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Safety Data Sheet Date of Issue: 07/18/14 |Revision Date: |Revision Number: 2.01 Imperial Supplies Part Number: 0057750 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Liquid. Product Name: 3M Machine Polish, PN 05986, 05996, 39009, 39809 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Automotive, Automotive Polish. 1.3. Name, Address, and Telephone of the Responsible Party Company 3M Automotive Aftermarket 3M Center, St. Paul, MN 55144-1000, USA Phone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency Telephone Number Emergency | 1-800-364-3577 or (651) 737-6501 (24 hours) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 1. Sensitizer | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat| | | | | |ion Mark| | | | | Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |May cause an allergic skin reaction. Precautionary Statements |General: (GHS-US) |Keep out of reach of children. |Prevention: |Avoid breathing dust/fume/gas/mist/vapors/spray. |Wear protective gloves. |Contaminated work clothing must not be allowed out |of the workplace. |Response: |IF ON SKIN: Wash with plenty of soap and water. |If skin irritation or rash occurs: Get medical |advice/attention. |Wash contaminated clothing before reuse. |Disposal: |Dispose of contents/container in accordance with |applicable local/regional/national/international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Water |7732-18-5 |60 - 100| | |Trade | | |Secret *| Hydrotreated Light Petroleum |64742-47-8 |10 - 30 | Distillates | |Trade | | |Secret *| Decamethylcyclopentasiloxane |541-02-6 |< 7 | | |Trade | | |Secret *| Aluminum Oxide |1344-28-1 |3 - 7 | | |Trade | | |Secret *| Ceramic Materials and Wares, |66402-68-4 |1 - 5 | Chemicals | |Trade | | |Secret *| Dodecamethylcyclohexasiloxane |540-97-6 |< 5 | | |Trade | | |Secret *| Ethylene oxide, polymer with |26316-40-5 |0.1 - 1 | ethylenediamine and propylene | |Trade | oxide | |Secret *| SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. First-aid Measures After Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. First-aid Measures After Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. First-aid Measures After Ingestion: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See Section 11.1. Information on toxicological effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Not applicable. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Closed containers exposed to heat from fire may build pressure and explode. Explosion Hazard: Substance Condition Hydrocarbons During Combustion Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store away from acids. Store away from oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Ingredient C.A.S. No. Agency Limit type Additional Comments Aluminum Oxide 1344-28-1 CMRG TWA:1 fiber/cc Aluminum Oxide 1344-28-1 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Aluminum, insoluble compounds 1344-28-1 ACGIH TWA(respirable fraction):1 mg/m3 A4: Not class. as human Carcin Decamethylcyclopentasiloxane 541-02-6 CMRG TWA:10 ppm Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA:165 ppm Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non aerosol):200 mg/m3 Skin Notation, A3: Confirmed animal carcin. 8.2. Exposure Controls Appropriate Engineering |Use general dilution ventilation and/or local Controls |exhaust ventilation to control airborne exposures to |below relevant Exposure |Limits and/or control |dust/fume/gas/mist/vapors/spray. If ventilation is |not adequate, use respiratory protection equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Select and use eye/face protection to prevent |contact based on the results of an exposure |assessment. The following eye/face protection(s) are |recommended: Safety Glasses with side shields. Skin and Body Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective Clothing. |Gloves made from the following material(s) are |recommended: |Neoprene. Respiratory Protection |An exposure assessment may be needed to decide if a |respirator is required. If a respirator is needed, |use respirators as part of a full respiratory |protection program. Based on the results of the |exposure assessment, select from the following |respirator type(s) to reduce inhalation exposure: |Half facepiece or full facepiece air-purifying |respirator suitable for organic vapor and |particulates For questions about suitability for a |specific application, consult with you respirator |manufacturer. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance | Odor |Slight solvent odor. Grey liquid. Odor Threshold |No Data Available pH |7.5 - 8.5 Relative Evaporation Rate |No Data Available (butylacetate=1) | Melting Point |No Data Available Freezing Point | Boiling Point |212 ÂºF Flash Point |>=200 ÂºF [Test Method: Closed Cup] Auto-ignition Temperature |No Data Available Decomposition Temperature |No Data Available Flammability (solid, gas) |Not Applicable Vapor Pressure |18 mmHg Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |0.958 - 1.006 [Ref Std: WATER=1] Solubility |Solubility In Water: No Data Available |Solubility- non-water: No Data Available Partition coefficient: |No Data Available n-octanol/water | Viscosity |16,000 - 20,000 centipoise [Test Method: |Brookfield] Lower Flammable Limit |No Data Available Upper Flammable Limit |No Data Available 9.2. Other Information Volatile Organic Compounds: 14.7 % [Test Method: calculated per CARB title 2] Percent volatile: 81.6 % VOC Less H2O & Exempt Solvents: 453 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Light. 10.5 Incompatible Materials Strong acids Strong oxidizing agents. 10.6 Hazardous Decomposition Products None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Symptoms/Injuries After Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Symptoms/Injuries After Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Symptoms/Injuries After Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicological information: Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. As a disposal alternative, Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Additional Information: EPA Hazardous Waste Number (RCRA): Not regulated. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Contact 3M for more information. Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Aluminum Oxide 1344-28-1 3 - 7 Aluminum Oxide (ALUMINUM OXIDE 1344-28-1 3 - 7 (FIBROUS FORMS ONLY)) SARA Section 311/312 Hazard Classes |Fire Hazard - No |Pressure Hazard - No |Reactivity Hazard - No |Immediate Hazard - Yes |Delayed Hazard - Yes Toxic Substances Control Act (TSCA) |The components of this product are in |compliance with the chemical notification |requirements of TSCA. |Contact 3M for more information. 15.2 US State Regulations <COMPONENT> Contact 3M for more information. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.