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SDS Sheet 0055990

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SECTION 1: IDENTIFICATION | |1.1. Product Identifier
Product Form:                                                                   
 
Product Name: Bead Butter Blue, concentrate                                     
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture:  Tire Mounting & Demounting                       
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Rema Tip Top - North America                                                    
 
119 Rockland Ave.                                                               
 
Northvale, NJ 07647                                                             
 
Phone: 201 256-8200                                                             
 


1.4.  Emergency Telephone Number
Emergency     | North America: 800-424-9300 (CHEMTREC)                          
 
number        |International: 703-527-3887 (CHEMTREC) Collect Calls Accepted    
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Acute Aquatic |Category 3    
Toxicity.     |              
              |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Environment
        
Signal Word (GHS-US)         |                                                  
 
Hazard Statements (GHS-US)   |H402: Harmful to aquatic life                     
 
Precautionary Statements     |                                                  
 
(GHS-US)                     |                                                  
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                           
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Diethanolamine, DEA             |111-42-2             |<1      |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest
 
in a position comfortable for breathing. If breathing has stopped, begin        
 
artificial respiration. If breathing is difficult, administer oxygen. If
symptoms 
persist, seek medical attention.                                                
 
First-aid Measures After Skin Contact: Immediately wash skin with plenty of
water 
for at least 15 minutes. If skin irritation or rash occurs, seek medical        
 
advice/attention.                                                               
 
First-aid Measures After Eye Contact: Rinse eyes with water for a few minutes.  
 
Remove contact lenses after the initial few minutes and if easy to do so and    
 
resume rinsing. If eye irritation develops, seek medical attention.             
 
First-aid Measures After Ingestion: Drink plenty of water in order to dilute    
 
ingested material. If the victim is drowsy or unconscious, do not give anything
by
mouth. If symptoms persist, seek medical attention.                             
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation: : Not expected to be ail inhalation hazard  
 
Symptoms/Injuries After Skin Contact: Slight or no skin irritation              
 
Symptoms/Injuries After Eye Contact: Slight or no eye irritation                
 
Symptoms/Injuries After Ingestion: Digestive tract irritation                   
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
                                                                                
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Water, Dry chemical, Carbon dioxide, Foam         
 
Unsuitable Extinguishing Media: None Identified                                 
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:                                                                    
 
Explosion Hazard: Hazardous Combustion Products: Hydrocarbons, Carbon monoxide, 
 
Carbon dioxide                                                                  
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:  This product is a slight fire hazard. Contain fire
run
off if possible. Unsuitable extinguishing media have not been identified.       
 
Protection During Firefighting: Wear full firefighting turn-out gear (full
Bunker 
gear), and respiratory protection (SCBA).                                       
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Personal Precautions: Persons not wearing proper PPE should be
 
excluded from the area of contamination until clean-up has been completed.
Ensure 
adequate ventilation.                                                           
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:  Recommended to wear chemical splash goggles & gloves and 
 
discard of gloves that show tears, pinholes, or signs of wear. Wear proper      
 
garments to prevent skin exposure, such as long-sleeves and pants.              
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Do not allow discharge into drains, surface waters, or sanitary sewer system.   
 
Prevent spreadmg over a wide area by constructing a dike. Local authorities
should
be advised if significant spillages cannot be contained or if material
discharges 
into drains or ground water.                                                    
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up: Contained spilled material with inert, non-combustible 
 
absorbent materials (e.g. sand, earth, diatomaceous earth, vermiculite).
Transfer 
to a suitable container for disposal according to proper federal, state, and
local
regulations.                                                                    
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Wear proper PPE when handling this product,  
 
which may include protective gloves and chemical splash goggles. Avoid contact  
 
with skin and eyes when possible. Wash hands and contaminated areas thoroughly  
 
after handling and before breaks. Do not eat, drink or smoke when handling this 
 
product.                                                                        
 
Hygiene Measures: Wash hands before breaks and immediately after handling
product.
When using, do not eat, drink, or smoke.                                        
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Keep container tightly closed in a cool, well-ventilated
area.
                                                                                
 
Incompatible Materials: Strong oxidizing agents                                 
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Exposure Limits :                                                               
 
Exposure limits have not been established for this product.                     
 
Diethanolamine, DEA             CAS # 111-42-2                                  
 
ACGIH                                       Threshold Limiting Value (TLV)      
 
2 mg/m3                                                                         
 
NIOSH                                       Recommended Exposure Limit (REL)    
 
3 ppm (15 mg/m3)                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Provide sufficient mechanical (general and or
local 
Controls                     |exhaust) ventilation to maintain exposures below  
 
                             |permissible exposure limits. Provide readily      
 
                             |accessible eye wash stations and safety showers.  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Recommended to wear suitable resistant gloves and 
 
                             |discard of gloves that show tears, pinholes, or   
 
                             |signs of wear. Suitable gloves will be based on   
 
                             |product use and the period of use, and may include
 
                             |neoprene, butyl-rubber, nitrile rubber, etc.      
 
Eye Protection               |Eye Protection: Recommended to wear tight fitting,
 
                             |chemical splash goggles with side shields when
there
                             |is potential for the exposure of the eyes to the  
 
                             |liquid. Have a suitable eye wash station or bottle
 
                             |nearby in case of splashing into the eyes.        
 
Skin and Body Protection     |Skin Protection: Recommended to wear long-sleeved 
 
                             |clothing, pants and proper foot covering in order
to
                             |prevent direct skin contact with the product. If  
 
                             |skin irritation develops, contact your facility   
 
                             |health and safety professional or your local
safety'
                             |equipment supplier to determine the proper
personal 
                             |protective equipment for your use.                
 
Respiratory Protection       |Although unlikely, a NIOSH-approved air-purifying 
 
                             |respirator with an appropriate cartridge and/or   
 
                             |filter may be appropriate under certain           
 
                             |circumstances where airborne concentrations are   
 
                             |expected to exceed exposure limits (if applicable)
 
                             |or if overexposure has otherwise been determined. 
 
                             |Protection provided by air-purifying respirators
is 
                             |limited. Use a positive pressure, air-supplied    
 
                             |respirator if there is any potential for          
 
                             |uncontrolled release, exposure levels are not
known 
                             |or any other circumstances where an air-purifying 
 
                             |respirator may not provide adequate protection.   
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |                                           
 
Appearance                          |Blue Liquid)                               
 
Odor                                |Bland                                      
 
Odor Threshold                      |No data available                          
 
pH                                  |No data available                          
 
Relative Evaporation Rate           |No data available                          
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No data available                          
 
Freezing Point                      |No data available                          
 
Boiling Point                       |>220°F(> 104 Deg.C)                        
 
Flash Point                         |No data available                          
 
Auto-ignition Temperature           |No data available                          
 
Decomposition Temperature           |No data available                          
 
Flammability (solid, gas)           |No data available                          
 
Vapor Pressure                      |No data available                          
 
Relative Vapor Density at 20 °C     |No data available                          
 
Relative Density                    |                                           
 
Specific Gravity                    |                                           
 
Solubility                          |Completely Soluble                         
 
Partition coefficient:              |No data avalable                           
 
n-octanol/water                     |                                           
 
Viscosity                           |No data available                          
 
Lower Flammable Limit               |No data available                          
 
Upper Flammable Limit               |No data available                          
 


9.2.  Other Information
                                                                                
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No decomposition if stored and applied as directed.                             
 


10.2      Chemical Stability
Stable under normal conditions.                                                 
 


10.3      Possibility of Hazardous Reactions
Product will not undergo hazardous polymerization if storage and use guidelines 
 
are followed.                                                                   
 


10.4      Conditions to Avoid
Excessive heat, Freezing                                                        
 


10.5      Incompatible Materials
Strong oxidizing agents                                                         
 


10.6      Hazardous Decomposition Products
Hydrocarbons. Carbon monoxide, Carbon dioxide                                   
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Acute toxicities are calculated based on component toxicities Mixture:          
 
Acute Oral Toxicity: LD50 Rat: > 5,000 mg/kg                                    
 
Acute Dermal Toxicity: LD50 Rabbit: > 5,000 mg/kg                               
 
Acute Inhalation Toxicity: LC50 Rat: > 25.0 mg/1                                
 
                                                                                
 
Diethanolamine. DEA                                                             
 
Acute Oral Toxicity                     CAS U 111-42-2                          
 
Acute Dermal Toxicity                LD50Rat: 710 mg/kg                         
 
LD50 Rabbit: 12,200 mg/kg                                                       
 
Skin Corrosion/Irritation:                                                      
 
Serious Eye Damage/Irritation:                                                  
 
Respiratory or Skin Sensitization:                                              
 
Germ Cell Mutagenicity:                                                         
 
Carcinogenicity:                                                                
 
OSHA: No                                                                        
 
International Agency for Research on Cancer (IARC): No; 4 [Possibly Not         
 
Carcinogenic] ACGIH: No; A5 [Not Suspected]                                     
 
National Toxicology Program (NTP) Report on Carcinogens: No                     
 
Reproductive Toxicity:                                                          
 
Specific Target Organ Toxicity (Single Exposure):                               
 
Specific Target Organ Toxicity (Repeated Exposure):                             
 
Aspiration Hazard:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms: Slight skin or eye irritation, digestive tract irritation.    
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Eco-toxicity: This substance is expected to be toxic to aquatic organisms. It is
 
strongly advised that this substance does not enter the environment. Local      
 
authorities should be advised if significant spillages cannot be contamed or if 
 
material discharges into drams or ground water.                                 
 
Diethanolamine, DEA                         CAS # 111-42-2                      
 
Toxicity to Fish                                    LC50 - 1,4690 mg/1 (Fathead 
 
Minnow; 96 h)                                                                   
 
Toxicity to Daphnia                            EC50 - 55 mg/1 (Water Flea; 24 h)
 


12.2. Persistence and Degradability
This product is readily biodegradable.                                          
 


12.3. Bioaccumulative Potential
No data available                                                               
 


12.4. Mobility in Soil
No data available                                                               
 


12.5. Other Adverse Effects
No data available                                                               
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose of in accordance with Federal, State or 
 
Local regulations.                                                              
 
Additional Information: Contaminated packaging should be emptied as far as      
 
possible before disposal.                                                       
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |This product is not regulated as a hazardous material for 
 
                     |transport.                                                
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |This product is not regulated as a hazardous material for 
 
                     |transport.                                                
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |This product is not regulated as a hazardous material for 
 
                     |transport.                                                
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA Title III:                                                                 
 
Section 302 - Extremely Hazardous Chemicals                                     
 
The following ingredients are subject to the supplier notification requirements
of
Section 302 of the Superfund Amendments and Reauthorization Act (SARA/EPCRA) and
 
the requirements of 40 CFR Part 37:                                             
 
None Listed                                                                     
 
                                                                                
 
Section 313 - Toxic Chemicals                                                   
 
The following ingredients are subject to the supplier notification requirements
of
Section 313 of the Superfund Amendments and Reauthorization Act (SARA/EPCRA) and
 
the requirements of 40 CFR Part 37                                              
 
Component                            CAS #               Weight %               
 
CERCLA RQ                                                                       
 
Diethanolamine, DEA        111-42-2                < 1                          
 
100                                                                             
 
SARA Section 311/312 Hazard Classes |                                           
 
Toxic Substances Control Act (TSCA) |All components of this product conform to
the
                                    |US TSCA                                    
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Proposition 65:                                                      
 
Tins product does not contain chemicals known to the state of California to
cause 
cancer, birth defects or reproductive harm.                                     
 
                                                                                
 
The components of this product may be included on the various state hazardous   
 
materials lists noted below.                                                    
 
California Hazardous Substances List                                            
 
Delaware An Quality Management List                                             
 
Idaho Air Pollutants List                                                       
 
Illinois Toxic Air Contaminants List                                            
 
Maine Hazardous An Pollutants List                                              
 
Massachusetts Hazardous Substances List                                         
 
Michigan Critical Materials List                                                
 
Minnesota Hazardous Substances List                                             
 
New Jersey RTK Hazardous Substances List                                        
 
New Jersey TCPA Extremely Hazardous Substances List                             
 
New York List of Hazardous Substances                                           
 
North Carolina Toxic Air Contaminants List                                      
 
Pennsylvania Hazardous Substances List                                          
 
Washington Permissible Exposure Air Contaminants List                           
 
West Virginia Air Toxic Pollutants List                                         
 
Wisconsin Hazardous Air Contaminants List                                       
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |1/29/2014                                                      
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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