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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: ELIMINATOR III ENGINE DEGREASER 15 OZ CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Aerosol Engine Degreaser 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Telephone: (877) 376-2839 1.4. Emergency Telephone Number Emergency |Chem-Tel: 800-255-3924 number |International Emergency: 00+1+ 813-248-0585 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 2 aerosols | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |Flammable aerosol Precautionary Statements |Prevention (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use |Storage |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F |Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Toxic to aquatic life with long lasting effects Unknown acute toxicity: 5 % of the mixture consists of ingredient(s) of unknown toxicity 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) WATER |7732-18-5 |60 - 100| ETHANOL |64-17-5 |3 - 7 | DIETHYLENE GLYCOL MONOETHYL |111-90-0 |3 - 7 | ETHER | | | PROPANE |74-98-6 |1 - 5 | CITRUS TERPENES |94266-47-4 |1 - 5 | BUTANE |106-97-8 |1 - 5 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Get medical advice/attention if you feel unwell. First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See section 2 for more information. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Self-protection of the first aider: Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Note to physicians: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Carbon dioxide (CO2), Dry chemical, Foam. Unsuitable Extinguishing Media: None. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Flammable. Keep product and empty container away from heat and sources of ignition. Explosion Hazard: Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: None. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Contents under pressure. Do not puncture or incinerate cans. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions See Section 12 for additional ecological information. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Prevention of secondary hazards: Clean contaminated objects and areas thoroughly observing environmental regulations. Methods for Cleaning Up: Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Contents under pressure. Do not puncture or incinerate cans. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Do not expose to temperatures exceeding 50 Â°C/122 Â°F. Keep away from sunlight, ignition sources and other sources of heat. Incompatible materials: Strong oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines: Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 PROPANE 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 BUTANE 106-97-8 STEL: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 Other Information: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Eyewash stations. Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear protective gloves and protective clothing. Respiratory Protection |Use NIOSH-approved air-purifying respirator with |organic vapor cartridge or canister, as appropriate. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid; Aerosol Appearance |White Odor |Citrus Odor Threshold |No information available pH |9.0 Relative Evaporation Rate |<1 Butyl acetate = 1 (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |> 38 Â°C / >100 Â°F Flash Point |No information available, No flame projection Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density |0.98 Specific Gravity | Solubility |Soluble in water Partition coefficient: |No information available n-octanol/water | Viscosity | Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information Softening point: No information available Molecular weight: No information available VOC Content (%): 9.9% Density: No information available Bulk density: No information available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: May cause skin irritation and/or dermatitis. Serious Eye Damage/Irritation: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: May cause irritation of respiratory tract. Symptoms/Injuries After Skin Contact: May cause skin irritation and/or dermatitis. Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Symptoms/Injuries After Ingestion: Ingestion may cause irritation to mucous membranes. Chronic Symptoms: May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin. Target Organ Effects: Blood, Central nervous system, Eyes, Liver, Reproductive System, Respiratory system, Skin. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 90 % of the mixture consists of components(s) of unknown hazards to the aquatic environment. Chemical Name Algae/aquatic plants Fish Crustacea ETHANOL 64-17-5 - 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 DIETHYLENE GLYCOL MONOETHYL ETHER 111-90-0 - 10000: 96 h Lepomis macrochirus mg/L LC50 static 19100 - 23900: 96 h Lepomis macrochirus mg/L LC50 flow-through 11400 - 15700: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 11600 - 16700: 96 h Pimephales promelas mg/L LC50 flow-through 13400: 96 h Salmo gairdneri mg/L LC50 flow through 3940 - 4670: 48 h Daphnia magna mg/L EC50 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil No information available. Chemical Name Partition coefficient ETHANOL 64-17-5 -0.32 DIETHYLENE GLYCOL MONOETHYL ETHER 111-90-0 -0.8 PROPANE 74-98-6 2.3 BUTANE 106-97-8 2.89 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal should be in accordance with applicable regional, national and local laws and regulations. Additional Information: Contaminated packaging: Do not reuse container. US EPA Waste Number D001 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ETHANOL 64-17-5 Toxic Ignitable SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes | | ERG Number |126 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Consumer commodity Identification Number|ID 8000 |<PICTOGRAM PHRASE> Hazard Class |9 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |9L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Chemical Name SARA 313 - Threshold Values % DIETHYLENE GLYCOL MONOETHYL ETHER - 111-90-0 1.0 CWA (Clean Water Act): This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA: This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. SARA Section 311/312 Hazard Classes |Acute health hazard |Yes |Chronic Health Hazard |No |Fire hazard |Yes |Sudden release of pressure hazard No |Reactive Hazard |No Toxic Substances Control Act (TSCA) |Complies 15.2 US State Regulations <COMPONENT> California Proposition 65: This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental U.S. State Right-to-Know Regulations: Chemical Name New Jersey Massachusetts Pennsylvania DIETHYLENE GLYCOL MONOETHYL ETHER 111-90-0 X - X ETHANOL 64-17-5 X X X PROPANE 74-98-6 X X X BUTANE 106-97-8 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |15-Jun-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.