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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: DIESEL 9.1.1 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Diesel fuel additive 1.3. Name, Address, and Telephone of the Responsible Party Company: Power Service Products, Inc. P.O. Box 1089 Weatherford, TX 76086 Email: email@example.com Phone: 800/643-9089 or 817-599-9486 1.4. Emergency Telephone Number Emergency |Within USA 1-800-424-9300. Outside USA 001-703-527-3887 (Call number |Collect). SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Health Hazard |Category Criteria | Acute |NC Toxicity, | Oral: | Acute |NC Toxicity, | Dermal: | Acute |NC Toxicity, | Inhalation, | Vapors: | Skin |2 Corrosion/Irri| tation: | Serious Eye |2 Damage/Eye | Irritation: | Respiratory |NC Sensitization:| Skin |NC Sensitization:| Germ Cell |NC Mutagenicity: | | Health Hazard |Category Criteria | Carcinogenicit|NC y: | Reproductive |NC Toxicity: | Specific |3 Target Organ | Toxicity, | Single | Exposure: | Specific |NC Target Organ | Toxicity, | Repeated | or Prolonged | Exposure: | Aspiration |1 Hazard: | | Physical |Category Properties | Criteria | Explosives: |NC Flammable |NC Gases: | Flammable |NC Aerosols: | Oxidizing |NC Gases: | Gases Under |NC Pressure: | Flammable |3 Liquids: | Flammable |NC Solids: | Self-Reactive |NC Chemicals: | Pyrophoric |NC Liquids: | Pyrophoric |NC Solids: | Self-Heating |NC Chemicals: | Chemicals |NC Which, in | Contact with | Water, | Emit Flammable| Gases: | Oxidizing |NC Liquids: | Oxidizing |NC Solids: | Organic |NC Peroxides: | Corrosive to |NC Metals: | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Flammable liquid and vapor. Toxic if inhaled. May be |fatal if swallowed and enters airways. Harmful if |swallowed. Causes skin and serious eye irritation. |May cause respiratory irritation. Precautionary Statements |Keep away from sparks and open flames. No smoking. (GHS-US) |Keep container tightly closed. Use only non-sparking |tools. Ground/Bond container and receiving |equipment. Use explosion-proof pumps when pumping. |Take precautionary measures against static |discharge. Avoid breathing vapors. Use only outdoors |or in a well-ventilated area. Wash hands thoroughly |after handling. Do not eat, drink or smoke when |using this product. Wear protective gloves and eye |protection. Store locked up and in cool, well |ventilated place. KEEP OUT OF REACH OF CHILDREN. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Aliphatic hydroxy hydrocarbons |Trade secret |40 - 90 | Petroleum Distillates |Trade secret |20 - 40 | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: As a precaution, exposure to liquids, vapors, mists and fumes should be minimized. First-aid Measures After Inhalation: Remove person to fresh air and keep comfortable for breathing. Call a doctor. First-aid Measures After Skin Contact: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs get medical advice/attention. First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice. First-aid Measures After Ingestion: If swallowed, IMMEDIATELY call a doctor. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use water fog, alcohol-resistant foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Vapors are heavier than air and may travel along the ground to a distant ignition source and flash back. See Section 10 for Stability and Reactivity. NOTE: EMPTY CONTAINERS CONTAIN COMBUSTIBLE VAPORS THAT CAN CAUSE FLASH FIRES OR EXPLOSIONS. CONTAINERS ARE SINGLE-TRIP CONTAINERS AND SHOULD NOT BE USED FOR ANY REASON AFTER BEING EMPTIED. DO NOT USE CUTTING TORCH EQUIPMENT OR ANY OTHER FLAME OR OTHER SOURCES OF IGNITION ON ANY EMPTY CONTAINER. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Use standard protective equipment including self-contained breathing apparatus (SCBA). SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas. Eliminate all sources of ignition in the vicinity of the spill or released vapor. See Section 2 for Hazards Identification. See Section 4 for First Aid Measures. See Section 5 for Fire Fighting Information. See Section 8 for Personal Protective Equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Eliminate potential sources of ignition. Stop leak if it can be done without risk. Dike and contain spill. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. A vapor suppressing foam may be used to reduce vapors. Methods for Cleaning Up: Local, state and federal laws and/or regulations may apply to releases and disposal of this material, as well as those materials and items employed in the clean-up releases. The user/responder will need to determine which local, state and federal laws and/or regulations are applicable. The National Response Center can be reached at 1-800-424-8802. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes and skin. Use only with adequate ventilation. Use proper bonding and/or grounding procedures. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Keep away from ignition sources such as heat, sparks, and flames. No smoking. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: DO NOT USE OR STORE near heat, sparks, or flame. USE AND STORE ONLY IN A WELL-VENTILATED AREA. Handle containers with care. Keep container closed when not in use. Store locked up. STORAGE TEMPERATURE: -40�F to 100�F (-40�C to 38�C) 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters CAS # OSHA ACGIH NIOSH PEL TLV STEL REL STEL IDLH Note Ethylbenzene 100-41-4 100 ppm 20 ppm not est. 100 ppm 125 ppm 800 ppm (LEL) n/a Naphthalene 91-20-3 10 ppm 10 ppm not est. 10 ppm 15 ppm 250 ppm skin Petroleum Distillates n/a 500 ppm not est. not est. not est not est not est n/a 2-Butanol 78-92-2 150 ppm 100 ppm not est. 100 ppm 150 ppm 2,000 ppm n/a N-Butanol 71-36-3 100 ppm 20 ppm not est. not est. not est 1,400 ppm (LEL) skin Cumene 98-82-8 50 ppm 50 ppm not est. 50 ppm not est 900 ppm (LEL) skin Toluene 108-88-3 100 ppm 20 ppm not est. 100 ppm 150 ppm 500 ppm skin 8.2. Exposure Controls Appropriate Engineering |The level of protection and types of controls Controls |necessary will vary depending upon potential |exposure conditions. Local exhaust ventilation is |recommended to control exposure. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Eye protection such as safety glasses or chemical |goggles is recommended if contact is likely. Skin and Body Protection |If prolonged or repeated skin contact is likely, |chemical/oil resistant clothing and gloves are |recommended. Wear additional protective clothing as |appropriate. Respiratory Protection |Wear a NIOSH/MSHA approved respirator as necessary. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Liquid, straw yellow Odor |Strong solvent Odor Threshold |Not available pH |7 - 8 (slightly basic) Relative Evaporation Rate |Not available (butylacetate=1) | Melting Point |Not available Freezing Point |Not available Boiling Point |200�F (93�C) est. Flash Point |75�F (TCC) 24�C Auto-ignition Temperature |Not available Decomposition Temperature |Not available Flammability (solid, gas) |Not available Vapor Pressure |0.58 est. Relative Vapor Density at 20 �C |>3.0 est, Relative Density |0.84 Specific Gravity |0.84 Solubility |Not available Partition coefficient: |Not available n-octanol/water | Viscosity |Not available Lower Flammable Limit |Not available Upper Flammable Limit |Not available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity see Incompatible Materials below 10.2 Chemical Stability This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. 10.3 Possibility of Hazardous Reactions 10.4 Conditions to Avoid Flames, high energy ignition sources, and elevated temperatures. 10.5 Incompatible Materials May react with oxygen, oxidizing agents, such as; chlorates, nitrates, peroxides, etc., amines, caustics, alkanolamines halogens, chlorine. 10.6 Hazardous Decomposition Products Carbon oxides, products of incomplete combustion. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Repeated skin exposure to a component of this product may cause irritation, even a burn; may cause a more severe response on covered skin, such as under clothing or gloves. Inhalation exposure to a component of this product has caused fetotoxicity in the presence of maternal toxicity in animals. Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: The following chemicals are listed as indicated: Chemical List Cumene IARC, NTP Ethylbenzene IARC Naphthalene IARC, NTP Reproductive Toxicity: No information available. Specific Target Organ Toxicity (Single Exposure): Respiratory tract irritation. Specific Target Organ Toxicity (Repeated Exposure): No information available Aspiration Hazard: Aspiration hazard identified. Symptoms/Injuries After Inhalation: Breathing of high vapor concentrations may cause dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness. The vapor or fumes from this material may cause respiratory irritation. Breathing this material at elevated concentrations causes central nervous system effects. Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion or disorientation. At extreme exposures, central nervous system effects may include respiratory depression, tremors, or convulsions, loss of consciousness, coma or death. Symptoms/Injuries After Skin Contact: Repeated skin exposure to a component of this product may cause irritation, even a burn; may cause a more severe response on covered skin, such as under clothing or gloves. Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity This material is expected to be toxic to aquatic organisms. 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil No information available. 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: RCRA Information: Disposal of unused product may be subject to RCRA hazardous waste regulations (40 CFR Part 261). Disposal of the used product may also be regulated as hazardous waste due to resulting mixture characteristics, mixture components or product use. Such changes to the product may result in different and/or additional hazardous waste codes. Potential RCRA waste code based on the product as shipped: D001 IGNITABILITY. State or local laws may impose additional regulatory requirements regarding disposal. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. Additional Information: EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN FLAMMABLE VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION HAZARD DATA. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Flammable Liquid, N.O.S., (Aliphatic Hydroxy Hydrocarbons) Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN 1993 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Section 313: Specific chemical information is being withheld as a Trade Secret. The following chemicals subject to the reporting requirements of EPCRA Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (40 CFR Part 372) may be present in this product at a concentration that does not exceed the specified upper weight percentage. CAS Number Chemical Name Max % 78-92-2 2-Butanol 21.5 71-36-3 N-Butanol 21.5 100-41-4 Ethylbenzene 9.0 98-82-8 Cumene 1.5 108-88-3 Toluene 1.5 91-20-3 Naphthalene 0.5 State or local laws may impose additional regulatory requirements for components of this material. It is the responsibility solely of the Employer to maintain compliance with State and Local reporting. SARA Section 311/312 Hazard Classes |Acute Health Effects: Yes |Sudden Release of Pressure Hazard: No |Chronic Health Effects: Yes |Reactivity Hazard: No |Fire Hazard: Yes Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> This product contains a chemical known to the state of California to cause cancer and/or birth defects or other reproductive harm: ethylbenzene, toluene, cumene, naphthalene. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |May 30, 2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.