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SDS Sheet 0058342

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Safety Data Sheet | |
Date of Issue: 02-Jan-2013 |Revision Date: 01-Jun-2015 |Revision Number: 1        
Imperial Supplies Part Number: 0058342                                            

SECTION 1: IDENTIFICATION                                                         

1.1.  Product Identifier
Product Form:                                                                     
Product Name: TheraTears Preservative Free Lubricant Eye Drops                    
CAS No:                                                                           
Synonyms: None                                                                    

1.2.  Intended Use of the Product
Use of the substance/mixture: Eyecare cleaner/eyedrop.                            

1.3.  Name, Address, and Telephone of the Responsible Party
Advanced Vision Research                                                          
2929 Plymouth Road                                                                
Ste. 275                                                                          
Ann Arbor                                                                         
Phone: 8005798327                                                                 

1.4.  Emergency Telephone Number
Emergency     |781-932-8327                                                       
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 

2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Reproductive  | Category 1B  
Toxicity      |              

2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Health  |        |        |        |        |        
                             |hazard  |        |        |        |        |        
Signal Word (GHS-US)         |Danger                                              
Hazard Statements (GHS-US)   |May damage fertility or the unborn child            
Precautionary Statements     |Prevention:                                         
(GHS-US)                     |Obtain special instructions before use              
                             |Do not handle until all safety precautions have been
                             |read and understood                                 
                             |Use personal protective equipment as required       
                             |IF exposed or concerned: Get medical                
                             |Store locked up                                     
                             |Dispose of contents/container to an approved waste  
                             |disposal plant                                      

2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Not applicable.             

2.4.  Unknown Acute Toxicity (GHS-US)
2E-05% of the mixture consists of ingredient(s) of unknown toxicity.              


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  

Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
Supplier Trade Secret           |Proprietary          |0.1 - 1 |                  
                                |                     |Trade   |                  
                                |                     |Secret *|                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  

*The exact percentage (concentration) of composition has been withheld as a
trade secret

SECTION 4: FIRST AID MEASURES                                                     

4.1.  Description of First Aid Measures
First-aid Measures General:                                                       
First-aid Measures After Inhalation: Remove to fresh air.                         
First-aid Measures After Skin Contact: Wash with soap and water.                  
First-aid Measures After Eye Contact: Rinse thoroughly with plenty of water, also 
under the eyelids. If symptoms persist, call a  physician.                        
First-aid Measures After Ingestion:  Rinse mouth immediately and drink plenty of  
water. Never give anything by mouth to an unconscious person.                     

4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: No information available.                                      
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms:                                                                 

4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Notes to Physician: Treat symptomatically.                                        

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use extinguishing measures that are appropriate to  
local circumstances and the surrounding environment.                              
Unsuitable Extinguishing Media: CAUTION: Use of water spray when fighting fire may
be inefficient.                                                                   

5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: No information available.                                            
Explosion Hazard:                                                                 
Sensitivity to Mechanical Impact: None.                                           
Sensitivity to Static Discharge: None.                                            

5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions:                                                        
Protection During Firefighting: As in any fire, wear self-contained breathing     
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            

6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Ensure adequate ventilation.                                    

6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             

6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             

6.2.  Environmental Precautions
See Section 12 for additional Ecological Information.                             

6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Prevent further leakage or spillage if safe to do so.            
Methods for Cleaning Up: Soak up with inert absorbent material. Pick up and       
transfer to properly labeled containers.                                          

6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        

SECTION 7: HANDLING AND STORAGE                                                   

7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Handle in accordance with good industrial      
hygiene and safety practice. Do not eat, drink or smoke when using this product.  
Take off contaminated clothing and wash before reuse.                             
Hygiene Measures: Do not eat, drink or smoke when using this product. Wash hands  
before breaks and immediately after handling the product.                         

7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                               
Storage Conditions: Store locked up.                                              
Incompatible Products: None known based on information supplied.                  

7.3.  Specific End Use(s)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  

8.1.  Control Parameters
Exposure Guidelines:                                                              
Chemical Name                                                                     
ACGIH TLV                                                                         
OSHA PEL                                                                          
NIOSH IDLH                                                                        
Supplier Trade Secret                                                             
TWA: 2 mg/m3 inhalable fraction                                                   
STEL: 6 mg/m3 inhalable fraction                                                  

8.2.  Exposure Controls
Appropriate Engineering      |Showers                                             
Controls                     |Eyewash stations                                    
                             |Ventilation systems.                                
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |                                                    
Eye Protection               |No special protective equipment required.           
Skin and Body Protection     |Wear protective gloves and protective clothing.     
Respiratory Protection       |No protective equipment is needed under normal use  
                             |conditions. If exposure limits are exceeded or      
                             |irritation is experienced, ventilation and          
                             |evacuation may be required.                         
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       

9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid, Viscous liquid                       
Appearance                          |Clear, colorless                             
Odor                                |Odorless                                     
Odor Threshold                      |No information available                     
pH                                  |7                                            
Relative Evaporation Rate (butyl    |No data available                            
acetate=1)                          |                                             
Melting Point                       |No data available                            
Freezing Point                      |No data available                            
Boiling Point                       |No data available                            
Flash Point                         |No data available                            
Auto-ignition Temperature           |No data available                            
Decomposition Temperature           |No data available                            
Flammability (solid, gas)           |No data available                            
Vapor Pressure                      |No data available                            
Relative Vapor Density at 20 °C     |No data available                            
Relative Density                    |                                             
Specific Gravity                    |1.05                                         
Solubility                          |Moderately soluble                           
Partition coefficient:              |1.5                                          
n-octanol/water                     |                                             
Viscosity                           |Kinematic viscosity: No data available       
                                    |Dynamic viscosity: 5                         
Lower Flammable Limit               |No data available                            
Upper Flammable Limit               |No data available                            

9.2.  Other Information
Softening Point: No data available                                                
VOC Content (%): No data available                                                
Particle Size Particle Size Distribution: No data available                       

SECTION 10: STABILITY AND REACTIVITY                                              

10.1      Reactivity
No data available.                                                                

10.2      Chemical Stability
Stable under recommended storage conditions.                                      

10.3      Possibility of Hazardous Reactions
None under normal processing.                                                     

10.4      Conditions to Avoid
None known based on information supplied.                                         

10.5      Incompatible Materials
None known based on information supplied.                                         

10.6      Hazardous Decomposition Products
None known based on information supplied.                                         

SECTION 11: TOXICOLOGICAL INFORMATION                                             

11.1. Information on Toxicological Effects
Acute Toxicity:                                                                   
Skin Corrosion/Irritation:                                                        
Serious Eye Damage/Irritation:                                                    
Respiratory or Skin Sensitization: No information available.                      
Germ Cell Mutagenicity: No information available.                                 
Reproductive Toxicity: Contains a known or suspected reproductive toxin.          
Specific Target Organ Toxicity (Single Exposure): No information available.       
Specific Target Organ Toxicity (Repeated Exposure): No information available.     
Aspiration Hazard: No information available.                                      
Symptoms/Injuries After Inhalation: Specific test data for the substance or       
mixture is not available.                                                         
Symptoms/Injuries After Skin Contact: Specific test data for the substance or     
mixture is not available.                                                         
Symptoms/Injuries After Eye Contact: Specific test data for the substance or      
mixture is not available.                                                         
Symptoms/Injuries After Ingestion: Specific test data for the substance or mixture
is not available.                                                                 
Chronic Symptoms:                                                                 

SECTION 12: ECOLOGICAL INFORMATION                                                

12.1. Toxicity
Ecotoxicity: The environmental impact of this product has not been fully          

12.2. Persistence and Degradability
No information available.                                                         

12.3. Bioaccumulative Potential

12.4. Mobility in Soil

12.5. Other Adverse Effects
No information available.                                                         

13.1. Waste treatment methods
Waste Disposal Recommendations:                                                   
Disposal methods: This material, as supplied, is not a hazardous waste according  
to Federal regulations (40 CFR 261). This material could become a hazardous waste 
if it is mixed with or otherwise comes in contact with a hazardous waste, if      
chemical additions are made to this material, or if the material is processed or  
otherwise altered. Consult 40 CFR 261 to determine whether the altered material is
a hazardous waste. Consult the appropriate state, regional, or local regulations  
for additional requirements.                                                      
Additional Information:                                                           
Contaminated Packaging: Dispose of contents/containers in accordance with local   

SECTION 14: TRANSPORT INFORMATION                                                 

14.1 In Accordance with DOT
Proper Shipping Name |NON REGULATED                                               
Hazard Class         |N/A                    |<PICTOGRAM PHRASE>                  
Identification Number|                       |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            

14.2 In Accordance with IMDG
Proper Shipping Name |Not regulated                                               
Hazard Class         |N/A                                                         
Identification Number|                                                            
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     

14.3 In Accordance with IATA
Proper Shipping Name |NON REGULATED                                               
Identification Number|                       |<PICTOGRAM PHRASE>                   
Hazard Class         |N/A                    |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization
Act of 1986 (SARA). This product does not contain any chemicals which are subject 
to the reporting requirements of the Act and Title 40 of the Code of Federal      
Regulations, Part 372.                                                            
CWA (Clean Water Act): This product does not contain any substances regulated as  
pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).     
CERCLA: This material, as supplied, does not contain any substances regulated as  
hazardous substances under the Comprehensive Environmental Response Compensation  
and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and           
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting          
requirements at the local, regional, or state level pertaining to releases of this
SARA Section 311/312 Hazard Classes |Acute Health Hazard: No                      
                                    |Chronic Health Hazard: Yes                   
                                    |Fire Hazard: No                              
                                    |Sudden release of pressure hazard: No        
                                    |Reactive Hazard: No                          
Toxic Substances Control Act (TSCA) |Complies                                     

15.2      US State Regulations
California Proposition 65: This product does not contain any Proposition 65       
U.S. State Right-to-Know Regulations:                                             
Chemical Name                                                                     
New Jersey                                                                        
Rhode Island                                                                      
Supplier Trade Secret                                                             


Revision date   |01-Jun-2015                                                      
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
GHS Full Text Phrases:                                                            
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Grainger disclaimer.

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.