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Safety Data Sheet | | Date of Issue: 06-27-2013 |Revision Date: 04-06-2014 |Revision Number: 03 Imperial Supplies Part Number: 0056510 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Liquid. Product Name: American Safety Technologies AS-150 HAPS Free Black CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Not available. 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Engineered Polymers 130 Commerce Drive Montgomeryville, PA 18936 United States Phone: (215) 855-8450 1.4. Emergency Telephone Number Emergency |CHEMTREC (800) 424-9300, International (703) 527-3887 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 3 liquids | Acute |Category 5 toxicity, | dermal | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame | | | | | Signal Word (GHS-US) |Flammable liquid and vapor. May be harmful in |contact with skin. Hazard Statements (GHS-US) |Prevention: |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. Keep container tightly closed. |Ground/bond container and receiving equipment. Use |explosion-proof electrical/ventilating/lighting |equipment. Use only non-sparking tools. Take |precautionary measures against static discharge. |Wear protective gloves/eye protection/face |protection. |Response: |If on skin (or hair): Take off immediately all |contaminated clothing. Rinse skin with water/shower. |In case of fire: Use appropriate media to |extinguish. |Storage: |Store in a well-ventilated place. Keep cool. |Disposal: Dispose of contents/container in |accordance with |local/regional/national/international regulations. Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) 1-Chloro-4-(trimethyl)benzene |98-56-6 |10 - 30 | Crystalline SiO2 (Quartz) |14808-60-7 |10 - 30 | Nepheline Syenite |37244-96-5 |10 - 30 | 1,2,4-Trimethylbenzene |95-63-6 |1 - < 3 | 1-Methoxy-2-propanol |107-98-2 |1 - < 3 | Aromatic Hydrocarbon Solvents |64742-95-6 |1 - < 3 | Carbon Black |1333-86-4 |0.1 - 1 | Other components below | |15 - 40 | reportable levels | | | *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Move to fresh air. Call a physician if symptoms develop or persist. First-aid Measures After Skin Contact: Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops and persists. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. General fire hazards: Flammable liquid and vapor. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Specific methods: Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Protection During Firefighting: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Do not smoke. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Wash contaminated clothing before reuse. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in original tightly closed container. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Keep in an area equipped with sprinklers. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Carbon Black (CAS 1333-86-4) PEL 3.5 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) Components Type Value Form Crystalline SiO2 (Quartz) (CAS 14808-60-7) TWA 0.3 mg/m3 0.1 mg/m3 2.4 millions of particle Total dust. Respirable. Respirable. US. ACGIH Threshold Limit Values Components Type Value Form 1,2,4-trimethylbenzene (CAS 95-63-6) TWA 25 ppm 1-methoxy-2-propanol (CAS 107-98-2) STEL TWA 100 ppm 50 ppm Carbon Black (CAS 1333-86-4) TWA 3 mg/m3 Inhalable fraction. Crystalline SiO2 (Quartz) (CAS 14808-60-7) TWA 0.025 mg/m3 Respirable fraction. US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form 1,2,4-trimethylbenzene (CAS 95-63-6) TWA 125 mg/m3 25 ppm 1-methoxy-2-propanol (CAS 107-98-2) STEL TWA 540 mg/m3 150 ppm 360 mg/m3 100 ppm Carbon Black (CAS 1333-86-4) TWA 0.1 mg/m3 Crystalline SiO2 (Quartz) (CAS 14808-60-7) TWA 0.05 mg/m3 Respirable dust. Biological limit values: No biological exposure limits noted for the ingredient(s). Exposure guidelines: US - California OELs: Skin designation: 1-methoxy-2-propanol (CAS 107-98-2) Can be absorbed through the skin. 8.2. Exposure Controls Appropriate Engineering |Explosion-proof general and local exhaust Controls |ventilation. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves. Eye Protection |Wear eye/face protection. Wear safety glasses with |side shields (or goggles). Skin and Body Protection |Other: Wear appropriate chemical resistant clothing. Respiratory Protection |If engineering controls do not maintain airborne |concentrations below recommended exposure limits |(where applicable) or to an acceptable level (in |countries where exposure limits have not been |established), an approved respirator must be worn. |When workers are facing concentrations above the |exposure limit they must use appropriate certified |respirators. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance |Liquid. Odor |Pungent. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |> 240 Â°F (> 115.56 Â°C) Flash Point |105.0 Â°F (40.6 Â°C) Auto-ignition Temperature |894.2 Â°F (479 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |8 mm Hg Relative Vapor Density at 20 Â°C |Not available. Relative Density |Not available. Specific Gravity |1.83 Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |Not available. Upper Flammable Limit |Not available. 9.2. Other Information Density: 1.83 g/cm3 Flammability class: Combustible II estimated VOC (Weight %): 98 g/l SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions Hazardous polymerization does not occur. 10.4 Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be harmful in contact with skin. Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: IARC Monographs. Overall Evaluation of Carcinogenicity: Carbon Black (CAS 1333-86-4) 2B Possibly carcinogenic to humans. Crystalline SiO2 (Quartz) (CAS 14808-60-7) 1 Carcinogenic to humans. US. National Toxicology Program (NTP) Report on Carcinogens: Crystalline SiO2 (Quartz) (CAS 14808-60-7) Known To Be Human Carcinogen. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): Not classified. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Not available. Symptoms/Injuries After Inhalation: Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: May be harmful in contact with skin. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Expected to be a low ingestion hazard. Chronic Symptoms: Prolonged inhalation may be harmful. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal instructions: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Paint Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN1263 | Label Codes |3 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Paint Hazard Class |3 Identification Number|UN1263 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |Not available. | EmS-No. (Spillage) |Not available. | 14.3 In Accordance with IATA Proper Shipping Name |Paint Identification Number|UN1263 |<PICTOGRAM PHRASE> Hazard Class |3 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |3L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. CERCLA Hazardous Substance List (40 CFR 302.4): 1-methoxy-2-propanol (CAS 107-98-2) LISTED US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed. SARA 304 Emergency release notification: Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration: 1,2,4-trimethylbenzene (CAS 95-63-6) % 1.0 US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance: 1,2,4-trimethylbenzene (CAS 95-63-6) Listed. SARA 302 Extremely hazardous substance: No. SARA 313 (TRI reporting): Chemical name CAS number % by wt. 1,2,4-trimethylbenzene 95-63-6 1 - < 3 Aluminium Oxide 1344-28-1 0.1 - 1 Benzene 71-43-2 0 - 0.1 Ethyl Benzene 100-41-4 0 - 0.1 Other federal regulations: Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Safe Drinking Water Act (SDWA): Not regulated. SARA Section 311/312 Hazard Classes |Immediate Hazard - No |Delayed Hazard - No |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |1-Chloro-4-(trimethyl)benzene (CAS 98-56-6) |1.0 % One-Time |Export Notification only. 15.2 US State Regulations <COMPONENT> US. Massachusetts RTK - Substance List: 1,2,4-trimethylbenzene (CAS 95-63-6) 1-methoxy-2-propanol (CAS 107-98-2) Carbon Black (CAS 1333-86-4) Crystalline SiO2 (Quartz) (CAS 14808-60-7) US. New Jersey Worker and Community Right-to-Know Act: 1,2,4-trimethylbenzene (CAS 95-63-6) 500 lbs US. Pennsylvania RTK - Hazardous Substances: 1,2,4-trimethylbenzene (CAS 95-63-6) 1-methoxy-2-propanol (CAS 107-98-2) Carbon Black (CAS 1333-86-4) Crystalline SiO2 (Quartz) (CAS 14808-60-7) US. Rhode Island RTK: 1,2,4-trimethylbenzene (CAS 95-63-6) US. California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance: Attapulgite (CAS 12174-11-7) Listed: December 28, 1999 Benzene (CAS 71-43-2) Listed: February 27, 1987 Carbon Black (CAS 1333-86-4) Listed: February 21, 2003 Crystalline SiO2 (Quartz) (CAS 14808-60-7) Listed: October 1, 1988 Cumene (CAS 98-82-8) Listed: April 6, 2010 Ethyl Benzene (CAS 100-41-4) Listed: June 11, 2004 Titanium Dioxide (CAS 13463-67-7) Listed: September 2, 2011 US - California Proposition 65 - CRT: Listed date/Developmental toxin: Benzene (CAS 71-43-2) Listed: December 26, 1997 Chloromethane (CAS 74-87-3) Listed: March 10, 2000 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin: Toluene (CAS 108-88-3) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin: Benzene (CAS 71-43-2) Listed: December 26, 1997 Chloromethane (CAS 74-87-3) Listed: August 7, 2009 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |04-06-2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.