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MATERIAL SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 6500 PENETRATING OIL IDENTIFICATION NUMBER: 0147-28 A-7119 DATE PRINTED: 12/13/07 PRODUCT USE/CLASS: PENETRATING OIL MANUFACTURED FOR: MANUFACTURED BY: IMPERIAL SUPPLIES LLC IMPERIAL SUPPLIES LLC 789 ARMED FORCES DRIVE 789 ARMED FORCES DRIVE P.O. BOX 11008 P.O. BOX 11008 GREEN BAY, WISCONSIN 54307 GREEN BAY, WISCONSIN 54307 PHONE: 920-494-7474 PHONE: 920-494-7474 EMERGENCY TELEPHONE: 920-494-7474 EMERGENCY TELEPHONE: 920-494-7474 MON-FRI / 8:00 AM - 5:00 PM MON-FRI / 8:00 AM - 5:00 PM PREPARER: CUSTOMER SERVICE, PHONE: PREPARE DATE: 12/13/07 SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS WT/WT % ITEM CHEMICAL NAME CAS NUMBER LESS THAN 01 KEROSENE 8008-20-6 50.0 % 02 PROPANE/ISOBUTANTE/N-BUTANE 68476-86-8 25.0 % 03 STODDARD SOLVENT 8052-41-3 20.0 % EXPOSURE LIMITS ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 400 PPM N.E. 400 PPM N.E. N.E. NO 02 1000 PPM N.E. 800 PPM N.E. N.E. YES 03 100 PPM N.E. 100 PPM 500 PPM N.E. YES (See Section 16 for abbreviation legend) SECTION 3 - HAZARDS IDENTIFICATION *** EMERGENCY OVERVIEW *** Vapors irritating to eyes and respiratory tract. Vapors may cause flash fire or explosion. EFFECTS OF OVEREXPOSURE - EYE CONTACT: Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening and swelling accompanied by stinging sensation and/or a feeling like that of fine dust in the eyes. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Headaches, dizziness, nausea, decreased blood pressure, changes in heart rate and cyanosis may result from over- exposure to vapor or skin exposure. Prolonged inhalation may be harmful. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal If swallowed. If a Corrosive product, may cause severe and permanent damage to mouth, throat and stomach. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Over exposure may cause nervous system damage. Overexposure may cause lung damage. Overexposure may cause kidney damage. May cause liver disorder (e.g. edema, proteinuria) and damage. PRIMARY ROUTE (S) OF ENTRY: SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION EYE CONTACT SECTION 4 - FIRST AID MEASURES FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water. Get medical attention, if irritation persists. FIRST AID - SKIN CONTACT: Wash with soap and water. Get medial attention If irritation develops or persists. FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial Respiration. If breathing is difficult, give oxygen. Get immediate medical attention. FIRST AID - INGESTION: Get medical attention immediately. If swallowed, do NOT Induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT: -156 F LOWER EXPLOSIVE LIMIT: 0.7 % (PENSKY-MARTENS C.C.) UPPER EXPLOSIVE LIMIT: 9.5 % AUTO IGNITION TEMPERATURE: ND EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM WATER FOG UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors can travel to a source of ignition and flash back. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. Do NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION: THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner, or properly disposed of. SPECIAL FIREFIGHTING PROCEDURES: Containers can build up pressure if exposed to heat (fire). As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. SECTION 7 - HANDLING AND STORAGE HANDLING: Wash thoroughly after handling. STORAGE: Keep away from heat, sparks and flame. Keep from freezing. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with an Organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air Supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. SKIN PROTECTION: Where contact is likely, wear chemical resistant gloves, a chemical suit, rubber boots, and chemical safety goggles plus a face shield. EYE PROTECTION: Wear safety glasses with side shields (or goggles) and a face shield. OTHER PROTECTIVE EQUIPMENT: STANDARD INDUSTRIAL CLOTHING STANDARDS SHOULD BE FOLLOWED. HYGIENIC PRACTICES: Wash hands before eating. Remove contaminated clothing and Wash before reuse. Use only in a well ventilated area. Follow all MSDS/label precautions even after container is emptied because they may retain product residues. Avoid prolonged or repeated contact with skin. Avoid breathing vapors from heated material. Avoid contact with eyes, skin, and clothing. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES BOILING RANGE: -43 - 522 F VAPOR DENSITY: Is heavier than air ODOR: SOLVENT ODOR THRESHOLD: ND APPEARANCE: AMBER EVAPORATION RATE: Is faster than Butyl SOLUBILITY IN H20: NEGLIGIBLE Acetate FREEZE POINT: 32 SPECIFIC GRAVITY: 0.7285 VAPOR PRESSURE: 80-90 Ph @ 0.0 %: NA PHYSICAL STATE: OIL VISCOSITY: OIL COEFFICIENT OF WATER/OIL DISTRIBUTION: COMPLETE (See Section 16 for abbreviation legend) SECTION 10 - STABILITY AND REACTIVITY CONDITIONS TO AVOID: ALL SOURCES OF IGNITION, WELDING ARCS, AND OPEN FLAMES. INCOMPATIBILITY: STRONG ACIDS, ALKALIS, OXIDIZERS, AND AMINES. HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON, OXIDES OF NITROGEN, AND MAY PRODUCE FORMS OF CHLORIDE, CHLORINE, AND PHOSGENE. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. SECTION 11 - TOXICOLOGICAL PROPERTIES PRODUCT LD50: 5000 mg/kg PRODUCT LC50: 5000 ppm COMPONENT TOXICOLOGICAL INFORMATION: CHEMICAL NAME LD50 LC50 KEROSENE >5000 MG/KG/RAT >5000 MG/M3/4H/RAT PROPANE/ISOBUTANE/N-BUTANE NE 65800 MG/M3/4H/RAT STODDARD SOLVENT >5000 MG/KG/RAT >5500 MG/M3/4H/RAT HYDRO TREATED, SEVERE, LT. NAPHTHENIC DI NE NE GEAR LUBE NE NE SECTION 12 - ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: No Information. SECTION 13 - DISPOSAL CONSIDERATIONS DISPOSAL METHOD: DISPOSE IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS. SECTION 14 - TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: CONSUMER COMMODITY DOT TECHNICAL NAME: ORM-D DOT HAZARD CLASS: HAZARD SUBCLASS: DOT UN/NA NUMBER: PACKING GROUP: RESP. GUIDE PAGE: SECTION 15 - REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) CERCLA - SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 'Hazard Categories' Promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD PRESSURIZED GAS HAZARD SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER WT/WT% IS LESS THAN No SARA Section 313 components exist in this product. TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: CHEMICAL NAME CAS NUMBER KEROSENE 8008-20-6 STODDARD SOLVENT 8052-41-3 U.S. STATE REGULATIONS: AS FOLLOWS - NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components In this product: CHEMICAL NAME CAS NUMBER HYDRO TREATED, SEVERE, LT. NAPHTHENIC DIST. 64742-52-5 GEAR LUBE MIXTURE PENNSYLVANIA RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than 3%: CHEMICAL NAME CAS NUMBER HYDRO TREATED, SEVERE, LT. NAPHTHENIC DIST. 64742-52-5 CALIFORNIA PROPOSITION 65: WARNING: The chemicals (s) noted below and contained in this product, are known To the state of California to cause cancer, birth defects or other reproductive harm: CHEMICAL NAME CAS NUMBER No Proposition 65 chemicals exist in this product. INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. SECTION 16 - OTHER INFORMATION HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 4 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 05/11/05 VOLATILE ORGANIC COMPOUNDS (VOCS): 5.19 lbs/gal, 622 grams/ltr LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined *** THIS MSDS IS NOT FOR REPRODUCTION OR REPRODUCTION OR DISTRIBUTION *** The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local Laws and regulations. <END OF MSDS>
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.