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SDS Sheet 0066221Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: 15 OZ SW ULTRA LOW VOC BRAKE CLNR 12PK CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States General Assistance 1-630-628-3000 1.4. Emergency Telephone Number Emergency | 1-866-836-8855, Outside US 1-952-852-4646 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable aerosols |Category 1 Serious eye damage/eye |Category 2A irritation | Sensitization, skin |Category 1 Reproductive toxicity |Category 2 (the unborn child) | Specific target organ |Category 3 toxicity, single | exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. May cause an allergic |skin reaction. Causes serious eye irritation. May |cause drowsiness or dizziness. Suspected of damaging |the unborn child. Precautionary Statements |Prevention: Obtain special instructions before use. (GHS-US) |Do not handle until all safety precautions have been |read and understood. Keep away from heat/sparks/open |flames/hot surfaces. - No smoking. Do not spray on |an open flame or other ignition source. Pressurized |container: Do not pierce or burn, even after use. |Avoid breathing gas. Wash thoroughly after handling. |Use only outdoors or in a well-ventilated area. |Contaminated work clothing must not be allowed out |of the workplace. Wear protective gloves/protective |clothing/eye protection/face protection. |Response: If on skin: Wash with plenty of water. If |inhaled: Remove person to fresh air and keep |comfortable for breathing. If in eyes: Rinse |cautiously with water for several minutes. Remove |contact lenses, if present and easy to do. Continue |rinsing. If exposed or concerned: Get medical |advice/attention. Call a poison center/doctor if you |feel unwell. Specific treatment (see this label). If |skin irritation or rash occurs: Get medical |advice/attention. If eye irritation persists: Get |medical advice/attention. Wash contaminated clothing |before reuse. |Storage: Store in a well-ventilated place. Keep |container tightly closed. Store locked up. Protect |from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. |Disposal: Dispose of contents/container in |accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None Known 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Acetone |67-64-1 |60 - 80 | Methyl Acetate |79-20-9 |10 - 20 | Carbon Dioxide |124-38-9 |2.5 - 10| Xylene |1330-20-7 |2.5 - 10| n-Heptane |142-82-5 |1 - 2.5 | d-Limonene |5989-27-5 |0.1 - 1 | Toluene |108-88-3 |0.1 - 1 | Other components below | |2.5 - 10| reportable levels | | | *Designates that a specific | | | chemical identity and/or | | | percentage of composition has | | | been withheld as a trade secret.| | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: In case of eczema or other skin disorders: Seek medical attention and take along these instructions. First-aid Measures After Eye Contact: Rinse with water. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Rinse mouth. Get medical attention if symptoms occur. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Dermatitis. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Rash. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an allergic skin reaction. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Powder. Alcohol resistant foam. Carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. Extremely flammable aerosol. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods: Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent product from entering drains. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid breathing gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Pregnant or breastfeeding women must not handle this product. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Level 2 Aerosol. Storage Conditions: Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Carbon Dioxide (CAS 124-38-9) PEL 9000 mg/m3 5000 ppm Methyl Acetate (CAS 79-20-9) PEL 610 mg/m3 200 ppm n-Heptane (CAS 142-82-5) PEL 2000 mg/m3 500 ppm Xylene (CAS 1330-20-7) PEL 435 mg/m3 100 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) Components Type Value Toluene (CAS 108-88-3) Ceiling 300 ppm TWA 200 ppm US. ACGIH Threshold Limit Values Components Type Value Acetone (CAS 67-64-1) STEL 750 ppm TWA 500 ppm Carbon Dioxide (CAS 124-38-9) STEL 30000 ppm TWA 5000 ppm Methyl Acetate (CAS 79-20-9) STEL 250 ppm TWA 200 ppm n-Heptane (CAS 142-82-5) STEL 500 ppm TWA 400 ppm Toluene (CAS 108-88-3) TWA 20 ppm Xylene (CAS 1330-20-7) STEL 150 ppm TWA 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Acetone (CAS 67-64-1) TWA 590 mg/m3 250 ppm Carbon Dioxide (CAS 124-38-9) STEL 54000 mg/m3 30000 ppm TWA 9000 mg/m3 5000 ppm Methyl Acetate (CAS 79-20-9) STEL 760 mg/m3 250 ppm TWA 610 mg/m3 200 ppm n-Heptane (CAS 142-82-5) Ceiling 1800 mg/m3 440 ppm TWA 350 mg/m3 85 ppm Toluene (CAS 108-88-3) STEL 560 mg/m3 150 ppm TWA 375 mg/m3 100 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Acetone (CAS 67-64-1) 50 mg/l Acetone Urine * Toluene (CAS 108-88-3) 0.3 mg/g o-Cresol, with hydrolysis Creatinine in * 0.03 mg/l Toluene Urine * 0.02 mg/l Toluene Blood * Xylene (CAS 1330-20-7 1.5 g/g Methylhippuric acids Creatinine in urine * Exposure guidelines US - California OELs: Skin designation Toluene (CAS 108-88-3) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Toluene (CAS 108-88-3) Skin designation applies. 82. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Provide |eyewash station. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear appropriate chemical resistant gloves. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear appropriate chemical resistant clothing. Use of |an impervious apron is recommended. Respiratory Protection |If permissible levels are exceeded use NIOSH |mechanical filter / organic vapor cartridge or an |air-supplied respirator. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Gas. Appearance | Odor |Not available. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |119.07 Â°F (48.37 Â°C) estimated Flash Point |15.8 Â°F (-9.0 Â°C) estimated Auto-ignition Temperature |851 Â°F (455 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |4753.91 psig @70F estimated Relative Vapor Density at 20 Â°C |Not available. Relative Density |Not available. Specific Gravity |0.859 estimated Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |3.1 % estimated Upper Flammable Limit |16 % estimated 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions Hazardous polymerization does not occur. 10.4 Conditions to Avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5 Incompatible Materials Strong acids. Acids. Strong oxidizing agents. Nitrates. Aluminum. Halogens. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Narcotic effects. May cause an allergic skin reaction. Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Not available. Skin sensitization: May cause an allergic skin reaction. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: Risk of cancer cannot be excluded with prolonged exposure. Reproductive Toxicity: Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. Suspected of damaging the unborn child. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Not likely, due to the form of the product. Symptoms/Injuries After Inhalation: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: May cause an allergic skin reaction. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Expected to be a low ingestion hazard. Chronic Symptoms: Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Harmful to aquatic life with long lasting effects. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. Acetone -0.24 d-Limonene 4.232 Methyl Acetate 0.18 n-Heptane 4.66 Toluene 2.73 Xylene 3.12 - 3.2 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Additional Information: Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company. US RCRA Hazardous Waste U List: Reference Acetone (CAS 67-64-1) U002 Toluene (CAS 108-88-3) U220 Xylene (CAS 1330-20-7) U239 Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, (each not exceeding 1 L capacity) Hazard Class |2.1 |<PICTOGRAM PHRASE>[pic] Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes |2.1 |<PICTOGRAM PHRASE>[pic] ntification Of The | | Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable Identification Number|UN1950 |<PICTOGRAM PHRASE>[pic] Hazard Class |2.1 | Label Codes |2.1 | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Listed. Toluene (CAS 108-88-3) Listed. Xylene (CAS 1330-20-7) Listed. SARA 304 Emergency release notification: Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 302 Extremely hazardous substance Not listed. SARA 313 (TRI reporting) Chemical name CAS number % by wt. Xylene 1330-20-7 2.5 - 10 Ethyl Benzene 100-41-4 0.1 - 1 Toluene 108-88-3 0.1 - 1 Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Toluene (CAS 108-88-3) Xylene (CAS 1330-20-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Toluene (CAS 108-88-3) 6594 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Toluene (CAS 108-88-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |All components are on the U.S. EPA TSCA |Inventory List. 15.2 US State Regulations <COMPONENT> US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Carbon Dioxide (CAS 124-38-9) Methyl Acetate (CAS 79-20-9) n-Heptane (CAS 142-82-5) Toluene (CAS 108-88-3) Xylene (CAS 1330-20-7) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Carbon Dioxide (CAS 124-38-9) Methyl Acetate (CAS 79-20-9) n-Heptane (CAS 142-82-5) Toluene (CAS 108-88-3) Xylene (CAS 1330-20-7) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Carbon Dioxide (CAS 124-38-9) Methyl Acetate (CAS 79-20-9) n-Heptane (CAS 142-82-5) Toluene (CAS 108-88-3) Xylene (CAS 1330-20-7) US. Rhode Island RTK Acetone (CAS 67-64-1) Toluene (CAS 108-88-3) Xylene (CAS 1330-20-7) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Ethyl Benzene (CAS 100-41-4) Listed: June 11, 2004 US - California Proposition 65 - CRT: Listed date/Developmental toxin Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.