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Safety Data Sheet | | Date of Issue: 06/02/2014 |Revision Date: 06/06/2014 |Revision Number: 1.0 Imperial Supplies Part Number: 0058530 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: Ammonia Inhalant Solution CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: OTC drug used to treat or prevent fainting. For professional use only. 1.3. Name, Address, and Telephone of the Responsible Party Company James Alexander Corporation 845 Route 94 Blairstown NJ 07825 Phone: (908) 362-9266 1.4. Emergency Telephone Number Emergency |Chemtrec (800) 424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flam. Liq. 2 |H225 Skin Corr. 1B |H314 Eye Dam. 1 |H318 Carc. 1A |H350 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Corrosio|Health | | | | |n |Hazard | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H225 - Highly flammable liquid and vapour |H314 - Causes severe skin burns and eye damage |H318 - Causes serious eye damage |H350 - May cause cancer Precautionary Statements |P201 - Obtain special instructions before use (GHS-US) |P202 - Do not handle until all safety precautions |have been read and understood |P210 - Keep away from heat, hot surfaces, open |flames, sparks. - No smoking |P233 - Keep container tightly closed |P240 - Ground/bond container and receiving equipment | |P241 - Use explosion-proof electrical, lighting, |ventilating equipment |P242 - Use only non-sparking tools |P243 - Take precautionary measures against static |discharge |P260 - Do not breathe dust, fume, gas, mist, spray, |vapours |P264 - Wash hands thoroughly after handling |P280 - Wear eye protection, protective clothing, |protective gloves P301+P330+P331 - IF SWALLOWED: |rinse mouth. Do NOT induce vomiting P303+P361+P353 - |IF ON SKIN (or hair): Remove/Take off immediately |all contaminated clothing. Rinse skin with |water/shower |P304+P340 - IF INHALED: Remove victim to fresh air |and keep at rest in a position comfortable for |breathing |P305+P351+P338 - If in eyes: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing |P308+P313 - IF exposed or concerned: Get medical |advice/attention |P310 - Immediately call a POISON CENTER or |doctor/physician |P321 - Specific treatment (see on this label) |P363 - Wash contaminated clothing before reuse |P370+P378 - In case of fire: Use dry chemical |powder, alcohol-resistant foam, carbon dioxide |(CO2), water spray, sand, earth for extinction |P403+P235 - Store in a well ventilated place. Keep |cool |P405 - Store locked up |P501 - Dispose of contents/container to comply with |applicable local, national and international |regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: No additional information available. 2.4. Unknown Acute Toxicity (GHS-US) No data available. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Not applicable. | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Ethyl alcohol |(CAS No) 64-17-5 |30 - 40 |Flam. Liq. 2, H225 | | | | | |Carc. 1A, H350 Ammonia |(CAS No) 7664-41-7 |15 - 20 |Flam. Gas 2, H221 | | |Compressed gas, | | |H280 | | |Acute Tox. 3 | | |(Inhalation:gas), | | |H331 | | |Skin Corr. 1B, | | |H314 | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid Measures After Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. If breathing stops, give artificial respiration. In case of breathing difficulties administer oxygen. by trained personnel. Seek medical attention immediately. First-aid Measures After Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove/Take off immediately all contaminated clothing. Do not rub the skin and eyes after direct contact with the product. Seek medical attention immediately. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately get medical attention. First-aid Measures After Ingestion: If the person is fully conscious, make him/her drink water. Never give an unconscious person anything to drink. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. If swallowed, rinse mouth with water (only if the person is conscious). 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Causes severe skin burns and eye damage. This material or its emissions may affect the central nervous system and/or aggravate pre-existing disorders. Symptoms/Injuries After Inhalation: May cause cancer by inhalation. Prolonged and repeated inhalation of decomposition products may cause a pulmonary oedema. Depression of the central nervous system, headaches, dizziness, drowsiness, loss of coordination. Irritating to the respiratory system, may cause throat pain and cough. Difficulty in breathing. Symptoms/Injuries After Skin Contact: May cause severe burns. Symptoms/Injuries After Eye Contact: Causes serious eye damage. Can cause blindness. Symptoms/Injuries After Ingestion: May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. Ingestion may cause nausea, vomiting and diarrhea. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed No additional information available. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol resistant foam. Dry powder. Carbon dioxide. Sand. Unsuitable Extinguishing Media: Do not use a heavy water stream. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Highly flammable liquid and vapour. Explosion Hazard: May form flammable/explosive vapour-air mixture. Reactivity: Thermal decomposition generates : Corrosive vapours. Reacts violently with acids. An exothermic reaction may occur. 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Other information: Containers may swell and Burst during a fire due to internal pressure caused by heat. Vapours are heavier than air and may travel considerable distance to an ignition source and flash back to source of vapours. Alcohols burn with a pale blue flame which may be extremely hard to see under normal lighting conditions. Personnel may be able to feel the heat of the fire without seeing flames. Extreme caution must be exercised in fighting alcohol fires. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Eliminate all ignition sources if safe to do so. Use special care to avoid static electric charges. No naked lights. No smoking. Stop leak if safe to do so. No action shall be taken involving any personal risk or without suitable training. Wear protective clothing. For further information refer to section 8 : Exposure-controls/personal protection. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Consult the appropriate authorities about waste disposal. Ensure all national/local regulations are observed. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Handle empty containers with care because residual vapours are flammable. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Personal protective equipment should be selected based upon the conditions under which this product is handled or used. Use personal protective equipment as required. Provide good ventilation in process area to prevent formation of vapour. Do not breathe gas, fumes, vapour or spray. No naked lights. No smoking. Use only non-sparking tools. Never use pressure to empty container. Ground/bond container and receiving equipment. Take care to allow internal pressure to escape from container before releasing closures. Remove closure carefully; internal pressure may be present. Keep closure up to prevent leakage. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Hygiene Measures: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Use explosion-proof machinery, apparatus, ventilation facilities, tools etc. Ensure the ventilation system is regularly maintained and tested. Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists and/or vapors below the recommended exposure limits. Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. A washing facility/water for eye and skin cleaning purposes should be present. Comply with applicable regulations. Storage Conditions: Keep only in the original container in a cool well ventilated place. Keep in fireproof place. Keep container tightly closed. Protect containers against physical damage. Detached outside storage is preferable. Inside storage should be in an NFPA approved flammable liquids storage room or cabinet. Store in corrosion-proof area at temperatures below 77 degrees F (25oC). Store away from direct sunlight or other heat sources. Incompatible materials: Avoid mixing with acids, most common metals, strong oxidizing agents, brass, zinc, chlorine, aluminum, copper, bronze, mercury, dimethyl sulfate and acetyl chloride. 7.3. Specific End Use(s) No additional information available. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Ammonia (7664-41-7) USA ACGIH ACGIH TWA (ppm) 25 ppm USA ACGIH ACGIH STEL (ppm) 35 ppm USA OSHA OSHA PEL (TWA) (mg/mÂ³) 35 mg/mÂ³ USA OSHA OSHA PEL (TWA) (ppm) 50 ppm Ethyl alcohol (64-17-5) USA ACGIH ACGIH STEL (ppm) 1000 ppm USA OSHA OSHA PEL (TWA) (mg/mÂ³) 1900 mg/mÂ³ USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm 8.2. Exposure Controls Appropriate Engineering |Emergency eye wash fountains and safety showers Controls |should be available in the immediate vicinity of any |potential exposure. Provide exhaust ventilation or |other engineering controls to keep the airborne |concentrations of mists and/or vapors below the |recommended exposure limits. Use explosion-proof |ventilating equipment. Personal Protective Equipment|Avoid all unnecessary exposure. A hazard assessment |of the work area for PPE requirements should be |conducted by a qualified professional pursuant to |OSHA regulations. For certain operations, additional |Personal Protection Equipment (PPE) may be required. |Protective goggles. Gloves. Protective clothing. Materials for Protective | Clothing | Hand Protection |Wear protective gloves. rubber gloves. For special |purposes, it is recommended to check the resistance |to chemicals of the protective gloves mentioned |above together with the supplier of these gloves. Eye Protection |Chemical goggles or face shield. Skin and Body Protection |Wear suitable protective clothing. Chemical |resistant safety shoes. Respiratory Protection |Wear a self-contained breathing apparatus and |appropriate personal protective equipment (PPE). |Suggestions provided in this section for exposure |control and specific types of protective equipment |are based on readily available information. Users |should consult with the specific manufacturer to |confirm the performance of their protective |equipment. Specific situations may require |consultation with industrial hygiene, safety, or |engineering professionals. Care must be taken to |assure that any respirator chosen is capable of |protecting the user from both ammonia and ethyl |alcohol vapors. |Other information: Do not eat, drink or smoke during |use. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Clear. Odor |Pungent ammonia odour. Odor Threshold |No data available pH |No data available Relative Evaporation Rate |No data available (butylacetate=1) | Melting Point |No data available Freezing Point |No data available Boiling Point |> 35 Â°C (> 95 Â°F) Flash Point |< 10 Â°C (< 50 Â°F - Pensky Martens Closed Cup) Auto-ignition Temperature |No data available Decomposition Temperature |No data available Flammability (solid, gas) |No data available Vapor Pressure |No data available Relative Vapor Density at 20 Â°C |No data available Relative Density |No data available Specific Gravity |0.891 (Specific Gravity @ 25 Â°C ) Solubility |Soluble in water. Partition coefficient: | n-octanol/water | Viscosity |Viscosity, kinematic: No data available |Viscosity, dynamic: No data available Lower Flammable Limit |No data available Upper Flammable Limit |No data available 9.2. Other Information No additional information available. SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Thermal decomposition generates : Corrosive vapours. Reacts violently with acids. An exothermic reaction may occur. 10.2 Chemical Stability Not established. 10.3 Possibility of Hazardous Reactions Not established. 10.4 Conditions to Avoid Direct sunlight. Extremely high or low temperatures. Open flame. 10.5 Incompatible Materials Avoid mixing with acids, most common metals, strong oxidizing agents, brass, zinc, chlorine, aluminum, copper, bronze, mercury, dimethyl sulfate and acetyl chloride. 10.6 Hazardous Decomposition Products Thermal decomposition generates : Fume. Carbon monoxide. Carbon dioxide. May release flammable gases. Corrosive vapours. Ammonia. Nitrogen oxides. release of highly flammable gases/vapours hydrogen. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not classified. (Based on available data, the classification criteria are not met). Skin Corrosion/Irritation: Causes severe skin burns and eye damage. Serious Eye Damage/Irritation: Causes serious eye damage. Respiratory or Skin Sensitization: Not classified. (Based on available data, the classification criteria are not met). Germ Cell Mutagenicity: Not classified. (Based on available data, the classification criteria are not met). Carcinogenicity: May cause cancer. Reproductive Toxicity: Not classified. (Based on available data, the classification criteria are not met). Specific Target Organ Toxicity (Single Exposure): Not classified. (Based on available data, the classification criteria are not met). Specific Target Organ Toxicity (Repeated Exposure): Not classified. (Based on available data, the classification criteria are not met). Aspiration Hazard: Not classified. (Based on available data, the classification criteria are not met). Symptoms/Injuries After Inhalation: May cause cancer by inhalation. Prolonged and repeated inhalation of decomposition products may cause a pulmonary oedema. Depression of the central nervous system, headaches, dizziness, drowsiness, loss of coordination. Irritating to the respiratory system, may cause throat pain and cough. Difficulty in breathing. Symptoms/Injuries After Skin Contact: May cause severe burns. Symptoms/Injuries After Eye Contact: Causes serious eye damage. Can cause blindness. Symptoms/Injuries After Ingestion: May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. Ingestion may cause nausea, vomiting and diarrhea. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability Not established. 12.3. Bioaccumulative Potential Not established. 12.4. Mobility in Soil No additional information available 12.5. Other Adverse Effects Other information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose in a safe manner in accordance with local/national regulations. Do not re-use empty containers. Ensure all national/local regulations are observed. Consult the appropriate authorities about waste disposal. Additional Information: Handle empty containers with care because residual vapours are flammable. Ecology - waste materials: Avoid release to the environment. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Flammable liquids, corrosive, n.o.s. (Ammonia, Ethanol) Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN2924 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |No additional information available Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |No additional information available Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Ammonia Inhalant Solution RQ (Reportable quantity, section 304 of EPA's List of Lists) : 588 lb Ammonia (7664-41-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 302 (Specific toxic chemical listings) Listed on SARA Section 313 (Specific toxic chemical listings) RQ (Reportable quantity, section 304 of EPA's List of Lists) : 100 lb SARA Section 302 Threshold Planning Quantity (TPQ) 500 SARA Section 313 - Emission Reporting 1.0 % (includes anhydrous Ammonia and aqueous Ammonia from water dissociable Ammonium salts and other sources, 10% of total aqueous Ammonia is reportable under this listing) SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |Ethyl alcohol (64-17-5) |Listed on the United States TSCA (Toxic |Substances Control Act) inventory 15.2 US State Regulations <COMPONENT> Ethyl alcohol (64-17-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes Yes SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |06/06/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.