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SDS Sheet 0065440Printer Friendly View
SECTION 1: IDENTIFICATION | |1.1. Product Identifier Product Form: Product Name: 6544-1 VANDAL MARK REMOVER-6P CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Graffiti Remover. 1.3. Name, Address, and Telephone of the Responsible Party Company American Jetway Corporation 34136 Myrtle Street Wayne, MI 48184-0126 Phone 1.4. Emergency Telephone Number Emergency | 1-800-424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Acute toxicity|Category 4 - Inhalation | (Dusts/Mists) | Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2 damage/eye | irritation | Carcinogenicit|Category 2 y | Reproductive |Category 2 Toxicity | Specific |Category 3 target organ | toxicity | (single | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | Gases under |Compressed Gas pressure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Flame |Gas Cylinder Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Hazard Statements |Harmful if inhaled |Causes skin irritation |Causes serious eye irritation |Suspected of causing cancer |Suspected of damaging fertility or the unborn child |May cause respiratory irritation. May cause |drowsiness or dizziness |May be fatal if swallowed and enters airways |Extremely flammable aerosol |Contains gas under pressure; may explode if heated Precautionary Statements |Precautionary Statements - Prevention (GHS-US) |Obtain special instructions before use |Do not handle until all safety precautions have been |read and understood |Wear protective gloves/protective clothing/eye |protection/face protection |Avoid breathing dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Wash face, hands and any exposed skin thoroughly |after handling |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use | |Precautionary Statements - Response |If exposed or concerned: Get medical |advice/attention |Specific treatment (see first aid on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water. |Take off contaminated clothing and wash before reuse | |If skin irritation occurs: Get medical |advice/attention |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting | |Precautionary Statements - Storage |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F |Precautionary Statements - Disposal | |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None . Very toxic to aquatic life with long lasting effects 0% of the mixture consists of ingredient(s) of unknown toxicity 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |%* |Classification | | |(GHS-US) XYLENE |1330-20-7 |20-30 | PROPANE/ISOBUTANE/N-BUTANE |68476-86-8 |10-20 | ETHYL BENZENE |100-41-4 |1-10 | ISOPROPYL ALCOHOL |67-63-0 |1-10 | SODIUM NITRITE |7632-00-0 |0.1-1 | TOLUENE |108-88-3 |0.1-1 | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Artificial respiration and/or oxygen may be necessary. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. First-aid Measures After Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or Poison Control Center immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Irritating to respiratory system. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes eye irritation. Symptoms/Injuries After Ingestion: Harmful or fatal. if swallowed and enters airways. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog.Dry chemical. Carbon dioxide (CO2). Cool containers/tanks with water spray. Unsuitable Extinguishing Media: Keep away from heat and sources of ignition. Do not smoke. Cool containers / tanks with water spray. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable. Keep product and empty container away from heat and sources of ignition. Risk of ignition. In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with water spray. Explosion Hazard: Sensitivity to Mechanical Impact none. Sensitivity to Static Discharge May be ignited by heat, sparks or flames. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans.Do no stick pin or any other sharp object into opening on top of can. Avoid skin contact. Use with adequate ventilation. Keep container away from heat,flames, and all other sources of ignition. Keep can away from all sources of electricity such as electric motors and batteries. Do not spray on hot surfaces. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Should not be released into the environment. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Clean contaminated surface thoroughly. After cleaning, flush away traces with water. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep in properly labeled containers. Keep out of the reach of children. Store locked up. Storage Conditions: 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH XYLENE 1330-20-7 STEL: 150 ppm TWA: 100 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m3 PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 74-98-6: TWA: 1000 ppm 106-97-8: STEL: 1000 ppm 75-28-5: STEL: 1000 ppm 74-98-6:TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 106-97-8: (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 74-98-6:IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 106-97-8:TWA: 800 ppm TWA: 1900 mg/m3 75-28-5:TWA: 800 ppm TWA: 1900 mg/m3 ETHYL BENZENE 100-41-4 TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 125 ppm (vacated) STEL: 545 mg/m3 IDLH: 800 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 ISOPROPYL ALCOHOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 TOLUENE 108-88-3 TWA: 20 ppm TWA: 200 ppm (vacated) TWA: 100 ppm (vacated) TWA: 375 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 560 mg/m3 Ceiling: 300 ppm IDLH: 500 ppm TWA: 100 ppm TWA: 375 mg/m3 STEL: 150 ppm STEL: 560 mg/m3 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Aerosol Appearance |opaque Odor |Solvent Odor Threshold |No information available pH |10.7 Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |-96.4 Â°C / -141 Â°F Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C |No information available Relative Density |No information available Specific Gravity |.908 Solubility |No information available Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%): 48.19 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Strong acids, alkalis, or oxidizing agents. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: 0% of the mixture consists of ingredient(s) of unknown toxicity Skin Corrosion/Irritation: Irritating to skin. Serious Eye Damage/Irritation: Irritating to eyes. Respiratory or Skin Sensitization: None known. Germ Cell Mutagenicity: None known. Carcinogenicity: The table below indicates whether each agency has evaluated a listed ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA XYLENE 1330-20-7 Group 3 ETHYL BENZENE 100-41-4 A3 Group 2B SODIUM NITRITE 7632-00-0 Group 2A TOLUENE 108-88-3 Group 3 Reproductive Toxicity: Product is or contains a chemical which is a known or suspected reproductive hazard. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Vapors may irritate throat and respiratory system. May cause drownsiness and dizziness based on components. May cause irritation of respiratory tract. Avoid breathing vapors or mists. Symptoms/Injuries After Skin Contact: Irritating to skin. Repeated exposure may cause skin dryness or cracking. Prolonged skin contact may defat the skin and produce dermatitis. Avoid contact with skin. Symptoms/Injuries After Eye Contact: Irritating to eyes. Avoid contact with eyes. Symptoms/Injuries After Ingestion: May be harmful if swallowed. Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates XYLENE 1330-20-7 13.1 - 16.5 mg/L LC50 Lepomis macrochirus 96h flow-through 13.5 - 17.3 mg/L LC50 Oncorhynchus mykiss 96h 2.661 - 4.093 mg/L LC50 Oncorhynchus mykiss 96h static 23.53 - 29.97 mg/L LC50 Pimephales promelas 96h static 30.26 - 40.75 mg/L LC50 Poecilia reticulata 96h static 7.711 - 9.591 mg/L LC50 Lepomis macrochirus 96h static 13.4 mg/L LC50 Pimephales promelas 96h flow-through 19 mg/L LC50 Lepomis macrochirus 96h 780 mg/L LC50 Cyprinus carpio 96h semi-static 780 mg/L LC50 Cyprinus carpio 0.6 mg/L LC50 Gammarus lacustris 48h 3.82 mg/L EC50 water flea 48h PROPANE/ISOBUTANE/NBUTANE 68476-86-8 ETHYL BENZENE 100-41-4 4.6 mg/L EC50 Pseudokirchneriella subcapitata 72h 438 mg/L EC50 Pseudokirchneriella subcapitata 96h 2.6 - 11.3 mg/L EC50 Pseudokirchneriella subcapitata 72h static 1.7 - 7.6 mg/L EC50 Pseudokirchneriella subcapitata 96h static 11.0 - 18.0 mg/L LC50 Oncorhynchus mykiss 96h static 7.55 - 11 mg/L LC50 Pimephales promelas 96h flow-through 9.1 - 15.6 mg/L LC50 Pimephales promelas 96h static 32 mg/L LC50 Lepomis macrochirus 96h static 4.2 mg/L LC50 Oncorhynchus mykiss 96h semi-static 9.6 mg/L LC50 Poecilia reticulata 96h static 1.8 - 2.4 mg/L EC50 Daphnia magna 48h ISOPROPYL ALCOHOL 67-63-0 1000 mg/L EC50 Desmodesmus subspicatus 96h 1000 mg/L EC50 Desmodesmus subspicatus 72h 11130 mg/L LC50 Pimephales promelas 96h static 9640 mg/L LC50 Pimephales promelas 96h flow-through 1400000 ?g/L LC50 Lepomis macrochirus 96h 13299 mg/L EC50 Daphnia magna 48h SODIUM NITRITE 7632-00-0 0.092 - 0.13 mg/L LC50 Oncorhynchus mykiss 96h flow-through 0.4 - 0.6 mg/L LC50 Oncorhynchus mykiss 96h semi-static 0.65 - 1 mg/L LC50 Oncorhynchus mykiss 96h static 0.19 mg/L LC50 Oncorhynchus mykiss 96h flow-through 2.3 mg/L LC50 Pimephales promelas 96h flow-through 20 mg/L LC50 Pimephales promelas 96h static TOLUENE 108-88-3 433 mg/L EC50 Pseudokirchneriella subcapitata 96h 12.5 mg/L EC50 Pseudokirchneriella subcapitata 72h static 11.0 - 15.0 mg/L LC50 Lepomis macrochirus 96h static 14.1 - 17.16 mg/L LC50 Oncorhynchus mykiss 96h static 15.22 - 19.05 mg/L LC50 Pimephales promelas 96h flow through 5.89 - 7.81 mg/L LC50 Oncorhynchus mykiss 96h flow-through 50.87 - 70.34 mg/L LC50 Poecilia reticulata 96h static 12.6 mg/L LC50 Pimephales promelas 96h static 28.2 mg/L LC50 Poecilia reticulata 96h semi static 5.8 mg/L LC50 Oncorhynchus mykiss 96h semi-static 54 mg/L LC50 Oryzias latipes 96h static 5.46 - 9.83 mg/L EC50 Daphnia magna 48h Static 11.5 mg/L EC50 Daphnia magna 48h 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. Chemical Name log Pow XYLENE 1330-20-7 3.15 PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 2.8 ETHYL BENZENE 100-41-4 3.118 ISOPROPYL ALCOHOL 67-63-0 0.05 SODIUM NITRITE 7632-00-0 -3.7 TOLUENE 108-88-3 2.65 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste Disposal Methods: It must undergo special treatment, e.g. at suitable disposal site, to comply with local regulations. Contaminated packaging: Do not re-use empty containers. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D |or |LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, FLAMMABLE Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight %* SARA 313 - Threshold Values % XYLENE - 1330-20-7 1330-20-7 20-30 1.0 ETHYL BENZENE - 100-41-4 100-41-4 1-10 0.1 ISOPROPYL ALCOHOL - 67-63-0 67-63-0 1-10 1.0 SODIUM NITRITE - 7632-00-0 7632-00-0 0.1-1 1.0 TOLUENE - 108-88-3 108-88-3 0.1-1 1.0 Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances XYLENE 1330-20-7 100 lb X ETHYL BENZENE 100-41-4 1000 lb X X X SODIUM NITRITE 7632-00-0 100 lb X TOLUENE 108-88-3 1000 lb X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ XYLENE 1330-20-7 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ ETHYL BENZENE 100-41-4 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ SODIUM NITRITE 7632-00-0 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ TOLUENE 108-88-3 1000 lb 1 lb RQ 1000 lb final RQ RQ 454 kg final RQ RQ 1 lb final RQ RQ 0.454 kg final RQ SARA Section 311/312 Hazard Classes |Acute Health Hazard |:Yes |Chronic Health Hazard |:Yes |Fire Hazard |:Yes |Sudden Release of Pressure Hazard :Yes |Reactive Hazard |:no Toxic Substances Control Act (TSCA) |Chemical Name |TSCA | |XYLENE |X | |PROPANE/ISOBUTANE/N-BUTANE |X | |ETHYL BENZENE |X | |ISOPROPYL ALCOHOL |X | |SODIUM NITRITE |X | |TOLUENE |X | 15.2 US State Regulations <COMPONENT> California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name California Prop. 65 ETHYL BENZENE - 100-41-4 Carcinogen TOLUENE - 108-88-3 Developmental Female Reproductive U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania XYLENE 1330-20-7 X X X ETHYL BENZENE 100-41-4 X X X ISOPROPYL ALCOHOL 67-63-0 X X X SODIUM NITRITE 7632-00-0 X X X TOLUENE 108-88-3 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |06-May-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.