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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Black-Ice Stop Rust Rim Release CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Tire Mounting & Demounting 1.3. Name, Address, and Telephone of the Responsible Party Company: Rema Tip Top - North America 119 Rockland Ave. Northvale, NJ 07647 Phone: 201 256-8200 1.4. Emergency Telephone Number Emergency | North America: 800-424-9300 (CHEMTREC) number |International: 703-527-3887 (CHEMTREC) Collect Calls Accepted SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 Irritation | Eye Irritation|Category 2A Specific |Category 3 Target Organ | Systemic | Toxicity, | Single | Exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |H315: Causes skin irritation |H319: Causes serious eye irritation |H335: May cause respiratory irritation Precautionary Statements |Prevention: (GHS-US) |P233: Keep container tightly closed. |P261: Avoid breathing vapours. |P264: Wash skin and exposed areas thoroughly after |handling. |P271: Use only outdoors or in a well-ventilated |area. |P280: Wear protective gloves/eye protection. |Response: |P302 - P352: IF ON SKIN: Wash with plenty of soap |and water. |P304 + P340: IF INHALED: Remove victim to fresh an |and keep at rest in a position comfortable for |breathing. |P305 + P351 + P33S: IF IN EYES: Rinse cautiously |with water for several minutes. Remove contact |lenses, if present and easy to do. Continue rinsing. | |P312: Call a POISON CENTER or doctor/physician if |you feel unwell. |P321: Specific treatment found in supplemental First |Aid Section of tins SDS (Section 4). |P332 - P313: If skin irritation occurs: Get medical |advice attention. |P337 + P313: If eye irritation persists: Get medical |advice/attention. |P362: Take off contaminated clothing and wash before |reuse. |Storage: |P403 + P233: Store in a well-ventilated place. Keep |container tightly closed. |P405: Store locked up |Disposal: |P501: Dispose of contents/container ui accordance |with local, regional, and federal regulations 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Naphthenie Distillates, |64741-96-4 |35 - 50 | petroleum, refined | | | 12-Hydrostearic Acid |106-14-9 |5 - 10 | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If breathing has stopped, begin artificial respiration. If breathing is difficult, administer oxygen. If symptoms persist, seek medical attention. First-aid Measures After Skin Contact: Immediately wash skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes while washing. If skin irritation or rash occurs, seek medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Immediately rinse eyes with water for at least 15 minutes. Remove contact lenses after the initial few minutes and if easy to do so and resume rinsing. Rinse beneath eyelids by holding eyelids apart with clean fingers while rinsing. Seek immediate medical attention. First-aid Measures After Ingestion: Seek immediate medical attention. Do NOT induce vomiting. If the victim is drowsy or unconscious, do not give anything by mouth. Place individual on their left side and place their head down. Do not leave victim unattended. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Respiratory tract irritation, Nose, throat, and lung irritation, headache, nausea Symptoms/Injuries After Skin Contact: Skin irritation, redness Symptoms/Injuries After Eye Contact: Eye irritation, stinging, tearing, redness, swelling of the eyes Symptoms/Injuries After Ingestion: Mouth and throat bums, headache, nausea Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Dry chemical. Carbon dioxide, Alcohol-resistant foam Unsuitable Extinguishing Media: Direct water stream (See Precautions) 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Asphyxiants, Hydrocarbons, Carbon monoxide. Carbon dioxide Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Do not use direct water stream as this may spread fire as well as result in splattering. Product is slightly combustible. Flammable vapors may be emitted when product is heated above the published flash point. Use water spray to cool fire exposed containers and structures if this can be done with minimal risk. Avoid spreading burning material with water used for cooling purposes. Firefighting Instructions: Protection During Firefighting: Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Persons not wearing proper PPE should be excluded from the area of contamination until clean-up has been completed. Ensure adequate ventilation. Eliminate all ignition sources and pay attention to the spreading of gases, especially at ground level. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Recommended to wear splash goggles with side shields as well as resistant gloves, such as polyvinyl alcohol-based gloves, and discard of gloves that show tears, pinholes, or signs of wear. Wear proper garments to prevent skin exposure, such as long-sleeves and pants. Emergency Procedures: 6.2. Environmental Precautions Do not allow discharge into drains, surface waters, or sanitary sewer system. Prevent spreading over a wide area by constructing a dike. Local authorities should be advised if significant spillages cannot be contained or if material discharges into drains or ground water. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Eliminate all sources of ignition. Use non-sparking tools for material containment and collection. Ventilate the contaminated area. Contained spilled material with inert, non-combustible absorbent materials (e.g. sand, earth, diatomaceous earth, vermiculite). Transfer to a suitable container for disposal according to proper federal, state, and local regulations. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Containers of tins material may be hazardous when emptied. Since emptied Containers retain product residues (vapor, liquid, or solid), all hazard precautions given in tins SDS must be observed. Use only non-sparking tools. Do not cut. weld, braze, solder, or expose containers to other ignition sources. Wear proper PPE when handling this product including protective gloves and splash goggles. Avoid prolonged skin contact and breathing of product vapors. Use with adequate ventilation. Regular laundering of contaminated clothing is essential to reduce indirect skin contact with this material. Hygiene Measures: Do not inhale vapors. Wash hands before breaks and immediately after handling product. When using, do not eat, drink, or smoke. Wash contaminated clothing before re-use. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a well- ventilated area, away from heat and ignition sources. Keep container tightly closed and store locked up. Keep away from food, drink, and animal foodstuffs. Incompatible Materials: Bases, Oxidizing agents, Reducing agents 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Limits: Exposure limits have not been established for this product. 8.2. Exposure Controls Appropriate Engineering |Provide sufficient mechanical (general and or local Controls |exhaust) ventilation to maintain exposures below |permissible exposure limits. Provide readily |accessible eye wash stations and safety showers. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Recommended to wear suitable resistant gloves and |discard of gloves that show tears, pinholes, or |signs of wear. Suitable gloves will be based on |product use and the period of use, and may include |neoprene, butyl-rubber, nitrile rubber, etc. Eye Protection |Recommended to wear chemical splash goggles with |side shields when there is potential for the |exposure of the eyes to the liquid or vapor. Have a |suitable eye wash station or bottle nearby in case |of splashing into the eyes. Skin and Body Protection |Recommended to wear long-sleeved clothing, pants and |proper foot covering m order to prevent direct skin |contact with the product. If skin irritation |develops, contact your facility health and safety |professional or your local safety equipment supplier |to determine the proper personal protective |equipment for your use. Respiratory Protection |A NIOSH-approved air-purifying respirator with an |appropriate cartridge and/or filter may be |appropriate under certain circumstances where |airborne concentrations are expected to exceed |exposure limits (if applicable) or if overexposure |has otherwise been determined. Protection provided |by air-purifying respirators is limited. Use a |positive pressure, air-supplied respirator if there |is any potential for uncontrolled release, exposure |levels are not known or any other circumstances |where an air-purifying respirator may not provide |adequate protection. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Black Liquid Odor |Petroleum Odor Odor Threshold |No data available pH |No data available Relative Evaporation Rate |No data available (butylacetate=1) | Melting Point |No data available Freezing Point |No data available Boiling Point |> 572Â°F (> 300Â°C) Flash Point |> 392Â°F (> 200Â°C) Auto-ignition Temperature |No data available Decomposition Temperature |No data available Flammability (solid, gas) |No data available Vapor Pressure |< 0.01 mm Hg at 6SÂ°F (20Â°C) Relative Vapor Density at 20 Â°C |No data available Relative Density | Specific Gravity | Solubility |Insoluble Partition coefficient: |No data available n-octanol/water | Viscosity |No data available Lower Flammable Limit |No data available Upper Flammable Limit |No data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No decomposition if stored and applied as directed. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Product will not undergo hazardous polymerization if storage and use guidelines are followed. 10.4 Conditions to Avoid Heat, Flames, Sparks, Other ignition sources, Excessive heat 10.5 Incompatible Materials Bases, Oxidizing agents. Reducing agents. 10.6 Hazardous Decomposition Products Asphyxiants, Hydrocarbons, Carbon monoxide, Carbon dioxide SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Acute toxicities are calculated based on component toxicities Mixture: Acute Oral Toxicity: No data available Acute Dermal Toxicity: No data available Acute Inhalation Toxicity: No data available Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: OSHA: No International Agency for Research on Cancer (IARC): No; 3 [Not Classifiable] ACGIH: No; A4 (Not Suspected] National Toxicology Program (NTP) Report on Carcinogens: No Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Respiratory tract irritation, Nose, throat, and lung irritation, headache, nausea Symptoms/Injuries After Skin Contact: skin irritation, redness Symptoms/Injuries After Eye Contact: eye irritation, stinging, tearing, redness, swelling of the eyes Symptoms/Injuries After Ingestion: mouth and throat burns Chronic Symptoms: Based on current data, this product is not expected to have any chronic effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Eco-toxicity: This substance is not expected to be toxic to aquatic organisms. It is however, still advised that this substance does not enter the environment. Local authorities should be advised if significant spillages cannot be contained or if material discharges into drains or ground water. 12.2. Persistence and Degradability No data available 12.3. Bioaccumulative Potential No data available 12.4. Mobility in Soil No data available 12.5. Other Adverse Effects No data available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of in accordance with Federal, State or Local regulations. Additional Information: Contaminated packaging should be emptied as far as possible before disposal. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |This product is not regulated as a hazardous material for |transport. Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |This product is not regulated as a dangerous good for |transport. Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |This product is not regulated as a dangerous good for |transport. Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Title III: Section 302 - Extremely Hazardous Chemicals The following ingredients are subject to the supplier notification requirements of Section 302 of the Superfund Amendments and Reauthorization Act (SARA/EPCRA) and the requirements of 40 CFR Part 37: None Listed Section 313 - Toxic Chemicals: The following ingredients are subject to the supplier notification requirements of Section 313 of the Superfund Amendments and Reauthorization Act (SARA/EPCRA) and the requirements of 40 CFR Part 37: None Listed SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |All components of tins product conform to the |US TSCA 15.2 US State Regulations <COMPONENT> California Proposition 65 This product does not contain any chemicals contains chemicals known to the state of California to cause cancer, birth defects, or reproductive harm. The components of this product may be included on the various state hazardous materials lists noted below: California Hazardous Substances List Delaware Air Quality Management List Idaho Air Pollutants List Illinois Toxic Air Contaminants List Maine Hazardous Air Pollutants List Massachusetts Hazardous Substances List Michigan Critical Materials List Minnesota Hazardous Substances List New Jersey RTK Hazardous Substances List New Jersey TCPA Extremely Hazardous Substances List New York List of Hazardous Substances North Carolina Toxic Air Contaminants List Pennsylvania Hazardous Substances List Washington Permissible Exposure Air Contaminants List West Virginia Air Toxic Pollutants List Wisconsin Hazardous Air Contaminants List SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |1/29/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.