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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 135EA HEAVY DUTY RUBBERIZED UNDERCOATING 16OZ AE CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Undercoating - Aerosol 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Phone: (877) 376-2839 1.4. Emergency Telephone Number Emergency |Chem-Tel: 800-255-3924 number |International Emergency: 00+1+ 813-248-0585 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Reproductive |Category 2 toxicity | Specific |Category 1 target organ | toxicity | (repeated | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Flame Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Causes skin irritation |Suspected of damaging fertility or the unborn child |Causes damage to organs through prolonged or |repeated exposure |May be fatal if swallowed and enters airways |Extremely flammable aerosol Precautionary Statements |Prevention (GHS-US) |Obtain special instructions before use |Do not handle until all safety precautions have been |read and understood |Use personal protective equipment as required |Wash face, hands and any exposed skin thoroughly |after handling |Do not breathe dust/fume/gas/mist/vapors/spray |Do not eat, drink or smoke when using this product |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use |Response |IF exposed or concerned: Get medical |advice/attention |Specific treatment (see supplemental first aid |instructions on this label) |IF ON SKIN: Wash with plenty of soap and water |If skin irritation occurs: Get medical |advice/attention |Take off contaminated clothing and wash before reuse | |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |Storage |Store locked up |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F |Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: - Harmful to aquatic life with long lasting effects. - The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % w/w 1,3-butadiene (EINECS No. 203-450-8). If the substance is not classified as a carcinogen or mutagen, at least the S-phrases (2-)9-16 (Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3. - The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 % w/w benzene (EINECS No 200-753-7). Unknown acute toxicity: 37.5 % of the mixture consists of ingredient(s) of unknown toxicity. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) PETROLEUM GASES, LIQUEFIED, |68476-86-8 |10 - 30 | SWEETENED | | | ASPHALT, OXIDIZED |64742-93-4 |10 - 30 | TOLUENE |108-88-3 |7 - 13 | STODDARD SOLVENT |8052-41-3 |5 - 10 | TALC |14807-96-6 |3 - 7 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Get medical advice/attention if you feel unwell. First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See section 2 for more information. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Self-protection of the first aider: Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Note to physicians: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Carbon dioxide (CO2), Dry chemical, Foam. Unsuitable Extinguishing Media: None. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Explosion Hazard: Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Take precautionary measures against static discharges. Remove all sources of ignition. Contents under pressure. Do not puncture or incinerate cans. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions See Section 12 for additional ecological information. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Prevention of secondary hazards: Clean contaminated objects and areas thoroughly observing environmental regulations. Methods for Cleaning Up: Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Contents under pressure. Do not puncture or incinerate cans. Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store locked up. Do not expose to temperatures exceeding 50 Â°C/122 Â°F. Incompatible materials: Strong oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines: Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH TOLUENE 108-88-3 TWA: 20 ppm TWA: 200 ppm (vacated) TWA: 100 ppm (vacated) TWA: 375 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 560 mg/m3 Ceiling: 300 ppm IDLH: 500 ppm TWA: 100 ppm TWA: 375 mg/m3 STEL: 150 ppm STEL: 560 mg/m3 STODDARD SOLVENT 8052-41-3 TWA: 100 ppm TWA: 500 ppm TWA: 2900 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 525 mg/m3 IDLH: 20000 mg/m3 Ceiling: 1800 mg/m3 15 min TWA: 350 mg/m3 TALC 14807-96-6 TWA: 2 mg/m3 particulate matter containing no asbestos and <1% crystalline silica, respirable fraction (vacated) TWA: 2 mg/m3 respirable dust <1% Crystalline silica, containing no Asbestos TWA: 20 mppcf if 1% Quartz or more, use Quartz limit IDLH: 1000 mg/m3 TWA: 2 mg/m3 containing no Asbestos and <1% Quartz respirable dust Other Information: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear protective gloves and protective clothing. Respiratory Protection |Use NIOSH-approved air-purifying respirator with |organic vapor cartridge or canister, as appropriate. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid; Aerosol Appearance |Black Odor |Solvent Odor Threshold |No information available pH |No information available Relative Evaporation Rate |< 1 Butyl acetate = 1 (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |> 38 Â°C / >100 Â°F Flash Point |No information available, Gives a flame |projection at full valve opening or flashback |at any degree of valve opening Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density |1.02 Specific Gravity | Solubility |No information available Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information Softening point: No information available Molecular weight: No information available VOC Content (%): 39.5% Density: No information available Bulk density: No information available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Heat, flames and sparks. Take precautionary measures against static discharges. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides Oxides of sulfur Hydrogen sulfide SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: No information available. Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Central nervous system, Central Vascular System (CVS), Eyes, kidney, Liver, Respiratory system, Skin. Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Harmful by inhalation. Symptoms/Injuries After Skin Contact: May cause skin irritation and/or dermatitis. Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Symptoms/Injuries After Ingestion: Harmful if swallowed. Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chronic Symptoms: May cause adverse liver effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: 65 % of the mixture consists of components(s) of unknown hazards to the aquatic environment. Chemical Name Algae/aquatic plants Fish Crustacea ASPHALT, OXIDIZED 64742-93-4 56: 72 h Pseudokirchneriella subcapitata mg/L EC50 - - TOLUENE 108-88-3 433: 96 h Pseudokirchneriella subcapitata mg/L EC50 12.5: 72 h Pseudokirchneriella subcapitata mg/L EC50 static 15.22 - 19.05: 96 h Pimephales promelas mg/L LC50 flow through 12.6: 96 h Pimephales promelas mg/L LC50 static 5.89 - 7.81: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 14.1 - 17.16: 96 h Oncorhynchus mykiss mg/L LC50 static 5.8: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 11.0 - 15.0: 96 h Lepomis macrochirus mg/L LC50 static 54: 96 h Oryzias latipes mg/L LC50 static 28.2: 96 h Poecilia reticulata mg/L LC50 semi-static 50.87 - 70.34: 96 h Poecilia reticulata mg/L LC50 static 5.46 - 9.83: 48 h Daphnia magna mg/L EC50 Static 11.5: 48 h Daphnia magna mg/L EC50 TALC 14807-96-6 - 100: 96 h Brachydanio rerio g/L LC50 semi-static - 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil No information available. Chemical Name Partition coefficient PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 <=2.8 TOLUENE 108-88-3 2.65 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal of wastes: Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging: Do not reuse container. Additional Information: Contaminated packaging Do not reuse container. US EPA Waste Number: D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes TOLUENE 108-88-3 U220 Included in waste streams: F005, F024, F025, F039, K015, K036, K037, K149, K151 - U220 Chemical Name RCRA - Halogenated Organic Compounds RCRA - P Series Wastes RCRA - F Series Wastes RCRA - F Series Wastes TOLUENE 108-88-3 - - Toxic waste waste number F025 Waste description: Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution. - This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status TOLUENE 108-88-3 Toxic Ignitable SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN 1950 | Label Codes | | ERG Number |126 14.2 In Accordance with IMDG | Hazard Class |Aerosols, Limited Quantity (LQ) Identification Number|UN 1950 Label Codes |2.1 |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Consumer commodity Identification Number|ID 8000 |<PICTOGRAM PHRASE> Hazard Class |9 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |9L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Chemical Name SARA 313 - Threshold Values % TOLUENE - 108-88-3 1.0 CWA (Clean Water Act): This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances TOLUENE 108-88-3 1000 lb X X X CERCLA: This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302). Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) TOLUENE 108-88-3 1 lb - RQ 1 lb final RQ RQ 0.454 kg final RQ SARA Section 311/312 Hazard Classes |Acute health hazard |Yes |Chronic Health Hazard |Yes |Fire hazard |Yes |Sudden release of pressure hazard No |Reactive Hazard |No Toxic Substances Control Act (TSCA) |Complies 15.2 US State Regulations <COMPONENT> California Proposition 65: This product contains the following Proposition 65 chemicals. Chemical Name California Proposition 65 TOLUENE - 108-88-3 Developmental Female Reproductive U.S. State Right-to-Know Regulations: Chemical Name New Jersey Massachusetts Pennsylvania ASPHALT, OXIDIZED 64742-93-4 X - - TOLUENE 108-88-3 X X X STODDARD SOLVENT 8052-41-3 X X X TALC 14807-96-6 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |17-Jun-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.