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SDS Sheet 0065600Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 19 OZ SW C1 PEN. COIL CLEANER LB 12PK CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company: Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States Phone: 1-630-628-3000 1.4. Emergency Telephone Number Emergency | 1-866-836-8855, 1-952-852-4646 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Serious eye |Category 2 damage/eye | irritation | Sensitization,|Category 1 skin | Hazardous to |Category 3 the aquatic | environment, | acute hazard | Hazardous to |Category 3 the aquatic | environment,lo| ng-term hazard| 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. May cause an allergic |skin reaction. Causes serious eye irritation. Precautionary Statements |Prevention (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. Do not spray on an open flame or other |ignition source. Pressurized container: Do not |pierce or burn, even after use. Avoid breathing gas. |Wash thoroughly after handling. Contaminated work |clothing must not be allowed out of the workplace. |Wear protective gloves. Wear eye/face protection. |Response If on skin: Wash with plenty of water. If |in eyes: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. Specific treatment (see |this label). If skin irritation or rash occurs: Get |medical advice/attention. If eye irritation |persists: Get medical advice/attention. Wash |contaminated clothing before reuse. |Storage |Protect from sunlight. Do not expose to temperatures |exceeding 50Â°C/122Â°F. |Disposal |Dispose of contents/container in accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Butane |106-97-8 |2.5 - 10| 2-Butoxyethanol |111-76-2 |1 - 2.5 | Diethylene Glycol Monoethyl |111-90-0 |1 - 2.5 | Ether | | | EDTA Tertrasodium Salt |64-02-8 |1 - 2.5 | Propane |74-98-6 |1 - 2.5 | d-Limonene |5989-27-5 |0.1 - 1 | Other components below | |80 - 90 | reportable levels | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: If symptoms develop move victim to fresh air. Get medical attention if symptoms persist. First-aid Measures After Skin Contact: Wash off with soap and plenty of water. If skin irritation or rash occurs: Get medical advice/attention. For minor skin contact, avoid spreading material on unaffected skin. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: In the unlikely event of swallowing contact a physician or poison control center. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: May cause allergic skin reaction. Symptoms/Injuries After Eye Contact: Irritation of eyes and mucous membranes. Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water. Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. Explosion Hazard: Extremely flammable aerosol. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods: Use standard firefighting procedures and consider the hazards of other involved materials. Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. In the event of fire and/or explosion do not breathe fumes. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Ventilate closed spaces before entering. Keep out of low areas. Pay attention to flashback. Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stay upwind. Avoid breathing gas. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Prevent entry into waterways, sewers, basements or confined areas. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Keep out of low areas. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. If possible, turn leaking containers so that gas escapes rather than liquid. Isolate area until gas has dispersed. Collect spillage. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. This material and its container must be disposed of as hazardous waste. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Ground and bond containers when transferring material. Do not re-use empty containers. Do not get this material in contact with skin. Avoid breathing gas. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Observe good industrial hygiene practices. Wash hands thoroughly after handling. Do not empty into drains. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 1 Aerosol (NFPA 30B). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value 2-Butoxyethanol (CAS 111-76-2) PEL 240 mg/m3 50 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3 1000 ppm US. ACGIH Threshold Limit Values Components Type Value 2-Butoxyethanol (CAS 111-76-2) TWA 20 ppm Butane (CAS 106-97-8) STEL 1000 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 2-Butoxyethanol (CAS 111-76-2) TWA 24 mg/m3 5 ppm Butane (CAS 106-97-8) TWA 1900 mg/m3 800 ppm Propane (CAS 74-98-6) TWA 1800 mg/m3 1000 ppm US. Workplace Environmental Exposure Level (WEEL) Guides Component Type Value Diethylene Glycol TWA 140 mg/m3 Monoethyl Ether (CAS 111-90-0) 25 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time 2-Butoxyethanol (CAS 200 mg/g Butoxyacetic Creatinine in * 111-76-2) acid (BAA), urine with hydrolysis * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. 8.2. Exposure Controls Appropriate Engineering |Good general ventilation (typically 10 air changes Controls |per hour) should be used. Ventilation rates should |be matched to conditions. If applicable, use process |enclosures, local exhaust ventilation, or other |engineering controls to maintain airborne levels |below recommended exposure limits. If exposure |limits have not been established, maintain airborne |levels to an acceptable level. Provide eyewash |station. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves. Eye Protection |Wear eye/face protection. Wear safety glasses with |side shields (or goggles). Skin and Body Protection |Other: Wear appropriate chemical resistant clothing. Respiratory Protection |If permissible levels are exceeded use NIOSH |mechanical filter / organic vapor cartridge or an |air-supplied respirator. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance |Compressed liquefied gas. Odor |Characteristic. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |212 Â°F (100 Â°C) estimated Flash Point |-156.0 Â°F (-104.4 Â°C) Propellant estimated Auto-ignition Temperature |Not available. Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |65 - 75 psig @ 70F estimated Relative Vapor Density at 20 Â°C | Relative Density |0.969 g/cm3 estimated estimated Specific Gravity |0.969 estimated estimated Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |Not available. Upper Flammable Limit |Not available. 9.2. Other Information Density: 0.94 g/cm3 estimated Flammability class: Flammable IB estimated Heat of combustion (NFPA 30B): 2.93 kJ/g estimated Percent volatile: 97.03 % estimated SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions Hazardous polymerization does not occur. 10.4 Conditions to Avoid Exposure to air. Avoid temperatures exceeding the flash point. 10.5 Incompatible Materials Oxygen. Do not mix with other chemicals. None known. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Acute LD50: 11169 mg/kg, Rat, Dermal May cause allergic skin reaction. Skin Corrosion/Irritation: Not expected to be hazardous by OSHA criteria. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Not available. Germ Cell Mutagenicity: Not expected to be hazardous by OSHA criteria. Not expected to be hazardous by WHMIS criteria. Carcinogenicity: Not expected to be hazardous by WHMIS criteria. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. d-Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive Toxicity: Not expected to be hazardous by OSHA criteria. Specific Target Organ Toxicity (Single Exposure): Not classified. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Not likely, due to the form of the product. Symptoms/Injuries After Inhalation: Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: May cause an allergic skin reaction. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Expected to be a low ingestion hazard. Chronic Symptoms: Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Repeated absorption may cause disorder of central nervous system, liver, kidneys and blood. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity LC50: 557 mg/L, Fish, 96.00 Hours EC50: 959 mg/L, Daphnia, 48.00 Hours IC50: 65.75 mg/L, Algae, 72.00 Hours Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected. Product Species Test Results 19 OZ SW C1 PEN. COIL CLEANER LB 12PK (CAS Mixture) Aquatic Algae IC50 Algae 65.7535 mg/L, 72 Hours Crustacea EC50 Daphnia 959 mg/L, 48 Hours Fish LC50 Fish 557 mg/L, 96 Hours Components Species Test Results 2-Butoxyethanol (CAS 111-76-2) Aquatic Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours Diethylene Glycol Monoethyl Ether (CAS 111-90-0) Aquatic Fish LC50 Bluegill (Lepomis macrochirus) > 10000 mg/l, 96 hours d-Limonene (CAS 5989-27-5) Aquatic Crustacea EC50 Water flea (Daphnia pulex) 69.6 mg/l, 48 hours Fish LC50 Fathead minnow (Pimephales promelas) 0.619 - 0.796 mg/l, 96 hours EDTA Tertrasodium Salt (CAS 64-02-8) Aquatic Algae IC50 Algae 1.01 mg/L, 72 Hours Fish LC50 Bluegill (Lepomis macrochirus) 472 - 500 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.83 Butane 2.89 Partition coefficient n-octanol / water (log Kow) Diethylene Glycol Monoethyl Ether -0.54 d-Limonene 4.232 Propane 2.36 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Additional Information: Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable Hazard Class |2.1 |<PICTOGRAM PHRASE> | |[pic] Identification Number|UN1950 | Label Codes |None | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes |None |<PICTOGRAM PHRASE> ntification Of The | |[pic] Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable Identification Number|UN1950 |<PICTOGRAM PHRASE> | |[pic] Hazard Class |2.1 | Label Codes |2.1 | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. CERCLA Hazardous Substance List (40 CFR 302.4): Not listed. SARA 304 Emergency release notification: Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. SARA 302 Extremely hazardous substance: Chemical name CAS number Reportable Threshold Threshold Threshold quantity planning quantity planning quantity, planning quantity, lower value upper value Anhydrous Ammonia 7664-41-7 100 500 lbs Benzyl chloride 100-44-7 100 500 lbs SARA 313 (TRI reporting): Not regulated. Other federal regulations: Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - No |Delayed Hazard - No |Fire Hazard - No |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |TSCA Section 12(b) Export Notification (40 |CFR 707, Subpt. D) |Not regulated. 15.2 US State Regulations <COMPONENT> US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. Pennsylvania Worker and Community Right-to-Know Law 2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. Rhode Island RTK Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65: California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance: Benzyl chloride (CAS 100-44-7) Listed: January 1, 1990 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.