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Material Safety Data Sheet | | Date of issue: |Revision Date: 11/04/2011 |Revision Number: Imperial Supplies Part Number: 0057760 1. PRODUCT AND COMPANY IDENTIFICATION Manufacturer: 3M - Automotive Aftermarket 3M Center, St. Paul, MN 55144-1000 Telephone Emergency Phone: 1-800-364-3577 or (651) 737-6501 (24 hours) Product Name: 3M(TM) Perfect-It(TM) Rubbing Compound PN 06085, 06086, 06087, 39060 Product Code(s): 22-5036-3, LB-K100-0674-3, LB-K100-0309-2, 60-4550-3485-4, 60-4550-3486-2, 60-4550-3487-0, 60-4550-3488-8, 60-4550-3638-8, 60-4550-3747-7, 60-4550-3748-5, 60-4550-5178-3, 60-4550-5180-9, 60-4550-5181-7, 60-4550-5256-7, XG-0038-1447-0 Recommended Use: Intended Use: Automotive UN-Number: Product Type: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Odor, Color, Grade: Creamy off-white liquid; Solvent odor General Physical Form: Liquid Appearance: |Physical State: Liquid |Odor: Creamy off-white | |liquid; Solvent odor Potential Health Effects Principle Routes of Exposure Acute Effects: Eyes |Mild Eye Irritation: Signs/symptoms may include |redness, pain, and tearing. Skin |Mild Skin Irritation: Signs/symptoms may include |localized redness, swelling, and itching. Allergic |Skin Reaction (non-photo induced): Signs/symptoms |may include redness, swelling, blistering, and |itching. Inhalation |Intentional concentration and inhalation may be |harmful or fatal. Respiratory Tract Irritation: |Signs/symptoms may include cough, sneezing, nasal |discharge, headache, hoarseness, and nose and throat |pain. Prolonged or repeated exposure may cause: |Pneumoconiosis: Sign/symptoms may include persistent |cough, breathlessness, chest pain, increased amounts |of sputum, and changes in lung function tests. May |be absorbed following inhalation and cause target |organ effects. Ingestion |Gastrointestinal Irritation: Signs/symptoms may |include abdominal pain, stomach upset, nausea, |vomiting and diarrhea. May be absorbed following |ingestion and cause target organ effects. Notes: Chronic Effects: Eyes | Skin | Inhalation | Ingestion | Notes: Aggravated Medical Conditions Environmental Hazard: May cause allergic skin reaction. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical/Ingredient Name |CAS-No |Weight% |ACGIH, |OSHA-PE|Other | | |TLV-TWA |L | WATER |7732-18-5 |40-70 | | | KEROSENE |8008-20-6 |10 30 | | | ALUMINUM OXIDE |1344-28-1 |10 30 | | | CASTOR OIL |8001-79-4 |1- 5 | | | WHITE MINERAL OIL |8042-47-5 |0.5 - 1.5 | | | (PETROLEUM) | | | | | ETHYLENE OXIDE, POLYMER |26316-40-5 |0.1 - 1 | | | WITH ETHYLENEDIAMINE AND | | | | | PROPYLENE OXIDE | | | | | POLY(OXY-1,2 |34398-01-1 |0.1 - 1 | | | ETHANEDIYL),.ALPHA.-UNDEC| | | | | YL .OMEGA.-HYDROXY- | | | | | NAPHTHALENE |91-20-3 |< 0.08 | | | | | | | | | | | | | | | | | | | | | | | Notes 4. FIRST AID MEASURES General Advice Eyes |Flush eyes with large amounts of water. If |signs/symptoms persist, get medical attention. Skin |Remove contaminated clothing and shoes. Immediately |flush skin with large amounts of water. Get medical |attention. Wash contaminated clothing and clean shoes |before reuse. Inhalation |Remove person to fresh air. If signs/symptoms |develop, get medical attention. Ingestion |If Swallowed: Do not induce vomiting unless |instructed to do so by medical personnel. Give victim |two glasses of water. Never give anything by mouth to |an unconscious person. Get medical attention. Notes to Physician | Protection of | First-aiders | Notes | 5. FIRE-FIGHTING MEASURES Flammability/Flammable | properties | Flash point |No flash point Recommended Extinguishing |Use fire extinguishers with class B Media |extinguishing agents (e.g., dry chemical, |carbon dioxide). Special Fire-Fighting |Wear full protective equipment (Bunker Gear) Procedures |and a self-contained breathing apparatus |(SCBA). | Explosion Data |No unusual fire or explosion hazards are |anticipated. Sensitivity to Mechanical | Impact | Sensitivity to Static | Discharge | | Specific Hazards from | Chemical | | Protective Equipment | NFPA |Health Hazard: |Flammability: 1|Instability:|Physical Hazard |2 | |0 | HMIS |Health Hazard: |Flammability: |Physical |PPE: | | |Hazard: | 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Environmental Precautions: For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Methods for Containment Methods for Cleaning Up: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Notes 7. HANDLING AND STORAGE Handling: Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid skin contact. Keep out of the reach of children. Store work clothes separately from other clothing, food and tobacco products. No smoking: Smoking while using this product can result in contamination of the tobacco and/or smoke and lead to polymer fume fever caused by the formation of the hazardous decomposition products mentioned in the Reactivity Data section of this MSDS. Do not breathe vapors. Do not breathe dust. Storage: Keep container in well-ventilated area. Store away from areas where product may come into contact with food or pharmaceuticals. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name |ACGIH TLV |OSHA PEL |NIOSH IDLH |OTHER ALUMINUM OXIDE |1 mg/m3 |5 mg/m3 | |CMRG TWA 1 | |TWA, as total | |fiber/cc | |dust 15 mg/m3 | | | |TWA, | | | |respirable | | | |fraction | | | |5 mg/m3 | | | |TWA, as total | | | |dust 15 mg/m3 | | KEROSENE |TWA, as total| | |CMRG TWA | | | |500 ppm |hydrocarbon | | | |vapor, | | | |non-aerosol | | | |200 mg/m3 | | | |Skin Notation| | | MINERAL OILS, |TWA, | | | HIGHLY-REFINED |inhalable | | | OILS |fraction | | | |5 mg/m3 | | | NAPHTHALENE |TWA 10 ppm |TWA 50 mg/m3 | | |Skin Notation| | | | | | | |STEL 15 ppm | | | |Skin Notation| | | WHITE MINERAL OIL| | | |CMRG TWA 5 (PETROLEUM) | | | |mg/m3 | | | |CMRG STEL | | | |10 mg/m3 Engineering Measures: Provide appropriate local exhaust ventilation on open containers. Use in an enclosed process area is recommended. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use in a well-ventilated area. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Personal Protective Equipment Eyes/Face |Avoid eye contact. The following eye protection(s) Protection |are recommended: Safety Glasses with side shields |Indirect Vented Goggles. Skin and Body |Avoid skin contact. Select and use gloves and/or Protection |protective clothing to prevent skin contact based on |the results of an exposure assessment. Consult with |your glove and/or protective clothing manufacturer |for selection of appropriate compatible materials. |Gloves made from the following material(s) are |recommended: Neoprene, Nitrile Rubber. Respiratory |Do not breathe vapors. Do not breathe dust. Select Protection |one of the following NIOSH approved respirators based |on airborne concentration of contaminants and in |accordance with OSHA regulations: Half facepiece or |fullface air-purifying respirator with organic vapor |cartridges and P100 particulate prefilters. Select |and use respiratory protection to prevent an |inhalation exposure based on the results of an |exposure assessment. Consult with your respirator |manufacturer for selection of appropriate types of |respirators. Ventilation/Other | Hygiene Measures 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance | |Odor |Solvent odor Odor Threshold | |Physical State |Liquid Color |Creamy |Viscosity | |off-white | | |liquid | | pH |7.5 - 8.5 |Percent Volatile, |80.6 % | |wt. % | Flash Point |No flash |Auto-ignition |No data available |point |Temperature | Decomposition | |Boiling Point/ Range|100 �C Temp | | | Melting | |Freezing Point | Point/Range | | | Flammability | |Explosion Limits | Specific Gravity |1.06 - 1.08 |Water Solubility |No Data Available |[Ref Std: | |Moderate |WATER=1] | | Solubility | |Evaporation Rate |No Data Availabl Vapor Pressure |18 mmHg [@ 20|Vapor Density | |�C] | | VOC content, wt. |16.1 % weight| | % | | | |176 g/l | | |Less H2O & | | |Exempt | | |Solvents 563 | | |g/l | | | | | Notes 10. STABILITY AND REACTIVITY Chemical Stability |Stable. Incompatible Products |None known. Conditions to avoid |None known. Hazardous Decomposition |Substance Products |Condition |Carbon monoxide During |Combustion |Carbon dioxide During |Combustion |Oxides of Nitrogen During |Combustion Hazardous Polymerization |Hazardous polymerization will not occur. Notes 11. TOXICOLOGY INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Acute Toxicity Product | Information | Inhalation | Eye Contact | Skin Contact | Ingestion | Chemical Name |LD50 Oral |LD50 Dermal |LC50 Inhalation | | | | | | Chronic Toxicity| Chemical Name |ACGIH |IARC |NTP |OSHA | | | | | | | | Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. 12. ECOLOGICAL INFORMATION Ecotoxicity: Not determined. The Environmental impact of this product has been fully investigated Chemical Name|Toxicity to |Toxicity to |Tox, to |Daphnia Magna |Algea |Fish |Microorganisms|(water flea) | | | | | | | | | | | | Notes: CHEMICAL FATE INFORMATION: Not determined. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Dispose of waste product in a permitted hazardous waste facility. Dispose of waste product in a permitted hazardous waste facility. Contaminated Packaging US EPA Waste number Notes: Since regulations vary, consult applicable regulations or authorities before disposal. 14. TRANSPORTATION INFORMATION For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. DOT UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | Emergency Response | Guide Number | TDG UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | MEX | UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | ICAO UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | IATA UN-Number | Proper Shipping name| Hazard Class | Packing Group | ERG Code | Description | IMDG/IMO UN-Number | Proper Shipping name| Hazard Class | Packing Group | EmS No. | Description | RID UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADR UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADN UN-Number Proper Shipping name Hazard Class Packing Group Classification Code Special Provisions Description Hazard Labels Limited Quantity 15. REGULATORY INFORMATION International Inventories TSCA: This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status NAPHTHALENE 91-20-3 Toxic Substances Applicable Control Act (TSCA) 4 Test Rule Chemicals The components of this product are in compliance with the chemical notification requirements of TSCA. DSL EINECS: All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. ENCS IECSC PICCS AICS U.S. Federal Regulations: Contact 3M for more information. SARA 313: Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt ALUMINUM OXIDE 1344-28-1 10 - 30 ALUMINUM OXIDE (ALUMINUM OXIDE (FIBROUS FORMS ONLY)) 1344-28-1 10 - 30 SARA 311/312 Hazard Categories Acute Health Hazard: Yes Chronic Health Hazard: Yes Fire Hazard: No Sudden Release of Pressure Hazard: No Reactive Hazard: No Clean Water Act CERCLA U.S. State Regulations: STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification NAPHTHALENE 91-20-3 **Carcinogen ** WARNING: contains a chemical which can cause cancer. U.S. State Right-to-Know Regulations International Regulations: Contact 3M for more information. Canada 16. OTHER INFORMATION Prepared By: Revision Date: 11/04/2011 Company: 3M - Automotive Aftermarket Revision number Telephone number: 1-800-364-3577 or (651) 737-6501 (24 hours) Notes Other Information Disclaimer information: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. END OF MATERIAL SAFETY DATA SHEET
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.