (800)247-3266, (216)566-2902 1.4. Emergency Telephone Number Emergency | (216) 566-2917, (800)424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) FLAMMABLE |Category 1 AEROSOLS | GASES UNDER |Compressed gas PRESSURE | SKIN |Category 2 CORROSION/IRRI| TATION | SERIOUS EYE |Category 2A DAMAGE/ EYE | IRRITATION | SPECIFIC |Category 3 TARGET ORGAN | TOXICITY | (SINGLE | EXPOSURE) | (Respiratory | tract | irritation and| Narcotic | effects) | SPECIFIC |Category 2 TARGET ORGAN | TOXICITY | (REPEATED | EXPOSURE) | ASPIRATION |Category 1 HAZARD | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. |Contains gas under pressure; may explode if heated. |Causes serious eye irritation. |Causes skin irritation. |May be fatal if swallowed and enters airways. |May cause respiratory irritation. |May cause drowsiness and dizziness. |May cause damage to organs through prolonged or |repeated exposure. Precautionary Statements |Prevention: (GHS-US) |Wear protective gloves. Wear eye or face protection. |Keep away from heat, hot |surfaces, sparks, open flames and other ignition |sources. No smoking. Pressurized |container: Do not pierce or burn, even after use. Do |not spray on an open flame or other ignition source. |Use only outdoors or in a well-ventilated area. Do |not breathe dust or mist. Wash hands thoroughly |after handling. |Response: |Get medical attention if you feel unwell. IF |INHALED: Remove victim to fresh air and keep at rest |in a position comfortable for breathing. Call a |POISON CENTER or |physician if you feel unwell. IF SWALLOWED: |Immediately call a POISON CENTER or physician. Do |NOT induce vomiting. IF ON SKIN: Wash with plenty of |soap and water. Take off contaminated clothing. Wash |contaminated clothing before reuse. If skin |irritation occurs: Get medical attention. IF IN |EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. If eye irritation persists: |Get medical attention. |Storage: |Store locked up. Protect from sunlight. Do not |expose to temperatures exceeding 50 Â°C/122 Â°F. Store |in a well-ventilated place. |Disposal: |Dispose of contents and container in accordance with |all local, regional, national and international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) 2-Propanol |67-63-0 |37.5 | Diethyltoluamide |134-62-3 |25.0 | Butane |106-97-8 |17.1 | Propane |74-98-6 |7.9 | Propylene Glycol |57-55-6 |2.5 | Acetone |67-64-1 |2.5 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. First-aid Measures After Skin Contact: Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. First-aid Measures After Ingestion: Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use an extinguishing agent suitable for the surrounding fire. Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Explosion Hazard: Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Protection During Firefighting: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel". 6.2. Environmental Precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Small spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50Â°C. Do not pierce or burn, even after use. Do not breathe vapor or mist. Do not swallow. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits 2-Propanol Butane Propane Propylene Glycol Acetone ACGIH TLV (United States, 4/2014). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. NIOSH REL (United States, 10/2013). TWA: 400 ppm 10 hours. TWA: 980 mg/mÂ³ 10 hours. STEL: 500 ppm 15 minutes. STEL: 1225 mg/mÂ³ 15 minutes. OSHA PEL (United States, 2/2013). TWA: 400 ppm 8 hours. TWA: 980 mg/mÂ³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 800 ppm 10 hours. TWA: 1900 mg/mÂ³ 10 hours. ACGIH TLV (United States, 4/2014). STEL: 1000 ppm 15 minutes. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/mÂ³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/mÂ³ 8 hours. AIHA WEEL (United States, 10/2011). TWA: 10 mg/mÂ³ 8 hours. ACGIH TLV (United States, 4/2014). TWA: 500 ppm 8 hours. TWA: 1188 mg/mÂ³ 8 hours. STEL: 750 ppm 15 minutes. STEL: 1782 mg/mÂ³ 15 minutes. NIOSH REL (United States, 10/2013). TWA: 250 ppm 10 hours. TWA: 590 mg/mÂ³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 2400 mg/mÂ³ 8 hours. 8.2. Exposure Controls Appropriate Engineering |Use only with adequate ventilation. Use process Controls |enclosures, local exhaust ventilation or other |engineering controls to keep worker exposure to |airborne contaminants below any recommended or |statutory limits. The engineering controls also need |to keep gas, vapor or dust concentrations below any |lower explosive limits. Use explosion proof |ventilation equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Chemical-resistant, impervious gloves complying with |an approved standard should be worn at all times |when handling chemical products if a risk assessment |indicates this is necessary. Considering the |parameters specified by the glove manufacturer, |check during use that the gloves are still retaining |their protective properties. It should be noted that |the time to breakthrough for any glove material may |be different for different glove manufacturers. In |the case of mixtures, consisting of several |substances the protection time of the gloves cannot |be accurately estimated. Eye Protection |Safety eyewear complying with an approved standard |should be used when a risk assessment indicates this |is necessary to avoid exposure to liquid splashes, |mists, gases or dusts. If contact is possible, the |following protection should be worn unless the |assessment indicates a higher degree of protection: |chemical splash goggles. Skin and Body Protection |Personal protective equipment for the body should be |selected based on the task being performed and the |risks involved and should be approved by a |specialist before handling this product. When there |is a risk of ignition from static electricity, wear |antistatic protective clothing. For the greatest |protection from static discharges, clothing should |include anti-static overalls, boots and gloves. |Other skin protection : Appropriate footwear and any |additional skin protection measures should be |selected based on the task being performed and the |risks involved and should be approved by a |specialist before handling this product. Respiratory Protection |Use a properly fitted, air-purifying or air-fed |respirator complying with an approved standard if a |risk assessment indicates this is necessary. |Respirator selection must be based on known or |anticipated exposure levels, the hazards of the |product and the safe working limits of the selected |respirator. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Not available. Odor Threshold |Not available. pH |7 Relative Evaporation Rate |5.6 (butyl acetate = 1) (butylacetate=1) | Melting Point |Not available. Freezing Point | Boiling Point |Not available. Flash Point |Closed cup: -29Â°C (-20.2Â°F) [Pensky-Martens |Closed Cup] Auto-ignition Temperature |Not available. Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |13.5 kPa (101.325 mm Hg) [at 20Â°C] Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity | Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Kinematic (room temperature): <0.205 cm2/s |(<20.5 cSt) |Kinematic (40Â°C (104Â°F)): <0.205 cm2/s (<20.5 |cSt) Lower Flammable Limit |Lower: 1.9% Upper Flammable Limit |Upper: 12.8% 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No specific test data related to reactivity available for this product or its ingredients. 10.2 Chemical Stability The product is stable. 10.3 Possibility of Hazardous Reactions Under normal conditions of storage and use, hazardous reactions will not occur. 10.4 Conditions to Avoid Avoid all possible sources of ignition (spark or flame). 10.5 Incompatible Materials No specific data. 10.6 Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Not available. Germ Cell Mutagenicity: Not available. Carcinogenicity: Not available. Reproductive Toxicity: Not available. Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Product/ingredient name Result Species Exposure 2-Propanol Diethyltoluamide Propylene Glycol Acetone Acute LC50 1400000 ?g/l Marine water Acute LC50 4200 mg/l Fresh water Acute EC50 75 ppm Fresh water Acute LC50 71.25 ppm Fresh water Acute EC50 >110 ppm Fresh water Acute LC50 1020000 ?g/l Fresh water Acute LC50 710000 ?g/l Fresh water Acute EC50 20.565 mg/l Marine water Acute LC50 6000000 ?g/l Fresh water Acute LC50 10000 ?g/l Fresh water Acute LC50 5600 ppm Fresh water Chronic NOEC 4.95 mg/l Marine water Chronic NOEC 0.016 ml/L Fresh water Chronic NOEC 0.1 ml/L Fresh water Chronic NOEC 5 ?g/l Marine water Crustaceans - Crangon crangon Fish - Rasbora heteromorpha Daphnia - Daphnia magna Fish - Oncorhynchus mykiss Daphnia - Daphnia magna Crustaceans - Ceriodaphnia dubia Fish - Pimephales promelas Algae - Ulva pertusa Crustaceans - Gammarus pulex Daphnia - Daphnia magna Fish - Poecilia reticulata Algae - Ulva pertusa Crustaceans - Daphniidae Daphnia - Daphnia magna - Neonate Fish - Gasterosteus aculeatus -Larvae 48 hours 96 hours 48 hours 96 hours 48 hours 48 hours 96 hours 96 hours 48 hours 48 hours 96 hours 96 hours 21 days 21 days 42 days 12.2. Persistence and Degradability Product/ingredient name Aquatic half-life Photolysis Biodegradability 2-Propanol Propylene Glycol Acetone - - - - - - Readily Readily Readily 12.3. Bioaccumulative Potential Product/ingredient name LogPow BCF Potential Diethyltoluamide - 2.4 low 12.4. Mobility in Soil Not available. 12.5. Other Adverse Effects No known significant effects or critical hazards. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |AEROSOLS Hazard Class |2.1 |<PICTOGRAM PHRASE> | |[pic] | | Identification Number|UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | |[pic] Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, flammable Identification Number|UN1950 |<PICTOGRAM PHRASE> | |[pic] Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) | 15.2 US State Regulations California Prop. 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |5/22/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.