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SDS Sheet 0065830Printer Friendly View
Safety Data Sheet Date of Issue: 12/16/2014 |Revision Date: |Revision Number: 01 Imperial Supplies Part Number: 0065830 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Aerosol. Product Name: Speedy-CleanÂ® RESCUE 911 Multi-Purpose Instant Leak Sealer - Black CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Coating 1.3. Name, Address, and Telephone of the Responsible Party Company Name: FastServ Supply 4060 E. Plano Parkway Plano,TX 75074 USA Phone: 800-527-4126 1.4. Emergency Telephone Number Emergency |INFOTRAC 1-800-535-5053 (US & Canada) number |1-352-323-3500 (International) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2A damage/eye | irritation | Carcinogenicit|Category 2 y | Reproductive |Category 2 toxicity (the | unborn child) | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Specific |Category 2 target organ | toxicity, | repeated | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 2 the aquatic | environment, | acute hazard | Hazardous to |Category 2 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Health |Exclamat|Environm| | | |Hazard |ion Mark|ent | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. May be fatal if |swallowed and enters airways. Causes skin |irritation. Causes serious eye irritation. May |cause drowsiness or dizziness. Suspected of causing |cancer. Suspected of damaging the unborn child. May |cause damage to organs through prolonged or |repeated exposure. Toxic to aquatic life. Toxic to |aquatic life with long lasting effects. Precautionary Statements |Prevention: (GHS-US) |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Keep away from heat/sparks/open |flames/hot surfaces. - No smoking. Do not spray on |an open flame or other ignition source. Pressurized |container: Do not pierce or burn, even after use. |Do not breathe mist or vapor. Wash thoroughly after |handling. Use only outdoors or in a well-ventilated |area. Avoid release to the environment. Wear |protective gloves/protective clothing/eye |protection/face protection. |Response: |If swallowed: Immediately call a poison |center/doctor. If on skin: Wash with plenty of |water. If inhaled: Remove person to fresh air and |keep comfortable for breathing. If in eyes: Rinse |cautiously with water for several minutes. Remove |contact lenses, if present and easy to do. Continue |rinsing. If exposed or concerned: Get medical |advice/attention. Call a poison center/doctor if you |feel unwell. Specific treatment (see this label). Do |NOT induce vomiting. If skin irritation occurs: Get |medical advice/attention. If eye irritation |persists: Get medical advice/attention. Take off |contaminated clothing and wash before reuse. Collect |spillage. |Storage: |Store in a well-ventilated place. Keep container |tightly closed. Store locked up. Protect from |sunlight. Do not expose to temperatures exceeding |50Â°C/122Â°F. |Disposal: |Dispose of contents/container in accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None Known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Acetone |67-64-1 |10-20 | Dimethyl Ether |115-10-6 |10-20 | Heptane, branched, cyclic and |426260-76-6 |10-20 | linear | | | Propane |74-98-6 |10-20 | Toluene |108-88-3 |10-20 | Isobutane |75-28-5 |2.5-10 | n-Heptane |142-82-5 |2.5-10 | Carbon Black |1333-86-4 |0.1 -1 | Methyl Isobutyl Ketone |108-10-1 |0.1 - 1 | Mineral Spirits |8052-41-3 |0.1 - 1 | Other components below | |10-20 | reportable levels | | | *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol resistant foam. Dry powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use waterjet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. Explosion Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Firefighting Instructions: Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, orflames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area ifthe leak is irreparable. Coverwith plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Methods for Cleaning Up: Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Forwaste disposal, see section 13 ofthe SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not breathe mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Pregnant or breastfeeding women must not handle this product. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 2 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Eye wash facilities |and emergency shower must be available when handling |this product. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear appropriate chemical resistant gloves. Eye Protection |Chemical respirator with organic vapor cartridge and |full facepiece. Skin and Body Protection | Respiratory Protection |Chemical respirator with organic vapor cartridge and |full facepiece. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Not available. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |180.25 Â°F (82.36 Â°C) estimated Flash Point |34.3Â°F(1.3Â°C) estimated Auto-ignition Temperature |761.64 Â°F (405.36 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |3738.61 psig @70F estimated Relative Vapor Density at 20 Â°C | Relative Density |0.725 g/cm3 estimated Specific Gravity |0.725 estimated Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |1.6 % estimated Upper Flammable Limit |14.3 % estimated 9.2. Other Information Density |0.72 g/cm3 estimated Flammability class |Flammable IB estimated Heat of combustion |19.75 kJ/g estimated Heat of combustion (NFPA 30B) |23.89 kJ/g estimated Percent volatile |62.13 % estimated VOC (Weight %) |63.53 % estimated SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions Hazardous polymerization does not occur. 10.4 Conditions to Avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Narcotic effects. Components Species Test Results Acetone (CAS 67-64-1) Acute Dermal LD50 Guinea pig > 7426 mg/kg, 24 Hours > 9.4 ml/kg, 24 Hours Rabbit > 7426 mg/kg, 2 4 Hours > 9.4 ml/kg, 24 Hours Inhalation LC50 Rat 55700 ppm, 3 Hours 132 mg/l, 3 Hours 50.1 mg/l Oral LD50 Rat 5800 mg/kg 2.2 ml/kg Carbon Black (CAS 1333-86-4) Acute Oral LD50 Rat > 8000 mg/kg Dimethyl Ether (CAS 115-10-6) Acute Inhalation NOEL Rat 2 ppm, 6 Hours Oral LD50 Rat 460 mg/kg Isobutane (CAS 75-28-5) Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l Methyl Isobutyl Ketone (CAS 108-10-1) Acute Inhalation LC50 Rat 2000 - 4000 ppm, 4 Hours Oral LD50 Rat 2.08 g/kg n-Heptane (CAS 142-82-5) Acute Dermal LD50 Rabbit > 2000 mg/kg, 24 Hours Inhalation LC50 Rat > 29.29 mg/l, 4 Hours Propane (CAS 74-98-6)Acute Acute Inhalation LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l 658 mg/l/4h Toluene (CAS 108-88-3) Acute Dermal LD50 Rabbit > 5000 mg/kg, 24 Hours Inhalation LC50 Mouse 6405 - 7436 ppm, 6 Hours 5320 ppm, 8 Hours Rat 5879 - 6281 ppm, 6 Hours 12.5-28.8 mg/l,4Hours Oral LD50 Rat 5000 mg/kg Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0 . 1% are mutagenic or genotoxic. Carcinogenicity: Suspected of causing cancer. Reproductive Toxicity: Suspected of damaging the unborn child. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Chronic Symptoms: Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. May cause damage to organs through prolonged or repeated exposure. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Toxic to aquatic life with long lasting effects. Components Species Test Results Acetone (CAS 67-64-1) Aquatic Crustacea EC50 Water flea (Daphnia magna) 21.6 - 23.9 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 4740 - 6330 mg/l, 96 hours Dimethyl Ether (CAS 115-10-6) Aquatic Crustacea EC50 Water flea (Daphnia magna) 4.3 - 7.8 mg/l, 48 hours Fish LC50 Striped bass (Morone saxatilis) 10.302- 16.743 mg/l, 96 hours Methyl Isobutyl Ketone (CAS 108-10-1) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 492 - 593 mg/l, 96 hours n-Heptane (CAS 142-82-5) Aquatic Fish LC50 Mozambique tilapia (Tilapia mossambica) 375 mg/l, 96 hours Toluene (CAS 108-88-3) Aquatic Algae IC50 Algae 433.0001 mg/L, 72 Hours Crustacea EC50 Daphnia Water flea (Daphnia magna) 7.645 mg/L, 48 Hours 5.46 - 9.83 mg/l, 48 hours Fish LC50 Coho salmon,silver salmon (Oncorhynchus kisutch) 8.11 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable, (each not exceeding 1 L capacity) Hazard Class |2.1 |[pic] Identification Number|UN1950 | Label Codes |None | ERG Number | 14.2 In Accordance with IMDG Proper Shipping |AEROSOLS Name | Hazard Class |2.1 Identification |UN1950 Number | Label Codes |None |[pic] ntification Of The | | Substance/m | | EmS-No. (Fire) |D | EmS-No. (Spillage) |U | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable Identification Number|UN1950 |[pic] Hazard Class |2.1 | Label Codes |None | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not Regulated. 15.2 US State Regulations US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Carbon Black (CAS 1333-86-4) Dimethyl Ether (CAS 115-10-6) Isobutane (CAS 75-28-5) Methyl Isobutyl Ketone (CAS 108-10-1) Mineral Spirits (CAS 8052-41-3) n-Heptane (CAS 142-82-5) Propane (CAS 74-98-6) Toluene (CAS 108-88-3) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Carbon Black (CAS 1333-86-4) Dimethyl Ether (CAS 115-10-6) Isobutane (CAS 75-28-5) Methyl Isobutyl Ketone (CAS 108-10-1) Mineral Spirits (CAS 8052-41-3) n-Heptane (CAS 142-82-5) Propane (CAS 74-98-6) Toluene (CAS 108-88-3) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Carbon Black (CAS 1333-86-4) Dimethyl Ether (CAS 115-10-6) Isobutane (CAS 75-28-5) Methyl Isobutyl Ketone (CAS 108-10-1) Mineral Spirits (CAS 8052-41-3) n-Heptane (CAS 142-82-5) Propane (CAS 74-98-6) Toluene (CAS 108-88-3) US. Rhode Island RTK Acetone (CAS 67-64-1) Dimethyl Ether (CAS 115-10-6) Isobutane (CAS 75-28-5) Methyl Isobutyl Ketone (CAS 108-10-1) Propane (CAS 74-98-6) Toluene (CAS 108-88-3) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Carbon Black (CAS 1333-86-4) Listed: February 21, 2003 Methyl Isobutyl Ketone (CAS 108-10-1) Listed: November 4,2011 US - California Proposition 65 - CRT: Listed date/Developmental toxin Toluene (CAS 108-88-3) Listed: January 1,1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.