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MATERIAL SAFETY DATA SHEET Non-Chlorinated Brake Cleaner - Not VOC Compliant HEALTH 2 FLAMMABILITY 3 Printed: 12/10/2007 FLAMMABILITY 3 INSTABILITY 0 Revision: 03/12/2007 REACTIVITY 0 HEALTH 2 Date Created: 03/12/2007 PPE B SPECIAL 6534-8 & 6534 12 Packs 6534-9 & 6 Packs 1. Product and Company Identification Product Code: GSC-0017-07 Product Name: Non-Chlorinated Brake Cleaner - Not VOC Compliant Referece #: CRC-EXP 88 Manufacturer Information Company Name: Excelda Manufacturing 12785 Emerson Dr. Brighton, MI 48116 Emergency Contact: MEDICAL EMERGENCY (888)314-4052 Atlernate Emergency Contact: DOT EMERGENCY (800)424-9300 Information: INFORMATION (248)486-3800 2. Composition/Information on Ingredients Hazardous Components CAS# Concentration OSHA ACGIH Other (Chemical Name) TWA TWA Limits 1.Toluene 108-88-3 33.0 -43.0 % 200 ppm 50 ppm No data. 2.Acetone 67-64-1 17.0 -27.0 % 1000 ppm 500 ppm No data. 3.Carbon dioxide 124-38-9 <10.0 % 5000 ppm 5000 ppm No data. 4.Methanol 67-56-1 26.0 -36.0 % 200 ppm 200 ppm No data. 5.2,2-Dimethoxypropane 77-76-9 < 5.0 % No data. No data. No data. Hazardous Components RTECS # OSHA STEL OSHA CEIL ACGIH STEL ACGIH CEIL (Chemical Name) 1.Toluene XS5250000 500 ppm/(10min) 300 ppm No data. No data. 2.Acetone AL3150000 No data. No data. 750 ppm No data. 3.Carbon dioxide FF6400000 No data. No data. 30,000 ppm No data. 4.Methanol PC1400000 No data. No data. 250 ppm No data. 5.2,2-Dimethoxypropane NA No data. No data. No data. No data. 3. Hazards Identification Emergency Overview Danger: Extremely Flammable. Vapor Harmful. Harmful or Fatal if Swallowed. May be fatal or cause blindness if swallowed. Eye & skin irritant. Contents under pressure. Route(s) of Entry: Inhalation? Yes Skin? Yes Eyes? Yes Ingestion? N.A. Potential Health Effects (Acute and Chronic) Inhalation: Dizziness, breathing difficulties, anesthetic effects, nausea and irritation to respiratory tract. Eyes: Irritation Skin: Irritation, contact dermatitis, and possible defatting of the skin. Ingestion: Aspiration hazard. May cause irritation to the gastrointestinal tract. Chronic overexposure may cause nervous damage. Signs and Symptoms Of Exposure Inhalation: Dizziness, breathing difficulties, anesthetic effects, nausea and irritation. Eyes: Irritation Skin: Irritation, redness Ingestion: Irritation of the gastrointestinal tract, or other discomfort. Medical Conditions Generally Aggravated By Exposure Breathing Problems OSHA Hazard Classes: HEALTH HAZARDS : Irritant PHYSICAL HAZARDS : Compressed Gas, Flammable Gas TARGET ORGANS & EFFECTS: Eyes, Skin, Central Nervous System, Respiratory System 4. First Aid Measures Emergency and First Aid Procedures Inhalation: Remove to fresh air. Give artificial respiration if necessary. Eyes: Flush with large amounts of water for 15 minutes. Skin: Remove contaminated clothing and wash area with soap and water. Ingestion: Call a physician. Do not induce vomiting. 5. Fire Fighting Measures Flash Pt. < 0.00 F (-17.8 C) Method Used: TCC Explosive Limits: LEL: No data. UEL: No data. Fire Fighting Instructions Remove containers from fire area if possible. Use self-contained breathing apparatus for fire fighting. Use water spray to keep containers cool. Flammable Properties and Hazards Contents under pressure. Exposure to heat may cause containers to burst releasing flammable components. Both liquid and gas components of this product are flammable. Flashpoint of the liquid component is below ambient temperatures. Hazardous Combustion Products CO2, carbon monoxide Extinguishing Media CO2, foam and fog Unsuitable Extinguishing Media No data available. 6. Accidental Release Measures Steps To Be Taken In Case Material Is Released Or Spilled Usually not a problem with aerosols. Area should be ventilated. Absorbent should be used to pick up excess liquid material. All used and unused product should be disposed of in accordance with federal, state and local regulations. 7. Handling and Storage Precautions To Be Taken in Handling Do not use near sources of heat, sparks or open flame. Precautions To Be Taken in Storing Store in a cool, dry area. Aerosol cans must be maintained below 120Â°F to prevent cans from exploding. Keep out of reach of children. 8. Exposure Controls/Personal Protection Respiratory Equipment (Specify Type) Use NIOSH/MSHA compliant respirators or self-contained breathing apparatus above exposure limits. Follow OSHA regulations 29CFR 1910.134. Eye Protection Safety glasses. Protective Gloves Wear chemically protective gloves. Other Protective Clothing Use a splash apron and boots if splashing occurs. Engineering Controls (Ventilation etc.) Adequate to prevent accumulation of vapors. Use mechanical means if necessary to maintain levels below the exposure limits. If working in a confined space, follow applicable OSHA regulations. 9. Physical and Chemical Properties Physical States: [ X ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: No data. Autoignition Pt. No data. Flash Pt: < 0.00 F (-17.8 C) Method: TCC Explosive Limits: LEL: No data. UEL: No data. Specific Gravity (Water = 1): 0.8223 Vapor Pressure (vs. Air or mm Hg): No data. Vapor Density (vs. Air = 1): No data. Evaporation Rate (vs Butyl No data. Acetate=1): Solubility in Water: No data. Other Solubility Notes Partially soluble in water. Soluble in most organic liquids. Percent Volatile: 75.0 % VOC / Volume: 5.1400 LB/GA Corrosion Rate: No data. pH: NA Appearance and Odor Liquid component is a clear, water-white liquid with distinct odor. Unless otherwise noted, all information in Section 9 pertains to the liquid component of the aerosol. VOC and percent volatile are based on both liquid and gaseous components. 10. Stability and Reactivity Stability: Unstable [ ] Stable [ X ] Conditions To Avoid - Instability High temperatures, heat, sparks, open flame. Incompatibility - Materials To Avoid Strong oxidizing agents. Hazardous Decomposition Or Byproducts Oxides of carbon. Hazardous Polymerization: Will occur [ ] Will not occur [ X ] Conditions To Avoid - Hazardous Polymerization None known. 11. Toxicological Information Toxicological Information Long-term toxicological studies have not been conducted for this product. See Section 3 of this MSDS for acute symptoms of overexposure. Carcinogenicity/Other Information This material is not an OSHA, IARC, or NTP carcinogen. Hazardous Components CAS # NTP IARC ACGIH OSHA (Chemical Name) 1. Toluene 108-88-3 n.a. n.a. A4 n.a. 2. Acetone 67-64-1 n.a. n.a. A4 n.a. 3. Carbon dioxide 124-38-9 n.a. n.a. n.a. n.a. 4. Methanol 67-56-1 n.a. n.a. n.a. n.a. 5. 2,2-Dimethoxypropane 77-76-9 n.a. n.a. n.a. n.a. Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No 12. Ecological Information Ecological Information No data available. 13. Disposal Considerations Waste Disposal Method This material if discarded may be hazardous waste under U.S. EPA RCRA regulations. All disposal activities must comply with federal,state and local regulations. Contact your local or state environmental agency for specific rules. Do not dump into sewers, on the ground, or into any body of water. 14. Transport Information LAND TRANSPORT (US DOT) DOT Proper Shipping Name; Aerosols, flammable DOT Hazard Class: 2.1 DOT Hazard Label: FLAMMABLE GAS UN/NA Number: UN1950 Additional Transport Information This product may be reclassified as a Consumer Commodity ORM-D subject to the restrictions and requirements of 49 CFR 173.306. 15. Regulatory Information US EPA SARA Title III Hazardous Components CAS # Sec.302 Sec. 304 Sec. 313 Sec. 110 (Chemical Name) (EHS) RQ (TRI) 1.Toluene 108-88-3 No Yes 1000 LB Yes Yes 2.Acetone 67-64-1 No Yes 5000 LB No Yes 3.Carbon dioxide 124-38-9 No No No No 4.Methanol 67-56-1 No Yes 5000 LB Yes No 5.2,2-Dimethoxypropane 77-76-9 No No No No US EPA CAA, CWA, TSCA Hazardous Components CAS # EPA CAA EPA CWA EPA TSCA CA PROP 65 (Chemical Name) NPDES 1.Toluene 108-88-3 HAP Yes Inventory, 8A CAIR Yes 2.Acetone 67-64-1 No No Inventory No 3.Carbon dioxide 124-38-9 No No Inventory No 4.Methanol 67-56-1 HAP No Inventory No 5.2,2-Dimethoxypropane 77-76-9 No No Inventory No SARA (Superfund Amendments and Reauthorization Act of 1986) Lists: Sec. 302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000 LB TPQ if not volatile. Sec. 304: EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. ** indicates statutory RQ. Sec. 313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a chemical category. Sec. 110: EPA SARA 110 Superfund Site Priority Contaminant List TSCA (Toxic Substances Control Act) Lists: Inventory: Chemical Listed in the TSCA Inventory. 5A(2): Chemical Subject to Significant New Rules (SNURS) 6A: Commercial Chemical Control Rules 8A: Toxic Substances Subject To Information Rules on Production 8A CAIR: Comprehensive Assessment Information Rules - (CAIR) 8A PAIR: Preliminary Assessment Information Rules - (PAIR) 8C: Records of Allegations of Significant Adverse Reactions 8D: Health and Safety Data Reporting Rules 8D TERM: Health and Safety Data Reporting Rule Terminations 12(b): Notice of Export Other Important Lists: CWA NPDES: EPA Clean Water Act NPDES Permit Chemical CAA HAP: EPA Clean Air Act Hazardous Air Pollutant CAA ODC: EPA Clean Air Act Ozone Depleting Chemical (1=CFC, 2=HCFC) CA PROP 65: California Proposition 65 International Regulatory Lists: EPA Hazard Categories: This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: [X] Yes [ ] No Acute (immediate) Health Hazard [ ] Yes [X] No Chronic (delayed) Health Hazard [X] Yes [ ] No Fire Hazard [X] Yes [ ] No Sudden Release of Pressure Hazard [ ] Yes [X] No Reactive Hazard Regulatory Information All components are either listed under TSCA or are exempt. This product contains chemicals known to the State of California to cause cancer, birth defects and other reproductive harm: Toluene (<43%), Ethylbenzene (<0.05%) Regulatory Information Statement The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Vendor assumes no responsibility for injury to vendee or third person proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes all risk in use of the material. 16. Other Information Company Policy or Disclaimer THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, EXCEPT THAT IS ACCURATE TO THE BEST KNOWLEDGE OF EXCELDA MANUFACTURING. THE DATA ON THIS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. EXCELDA MANUFACTURING ASSUMES NO LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THIS DATA. Licensed to Excelda Manufacturing, Inc. ANSI Z400.1 Format
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.