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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: NON-CHLORINATED BRAKE & PARTS CLEANER 14.5 OZ CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Aerosol Brake Cleaner 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Phone: (877) 376-2839 1.4. Emergency Telephone Number Emergency | 800-255-3924 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Acute toxicity|Category 4 - Oral | Acute |Category 4 toxicity- | Dermal | Acute toxicity|Category 4 - Inhalation | (Dusts/Mists) | Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2 damage/eye | irritation | Specific |Category 1 target organ | toxicity | (single | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Flame Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Harmful if swallowed |Harmful in contact with skin |Harmful if inhaled |Causes skin irritation |Causes serious eye irritation |Causes damage to organs |May be fatal if swallowed and enters airways |Extremely flammable aerosol Precautionary Statements |Precautionary Statements - Prevention (GHS-US) |Wash face, hands and any exposed skin thoroughly |after handling |Do not eat, drink or smoke when using this product |Wear protective gloves/protective clothing/eye |protection/face protection |Use only outdoors or in a well-ventilated area |Do not breathe dust/fume/gas/mist/vapors/spray |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use | |Precautionary Statements - Response |IF exposed: Call a POISON CENTER or doctor/physician | |Specific treatment (see supplemental first aid |instructions on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water |Call a POISON CENTER or doctor/physician if you feel |unwell |If skin irritation occurs: Get medical |advice/attention |Take off contaminated clothing and wash before reuse | |IF INHALED: Remove victim to fresh air and keep at |rest in a position comfortable for breathing |Call a POISON CENTER or doctor/physician if you feel |unwell |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |Rinse mouth | |Precautionary Statements - Storage |Store locked up |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F | |Precautionary Statements - Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Toxic to aquatic life with long lasting effects. 2.4. Unknown Acute Toxicity (GHS-US) 7 % of the mixture consists of ingredient(s) of unknown toxicity SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |%* |Classification | | |(GHS-US) ACETONE |67-64-1 |30 - 60 | METHANOL |67-56-1 |10 - 30 | HEPTANE |142-82-5 |10 - 30 | XYLENE |1330-20-7 |5 - 10 | CARBON DIOXIDE |124-38-9 |5 - 10 | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Get medical advice/attention if you feel unwell. First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Note to physicians: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Carbon dioxide (CO2), Dry chemical, Foam Unsuitable Extinguishing Media: None. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable. Vapors may travel to areas away from work site before igniting/flashing back to vapor source. Explosion Hazard: Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Use personal protective equipment as required. Remove all sources of ignition. Contents under pressure. Do not puncture or incinerate cans. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Handle in accordance with good industrial hygiene and safety practice. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Remove all sources of ignition. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not puncture or incinerate cans. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 METHANOL 67-56-1 STEL: 250 ppm TWA: 200 ppm S* TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 HEPTANE 142-82-5 STEL: 500 ppm TWA: 400 ppm TWA: 500 ppm TWA: 2000 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 1600 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 2000 mg/m3 IDLH: 750 ppm Ceiling: 440 ppm 15 min Ceiling: 1800 mg/m3 15 min TWA: 85 ppm TWA: 350 mg/m3 XYLENE 1330-20-7 STEL: 150 ppm TWA: 100 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m3 CARBON DIOXIDE 124-38-9 STEL: 30000 ppm TWA: 5000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 (vacated) TWA: 10000 ppm (vacated) TWA: 18000 mg/m3 (vacated) STEL: 30000 ppm (vacated) STEL: 54000 mg/m3 IDLH: 40000 ppm TWA: 5000 ppm TWA: 9000 mg/m3 STEL: 30000 ppm STEL: 54000 mg/m3 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear protective gloves and protective clothing. Respiratory Protection |Use NIOSH-approved air-purifying respirator with |organic vapor cartridge or canister, as appropriate. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Clear Odor |Solvent Odor Threshold |No information available PH |No information available Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |55-149 Â°C / 132- 300 Â°F Flash Point |< -18 Â°C / < 0 Â°F (Gives a flame projection |at full valve opening or |flashback at any degree of valve opening) Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C |>1 Air = 1 Relative Density |0.8 Specific Gravity | Solubility |Slightly soluble Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |12.8% Upper Flammable Limit |2.6% 9.2. Other Information Softening point No information available Molecular weight No information available VOC Content (%) 102.5 Density No information available Bulk density No information available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Heat, flames and sparks. Temperatures >50 Â°C / 122 Â°F. 10.5 Incompatible Materials Strong oxidizing agents, Amines 10.6 Hazardous Decomposition Products Carbon oxides SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: May cause skin irritation and/or dermatitis. Serious Eye Damage/Irritation: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Respiratory or Skin Sensitization: Harmful by inhalation. Germ Cell Mutagenicity: No information available Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen. Reproductive Toxicity: Chemical Name ACGIH IARC NTP OSHA XYLENE 1330-20-7 Group 3 Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Harmful by inhalation. Symptoms/Injuries After Skin Contact: May cause skin irritation and/or dermatitis. Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Symptoms/Injuries After Ingestion: Harmful if swallowed. Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Algae/aquatic plants Fish Crustacea ACETONE 67-64-1 4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 METHANOL 67-56-1 static HEPTANE 142-82-5 375.0: 96 h Cichlid fish mg/L LC50 10: 24 h Daphnia magna mg/L EC50 XYLENE 1330-20-7 13.4: 96 h Pimephales promelas mg/L LC50 flow-through 2.661 - 4.093: 96 h Oncorhynchus mykiss mg/L LC50 static 13.5 - 17.3: 96 h Oncorhynchus mykiss mg/L LC50 13.1 - 16.5: 96 h Lepomis macrochirus mg/L LC50 flow-through 19: 96 h Lepomis macrochirus mg/L LC50 7.711 - 9.591: 96 h Lepomis macrochirus mg/L LC50 static 23.53 - 29.97: 96 h Pimephales promelas mg/L LC50 static 780: 96 h Cyprinus carpio mg/L LC50 semi-static 780: 96 h Cyprinus carpio mg/L LC50 30.26 - 40.75: 96 h Poecilia reticulata mg/L LC50 static 3.82: 48 h water flea mg/L EC50 0.6: 48 h Gammarus lacustris mg/L LC50 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil No information available. 12.5. Other Adverse Effects No information available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal of wastes: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging: Do not reuse container. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|1950 | Label Codes | | ERG Number |126 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 Identification Number|ID 8000 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |D | EmS-No. (Spillage) |U | 14.3 In Accordance with IATA Proper Shipping Name |Consumer commodity Identification Number|1950 |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |9L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % METHANOL - 67-56-1 1.0 XYLENE - 1330-20-7 1.0 CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances XYLENE 1330-20-7 100 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ METHANOL 67-56-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ XYLENE 1330-20-7 RQ 100 lb final RQ RQ 45.4 kg final RQ SARA Section 311/312 Hazard Classes |Acute health hazard |Yes |Chronic Health Hazard |Yes |Fire hazard |Yes |Sudden release of pressure hazard No |Reactive Hazard |No Toxic Substances Control Act (TSCA) |Complies 15.2 US State Regulations <COMPONENT> California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 METHANOL - 67-56-1 Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ACETONE 67-64-1 X X X METHANOL 67-56-1 X X X HEPTANE 142-82-5 X X X XYLENE 1330-20-7 X X X CARBON DIOXIDE 124-38-9 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |08-Jun-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.