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SDS Sheet 0058510

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Safety Data Sheet                                                                 
Date of Issue:             |Revision Date: 2014-09     |Revision Number:          
Imperial Supplies Part Number: 0058510                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form:                                                                     
Product Name: Ammonium Nitrate Ice Pack                                           
CAS No: 6484-52-2                                                                 
Synonyms:                                                                         


1.2.  Intended Use of the Product
Use of the substance/mixture: cold therapy                                        


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                           
Shanghai Intco Medical Supply Co., Ltd                                            
1358, Hubin Road,                                                                 
Fengxian District, Shanghai, China                                                
Phone: 021-57456868                                                               


1.4.  Emergency Telephone Number
Emergency     | +86-021-57456868                                                  
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Not a         |              
dangerous     |              
substance     |              
according to  |              
GHS           |              
              |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame   |Skull   |Corrosio|Health  |        |        
                             |        |and     |n       |hazard  |        |        
                             |        |crossbon|        |        |        |        
                             |        |es      |        |        |        |        
Signal Word (GHS-US)         |                                                    
Hazard Statements (GHS-US)   |None.                                               
Precautionary Statements     |None.                                               
(GHS-US)                     |                                                    


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                             


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                  

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
Ammonium Nitrate                |6484-52-2            |30~70   |                  
Water                           |7732-18-5            |30~70   |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


(See Section 8 for Exposure Limits)

SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General:                                                       
First-aid Measures After Inhalation: Move casualty to fresh air and keep at rest. 
If breathing is difficult, give oxygen. Get medical attention if necessary.       
First-aid Measures After Skin Contact: Immediately flush the skin with plenty of  
water while removing contaminated clothing and shoes. Get immediate medical       
attention if necessary. Wash contaminated clothing before reuse.                  
First-aid Measures After Eye Contact: Eye irritation. Flush immediately with large
amounts of water for at least 15 minutes. Eyelids should be held away from the    
eyeball to ensure thorough rinsing. Get immediate medical attention if necessary. 
First-aid Measures After Ingestion: Get immediate medical attention. Do not induce
vomiting unless directed by medical personnel.                                    


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                                
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
                                                                                  

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use dry chemical, foam, or carbon dioxide to        
extinguish fire. Water may be ineffective but should be used to cool fire-exposed 
containers, structures and to protect personnel. Use water to dilute spills and to
flush them away from sources of ignition.                                         
Unsuitable Extinguishing Media:                                                   


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:                                                                      
Explosion Hazard: Irritating or toxic substances may be emitted upon thermal      
decomposition. Thermal decomposition products may include oxides of carbon and    
nitrogen.                                                                         
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions:  Exposed firefighters must wear NIOSH-approved positive
pressure self-contained breathing apparatus with full-face mask and full          
protective clothing.                                                              
Protection During Firefighting:                                                   

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: See section 8 for recommendations on the use of personal        
protective equipment.                                                             


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.2.  Environmental Precautions
Prevent spillage from entering drains. Any release to the environment may be      
subject to a federal/national or local reporting requirements.                    


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Pick up and arrange disposal without creating dust. Sweep up and 
keep in suitable, closed containers for disposal. Clean surfaces thoroughly with  
water to remove residual contamination.                                           
Methods for Cleaning Up: Dispose of all waste or clean up materials in accordance 
with local regulations. Containers, even when empty, will retain residue and      
vapors.                                                                           


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: All employees who handle Magnesium Sulfate     
should be trained to handle it safely. Do not breathe dust. Avoid allcontact with 
skin and eyes. Use this product only with adequate ventilation. Wash thoroughly   
after handling.                                                                   
Hygiene Measures:                                                                 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                               
Storage Conditions: Keep container tightly closed when not in use. Store          
containers in a cool, dry location, away from direct sunlight, sources of intense 
heat, or where freezing is possible. Keep containers closed--material is          
hygroscopic. Material should be stored in secondary containers or in a diked area,
as appropriate. Store containers away from incompatible chemicals (see Section 10,
Stability and Reactivity). Storage areas should be made of fire-resistant         
materials. Post warning and "NO SMOKING" signs in storage and use areas, as       
appropriate. Use corrosion-resistant structural materials, lighting, and          
ventilation systems in the storage area. Floors should be sealed to prevent       
absorption of this material. Inspect all incoming containers before storage, to   
ensure containers are properly labeled and not damaged. Have appropriate          
extinguishing equipment in the storage area (i.e., sprinkler system, portable fire
extinguishers). Empty containers may contain residual particulates; therefore,    
empty containers should be handled with care. Never store food, feed, or drinking 
water in containers which held this product. Keep this material away from food,   
drink and animal feed. Do not store this material in open or unlabeled containers.
Limit quantity of material stored. Wipe down area of use periodically to avoid the
accumulation of dusts.                                                            


7.3.  Specific End Use(s)
                                                                                  

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
                                                                                  


8.2.  Exposure Controls
Appropriate Engineering      |Avoid welding on pipes or tanks which have contained
Controls                     |ammonium nitrate solution until they have been      
                             |thoroughly washed out with water. Residual ammonium 
                             |nitrate may explode under conditions of organic     
                             |contamination, confinement, and high temperature.   
                             |Avoid containers, piping or fittings made of brass, 
                             |bronze, other copper containing alloys or galvanized
                             |metal. Do not run pumps with the discharge valve or 
                             |suction valve closed, pump must be on circulation.  
Personal Protective Equipment|                                                    
Materials for Protective     |Wear rubber gloves and protective clothing if there 
Clothing                     |is prolonged or repeated contact with liquid.       
                             |Other Protective Clothing or Equipment: Provide     
                             |safety shower/eye wash facility at sites of handling
                             |or storage.                                         
Hand Protection              |                                                    
Eye Protection               |Wear chemical safety goggles. Do not wear contact   
                             |lenses.                                             
Skin and Body Protection     |Other Protective Clothing or Equipment: Provide     
                             |safety shower/eye wash facility at sites of handling
                             |or storage.                                         
Respiratory Protection       |Respirators are not required for normal ventilation.
                             |If a misty condition prevails due to heat spraying  
                             |or agitation, a mist respirator approved by NIOSH   
                             |should be worn. If heated to decomposition or in    
                             |fire situation, utilize a self-contained breathing  
                             |apparatus.                                          
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Solid.                                       
Appearance                          |White granular solid. Deliquescent solid     
Odor                                |Odorless.                                    
Odor Threshold                      |Not available.                               
pH                                  |4.5 - 6.0 @ 25 deg. [Acidic.]                
Relative Evaporation Rate           |                                             
(butylacetate=1)                    |                                             
Melting Point                       |N/A                                          
Freezing Point                      |                                             
Boiling Point                       |Decomposition temperature: 210°C (410°F)     
Flash Point                         |                                             
Auto-ignition Temperature           |                                             
Decomposition Temperature           |210°C (410°F)                                
Flammability (solid, gas)           |                                             
Vapor Pressure                      |Not applicable.                              
Relative Vapor Density at 20 °C     |Not available.                               
Relative Density                    |                                             
Specific Gravity                    |1.725 (Water = 1)                            
Solubility                          |Easily soluble in cold water, hot water.     
                                    |Soluble in acetone. Partially soluble in     
                                    |methanol. Insoluble in diethyl ether.        
Partition coefficient:              |Not available.                               
n-octanol/water                     |                                             
Viscosity                           |                                             
Lower Flammable Limit               |                                             
Upper Flammable Limit               |                                             


9.2.  Other Information
                                                                                  

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
Also incompatible with finely powdered metals (aluminum, copper, chromium, iron,  
zinc brass, nickel , lead, manganese, magnesium, antimony), acetic acid, ammonium 
chloride, phosphorus, sodium perchlorate, sulfur, bismuth, cadmium, chlorides,    
cobalt, potassium and ammonium sulfate, sodium, sodium hypochlorite,              
sodiumpotassium alloy, organic materials and combustible materials (paper, oil,   
charcoal, etc.).                                                                  


10.2      Chemical Stability
The product is stable.                                                            


10.3      Possibility of Hazardous Reactions
Polymerization: Will not occur.                                                   


10.4      Conditions to Avoid
Incompatible materials.                                                           
Corrosivity: Non-corrosive in presence of glass.                                  


10.5      Incompatible Materials
Reactive with reducing agents, combustible materials, organic materials, metals,  
alkalis.                                                                          


10.6      Hazardous Decomposition Products
                                                                                  

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                   
Toxicity to Animals:                                                              
Acute Oral Toxicity: (rat) LD50 = 2,800 - 4,500 mg/kg bw.                         
Acute Inhalation Toxicity: 4-h: (rat) LC50 = >88.8 mg/L.                          
Acute Toxicity: Other Routes: Minimum lethal dose (rat): 0.065mg NH4NO3-N.        
Acute Dermal Toxicity: (Sprague-Dawley rat, albino) LD50 = > 5,000 mg/kg.         
Repeated Dose Toxicity: Inhalation: 2 weeks: NOAEL(rat) 185 mg/m3. Inhalation: 4  
weeks: NOAEL = 1 mg/m3.                                                           
Skin Corrosion/Irritation: Skin Irritation/Corrosion: 48 hr (rabbit) : Moderately 
irritating.                                                                       
Serious Eye Damage/Irritation:                                                    
Respiratory or Skin Sensitization:                                                
Germ Cell Mutagenicity:                                                           
Carcinogenicity: No data available                                                
Reproductive Toxicity: No data available                                          
Specific Target Organ Toxicity (Single Exposure): Not found to be toxic by oral,  
dermal and inhalation exposure as defined by OSHA                                 
Specific Target Organ Toxicity (Repeated Exposure):                               
Aspiration Hazard:                                                                
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms: Large amounts, 15 to 25 grams, may have serious or even fatal   
effects. Small repeated doses may lead to weakness, general depression, headache  
and mental impairment. Symptoms of over exposure, acute cyanosis, nausea, vertigo,
collapse, vomiting/abdominal pain, and tachycardia (rapid heartbeat), coma,       
convulsion and death can occur.                                                   

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
No data available                                                                 


12.2. Persistence and Degradability
                                                                                  


12.3. Bioaccumulative Potential
                                                                                  


12.4. Mobility in Soil
Ammonium ions bind to clay particles and leach slowly or not at all to ground     
water, whereas the nitrate can leach significantly. Monitoring Data: NH4          
background: 0.01 - 10mg N/L. NO3 background: 0.3 - 100 mg N/L.                    


12.5. Other Adverse Effects
EPA Ecological Toxicity rating :                                                  
Acute Toxicity to Fish:                                                           
(Cyprinus carpio L): 48-h: LC50= 1.15 - 1.72 mg un-ionized NH3/L;                 
(Chinook Salmon, rainbow trout, bluegill) 96-h: LC50= 420 - 1360 mg               
NO3/L                                                                             
Chronic Toxicity to Fish: No data available                                       
Acute Toxicity to Aquatic                                                         
Invertebrates: (Daphnia magna) EC50 = 555 mg/L                                    
Chronic Toxicity to Aquatic                                                       
Invertebrates:                                                                    
(Bullia digitalis) Up to 7 days: NOEC = 300 mg/L. Based on the standard Federal   
Insecticide Fungicide and Rodenticide Act                                         
(FIFRA) acute toxicity ratings for fish and Daphnia, the compounds in this        
category are considered practically non-toxic.                                    
Ammonium nitrate is a plant nutrient; however, large spills can kill vegetation.  
It should be reported to the proper authorities.                                  
Acute Toxicity to Aquatic Plants: No data available                               
Toxicity to Soil DwellingOrganisms: No data available                             
Toxicity to Terrestrial Plants: No data available                                 
Transport and Distribution:                                                       
Transport: Worldwide loss after application 0.004 - 1.2 Tg/yr. Distribution:      
0.251% to air; 45.4% to water; 54.2% to soil;                                     
0.0757% to sediment.                                                              

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: If uncontaminated, recover and reuse as product.  
Consult federal, state and local environmental agenciesfor acceptable disposal    
procedures.                                                                       
Additional Information: General Comments: Users of this product should review     
their operations in terms of applicable federal, state and local laws and         
regulations, then consult with appropriate regulatory agencies before discharging 
or disposing of waste material.                                                   

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |Ammonium Nitrate, Liquid                                    
Hazard Class         |5.1                    |<PICTOGRAM PHRASE>                  
Identification Number|UN2426                 |                                    
Label Codes          |Oxidiser               |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |                                                            
Hazard Class         |                                                            
Identification Number|                                                            
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     


14.3 In Accordance with IATA
Proper Shipping Name |                                                            
Identification Number|                       |<PICTOGRAM PHRASE>                   
Hazard Class         |                       |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
Chemical                                                                          
CAS NO.                                                                           
Percent by Weight                                                                 
CERCLA RQ (lbs)                                                                   
SARA (1986) Reporting                                                             
                                                                                  
                                                                                  
                                                                                  
                                                                                  
                                                                                  
311                                                                               
312                                                                               
313                                                                               
                                                                                  
Ammonium Nitrate                                                                  
6484-52-2                                                                         
40-87                                                                             
See note (1)                                                                      
Yes                                                                               
Yes                                                                               
See Note (2)                                                                      
                                                                                  
Aqueous Ammonia                                                                   
1336-21-6                                                                         
8.51-18.59                                                                        
NA                                                                                
NA                                                                                
NA                                                                                
Yes                                                                               
                                                                                  
Nitrate Compounds                                                                 
N/A                                                                               
31.0-67.49                                                                        
NA                                                                                
NA                                                                                
NA                                                                                
Yes                                                                               
                                                                                  
: This product is not an EPA Hazardous Substance per 40 CFR 116-117. Ammonium     
Nitrate Solutions contain alkalinity as high as 0.5% by weight (as ammonia). Any  
spill that exceeds 97.000 lbs. may exceed the 1000 lb. RQ for ammonium hydroxide. 
: Ammonium Nitrate contains aqueous ammonia and water dissociable nitrate         
compounds subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986.                             
CERCLA/Superfund, 40 CFR Parts 117, 302-:                                         
If this product contains components subject to substances designated as CERCLA    
reportable Quantity (RQ) Substances, it will be designated In the above table with
the RQ value in pounds. If there is a release of RQ Substance to the environment, 
notification to the National response Center, Washington D.C. (1-800-424-8802) is 
required.                                                                         
                                                                                  
California: Prop 65: This is not a chemical known to cause cancer, nor is it      
listed.                                                                           
                                                                                  
                                                                                  
                                                                                  
SARA Section 311/312 Hazard Classes |This product has teen reviewed according to  
                                    |the EPA Hazard Categories promulgated under  
                                    |Section 311 and 312 of me Supertund Amendment
                                    |and reauthorization Act of 1986 (SARA title  
                                    |ill) and is considered. under applicable     
                                    |definitions, to meet the following           
                                    |categories:                                  
                                    |Fire: No                                     
                                    |Pressure Generating: No                      
                                    |Reactivity: No                               
                                    |Acute: Yes                                   
                                    |Chronic: No                                  
Toxic Substances Control Act (TSCA) |All intentional ingredients listed on the    
                                    |TSCA inventory.                              

15.2      US State Regulations
California: Prop 65:                                                              
This is not a chemical known to cause cancer, nor is it listed.                   
                                                                                  

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |2014-09                                                          
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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