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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Gas/Pressurized Liquid Product Name: Turtle Wax Label & Sticker Remover CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Adhesive Remover - General Purpose (Aerosol) 1.3. Name, Address, and Telephone of the Responsible Party Company Turtle Wax, Inc. 625 Willowbrook Centre Parkway Willowbrook, Illinois 60527 Phone: 1.4. Emergency Telephone Number Emergency | 1(630)455-3700, 1(630)455-3868, 1(800)424-9300 (CHEMTREC) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Serious eye |2 irritation/eye| damage | Skin |1 irritation | Aspiration |1 Toxicity | Flammable |1 aerosol | Gas under |Compressed Gas Pressure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Flame |Gas Cylinder Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Causes serious eye irritation. May cause an allergic |skin reaction. May be fatal if swallowed and enters |airways. Extremely flammable aerosol. Contains gas |under pressure and may explode if heated. Precautionary Statements |Avoid breathing mist, fumes, or vapors. Wear (GHS-US) |protective gloves clothing, and splash proof goggles |to prevent eye and skin contact. Wash hands |thoroughly, with soap and water, after handling. In |case of skin contact, remove immediately all |clothing and wash with soap and water. Launder all |clothing before re-use. If rash develops or |irritation persists, seek medical attention. If in |eyes, rinse thoroughly with water for 15 minutes. |Remove contact lenses if worn. If eye irritation |persists, seek medical attention. If swallowed, do |NOT induce vomiting. Call a poison control center or |physician immediately. Keep away from heat, sparks, |hot surfaces or open flames. Do not smoke or spray |near open flame or source of ignition. Pressurized |container: Do not puncture or incinerate. Do not |store in direct sunlight or at temperatures above |50Â°C (120Â°F). Store in a well ventilated place. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Description of additional HNOC: Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Not applicable | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Petroleum Distillites |64742-47-8 |15-40% | (Hydrotreated Light) | | | Diethylene Glycol Monobutyl |112-34-5 |10-30% | Ether | | | Propane |74-98-6 |10-30% | Acetone |67-64-1 |7-13% | D-Limonene |5989-27-5 |3-7% | Undeceth-3 |34398-01-1 |1-5% | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove to fresh air and promote deep breathing. Get medical attention if effects persist. First-aid Measures After Skin Contact: In case of skin contact, wash thoroughly with soap and water. If irritation persists, get medical attention. First-aid Measures After Eye Contact: In case of eye contact, immediately flush eyes with plenty of water. Remove contact lenses if worn. If irritation persists, get medical attention. First-aid Measures After Ingestion: If swallowed, do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if effects persist. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: May cause respiratory tract irritation. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful of fatal. Symptoms/Injuries After Skin Contact: Cause skin irritation. May cause drying, cracking, or mild dermatitis. Symptoms/Injuries After Eye Contact: May cause temporary eye irritation. Symptoms may include pain, excess blinking and tearing, redness, and swelling. Symptoms/Injuries After Ingestion: May be harmful or fatal if swallowed. May cause stomach distress, nausea, and vomiting. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Symptoms may not appear immediately. Seek medical attention if effects persist and you feel un- well. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water spray, carbon dioxide, dry chemical, and alcohol foam. NFPA Aerosol Level 3. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: CO2, CO, and hydrocarbons. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Keep up wind of fire. Wear full firefighting turn out gear (full bunker gear) and respiratory protection (SCBA). See Section 8 for personal protection. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate all source of ignition. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain and absorb spill with inert material. Place in suitable container for disposal. Spilled material may be slippery. Use appropriate Personal Protective Equipment (PPE). Methods for Cleaning Up: Take up material and place in a suitable container. Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Provide adequate ventilation. Spilled material may be slippery. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Keep away from source of ignition. Do not smoke. Avoid contact with skin and eyes. Do not swallow. Do not eat, drink or smoke while handling. Wash hands with soap and water after handling. Launder all clothing and foot wear before re-use. Do not spray near flame of open ignition source. Use out doors with good ventilation. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep out of reach of children. Store in a well ventilated place. Do not store above 49Â°C (120Â°F). Do not store near heat source or in direct sun light. 7.3. Specific End Use(s) Shelf Life: Shelf life is considered to be 7 - 10 years when properly stored. Aerosol products have been known to last much longer in storage. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Limits 8 hr TWA: (OSHA PEL) (ACGIH TWA) Petroleum Distillites (Hydrotreated Light) 5 mg/m3 Oil Mist 5 mg/m3 Oil Mist Diethylene Glycol Monobutyl Ether not available 10 ppm Propane 1000 ppm 1000 ppm Acetone 1000 ppm 500 ppm 8.2. Exposure Controls Appropriate Engineering |Use adequate ventilation to keep exposure below Controls |recommended limits. Ensure that eye wash station and |safety shower are close to work station. Personal Protective Equipment|Ingestion Protection Requirements: Do not eat, drink |or smoke while handling. Wash hands with soap and |water after handling. Launder all clothing before re |use. Materials for Protective | Clothing | Hand Protection |Wear chemical resistant gloves and clothing to |prevent skin contact. Eye Protection |Wear safety glasses or splash goggles to prevent eye |contact. Skin and Body Protection |Wear suitable protective clothing. Respiratory Protection |Provide good ventilation. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Gas/Pressurized Liquid Appearance |Clear Thin Liquid (Dispensed as clear liquid) Odor |Cherry Odor Threshold |Not available pH |Not applicable (oil based) Relative Evaporation Rate |Not available (butylacetate=1) | Melting Point |Not available Freezing Point |Not available Boiling Point |Not available Flash Point |Not available Auto-ignition Temperature |Not available Decomposition Temperature | Flammability (solid, gas) |Not applicable Vapor Pressure |Not available Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |0.808 (liquid phase) Solubility |Insoluble in Water Partition coefficient: |Not available n-octanol/water | Viscosity |Water Thin (liquid phase) Lower Flammable Limit |Not available Upper Flammable Limit |Not available 9.2. Other Information % NVM by Weight: 24.0% % VOC Content (California): 14.5% SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Does not react under normal conditions. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Does not react under normal conditions. 10.4 Conditions to Avoid Heat and incompatible materials. 10.5 Incompatible Materials Strong oxidizers such as bleach and peroxides. 10.6 Hazardous Decomposition Products CO2, CO and hydrocarbons. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation / damage. Respiratory or Skin Sensitization: Based on available data, classification data are not met. Germ Cell Mutagenicity: Based on available data, classification data are not met. Carcinogenicity: Based on available data, classification data are not met. D-Limonene: IARC Group 3 Reproductive Toxicity: Based on available data, classification data are not met. Specific Target Organ Toxicity (Single Exposure): Based on available data, classification data are not met. Specific Target Organ Toxicity (Repeated Exposure): Based on available data, classification data are not met. Aspiration Hazard: Based on available data, classification data are not met. Symptoms/Injuries After Inhalation: May cause respiratory tract irritation. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful of fatal. Symptoms/Injuries After Skin Contact: Causes skin irritation. May cause drying, cracking, or mild dermatitis. Symptoms/Injuries After Eye Contact: Cause serious eye irritation. Symptoms may include pain, excess blinking and tearing, redness, and swelling. Symptoms/Injuries After Ingestion: May be harmful or fatal if swallowed and enters airways. May cause stomach distress, nausea, and vomiting. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Not recommended for release into aquatic systems without treatment. 12.2. Persistence and Degradability Not established. 12.3. Bioaccumulative Potential Not established. 12.4. Mobility in Soil Not established. 12.5. Other Adverse Effects None known. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: RCRA Hazardous Waste: Regulated as a hazardous waste (D-001 Ignitable). Waste Disposal Method: Dispose of in accordance with local, state and federal regulations. Waste Disposal Vessel: Metal drums are recommended. Dispose of un-used aerosol cans through a registered aerosol recycler. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |All ingredients are commercially available |and listed by the manufacturer under TSCA. 15.2 US State Regulations <COMPONENT> State Regulatory Information: The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the SDS may also be applicable for state requirements. For details on your regulatory requirements, contact the appropriate agency in your state. California Prop 65: CAS Number Concentration State Code None. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |March 12, 2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.