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SECTION 1: IDENTIFICATION | |1.1. Product Identifier Product Form: Product Name: Bead Butter Blue, concentrate CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Tire Mounting & Demounting 1.3. Name, Address, and Telephone of the Responsible Party Company Rema Tip Top - North America 119 Rockland Ave. Northvale, NJ 07647 Phone: 201 256-8200 1.4. Emergency Telephone Number Emergency | North America: 800-424-9300 (CHEMTREC) number |International: 703-527-3887 (CHEMTREC) Collect Calls Accepted SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Acute Aquatic |Category 3 Toxicity. | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Environment Signal Word (GHS-US) | Hazard Statements (GHS-US) |H402: Harmful to aquatic life Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Diethanolamine, DEA |111-42-2 |<1 | | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If breathing has stopped, begin artificial respiration. If breathing is difficult, administer oxygen. If symptoms persist, seek medical attention. First-aid Measures After Skin Contact: Immediately wash skin with plenty of water for at least 15 minutes. If skin irritation or rash occurs, seek medical advice/attention. First-aid Measures After Eye Contact: Rinse eyes with water for a few minutes. Remove contact lenses after the initial few minutes and if easy to do so and resume rinsing. If eye irritation develops, seek medical attention. First-aid Measures After Ingestion: Drink plenty of water in order to dilute ingested material. If the victim is drowsy or unconscious, do not give anything by mouth. If symptoms persist, seek medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: : Not expected to be ail inhalation hazard Symptoms/Injuries After Skin Contact: Slight or no skin irritation Symptoms/Injuries After Eye Contact: Slight or no eye irritation Symptoms/Injuries After Ingestion: Digestive tract irritation Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water, Dry chemical, Carbon dioxide, Foam Unsuitable Extinguishing Media: None Identified 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Hazardous Combustion Products: Hydrocarbons, Carbon monoxide, Carbon dioxide Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: This product is a slight fire hazard. Contain fire run off if possible. Unsuitable extinguishing media have not been identified. Protection During Firefighting: Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Personal Precautions: Persons not wearing proper PPE should be excluded from the area of contamination until clean-up has been completed. Ensure adequate ventilation. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Recommended to wear chemical splash goggles & gloves and discard of gloves that show tears, pinholes, or signs of wear. Wear proper garments to prevent skin exposure, such as long-sleeves and pants. Emergency Procedures: 6.2. Environmental Precautions Do not allow discharge into drains, surface waters, or sanitary sewer system. Prevent spreadmg over a wide area by constructing a dike. Local authorities should be advised if significant spillages cannot be contained or if material discharges into drains or ground water. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Contained spilled material with inert, non-combustible absorbent materials (e.g. sand, earth, diatomaceous earth, vermiculite). Transfer to a suitable container for disposal according to proper federal, state, and local regulations. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Wear proper PPE when handling this product, which may include protective gloves and chemical splash goggles. Avoid contact with skin and eyes when possible. Wash hands and contaminated areas thoroughly after handling and before breaks. Do not eat, drink or smoke when handling this product. Hygiene Measures: Wash hands before breaks and immediately after handling product. When using, do not eat, drink, or smoke. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed in a cool, well-ventilated area. Incompatible Materials: Strong oxidizing agents 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Limits : Exposure limits have not been established for this product. Diethanolamine, DEA CAS # 111-42-2 ACGIH Threshold Limiting Value (TLV) 2 mg/m3 NIOSH Recommended Exposure Limit (REL) 3 ppm (15 mg/m3) 8.2. Exposure Controls Appropriate Engineering |Provide sufficient mechanical (general and or local Controls |exhaust) ventilation to maintain exposures below |permissible exposure limits. Provide readily |accessible eye wash stations and safety showers. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Recommended to wear suitable resistant gloves and |discard of gloves that show tears, pinholes, or |signs of wear. Suitable gloves will be based on |product use and the period of use, and may include |neoprene, butyl-rubber, nitrile rubber, etc. Eye Protection |Eye Protection: Recommended to wear tight fitting, |chemical splash goggles with side shields when there |is potential for the exposure of the eyes to the |liquid. Have a suitable eye wash station or bottle |nearby in case of splashing into the eyes. Skin and Body Protection |Skin Protection: Recommended to wear long-sleeved |clothing, pants and proper foot covering in order to |prevent direct skin contact with the product. If |skin irritation develops, contact your facility |health and safety professional or your local safety' |equipment supplier to determine the proper personal |protective equipment for your use. Respiratory Protection |Although unlikely, a NIOSH-approved air-purifying |respirator with an appropriate cartridge and/or |filter may be appropriate under certain |circumstances where airborne concentrations are |expected to exceed exposure limits (if applicable) |or if overexposure has otherwise been determined. |Protection provided by air-purifying respirators is |limited. Use a positive pressure, air-supplied |respirator if there is any potential for |uncontrolled release, exposure levels are not known |or any other circumstances where an air-purifying |respirator may not provide adequate protection. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Blue Liquid) Odor |Bland Odor Threshold |No data available pH |No data available Relative Evaporation Rate |No data available (butylacetate=1) | Melting Point |No data available Freezing Point |No data available Boiling Point |>220�F(> 104 Deg.C) Flash Point |No data available Auto-ignition Temperature |No data available Decomposition Temperature |No data available Flammability (solid, gas) |No data available Vapor Pressure |No data available Relative Vapor Density at 20 �C |No data available Relative Density | Specific Gravity | Solubility |Completely Soluble Partition coefficient: |No data avalable n-octanol/water | Viscosity |No data available Lower Flammable Limit |No data available Upper Flammable Limit |No data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No decomposition if stored and applied as directed. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Product will not undergo hazardous polymerization if storage and use guidelines are followed. 10.4 Conditions to Avoid Excessive heat, Freezing 10.5 Incompatible Materials Strong oxidizing agents 10.6 Hazardous Decomposition Products Hydrocarbons. Carbon monoxide, Carbon dioxide SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Acute toxicities are calculated based on component toxicities Mixture: Acute Oral Toxicity: LD50 Rat: > 5,000 mg/kg Acute Dermal Toxicity: LD50 Rabbit: > 5,000 mg/kg Acute Inhalation Toxicity: LC50 Rat: > 25.0 mg/1 Diethanolamine. DEA Acute Oral Toxicity CAS U 111-42-2 Acute Dermal Toxicity LD50Rat: 710 mg/kg LD50 Rabbit: 12,200 mg/kg Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: OSHA: No International Agency for Research on Cancer (IARC): No; 4 [Possibly Not Carcinogenic] ACGIH: No; A5 [Not Suspected] National Toxicology Program (NTP) Report on Carcinogens: No Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: Slight skin or eye irritation, digestive tract irritation. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Eco-toxicity: This substance is expected to be toxic to aquatic organisms. It is strongly advised that this substance does not enter the environment. Local authorities should be advised if significant spillages cannot be contamed or if material discharges into drams or ground water. Diethanolamine, DEA CAS # 111-42-2 Toxicity to Fish LC50 - 1,4690 mg/1 (Fathead Minnow; 96 h) Toxicity to Daphnia EC50 - 55 mg/1 (Water Flea; 24 h) 12.2. Persistence and Degradability This product is readily biodegradable. 12.3. Bioaccumulative Potential No data available 12.4. Mobility in Soil No data available 12.5. Other Adverse Effects No data available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of in accordance with Federal, State or Local regulations. Additional Information: Contaminated packaging should be emptied as far as possible before disposal. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |This product is not regulated as a hazardous material for |transport. Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |This product is not regulated as a hazardous material for |transport. Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |This product is not regulated as a hazardous material for |transport. Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Title III: Section 302 - Extremely Hazardous Chemicals The following ingredients are subject to the supplier notification requirements of Section 302 of the Superfund Amendments and Reauthorization Act (SARA/EPCRA) and the requirements of 40 CFR Part 37: None Listed Section 313 - Toxic Chemicals The following ingredients are subject to the supplier notification requirements of Section 313 of the Superfund Amendments and Reauthorization Act (SARA/EPCRA) and the requirements of 40 CFR Part 37 Component CAS # Weight % CERCLA RQ Diethanolamine, DEA 111-42-2 < 1 100 SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |All components of this product conform to the |US TSCA 15.2 US State Regulations <COMPONENT> California Proposition 65: Tins product does not contain chemicals known to the state of California to cause cancer, birth defects or reproductive harm. The components of this product may be included on the various state hazardous materials lists noted below. California Hazardous Substances List Delaware An Quality Management List Idaho Air Pollutants List Illinois Toxic Air Contaminants List Maine Hazardous An Pollutants List Massachusetts Hazardous Substances List Michigan Critical Materials List Minnesota Hazardous Substances List New Jersey RTK Hazardous Substances List New Jersey TCPA Extremely Hazardous Substances List New York List of Hazardous Substances North Carolina Toxic Air Contaminants List Pennsylvania Hazardous Substances List Washington Permissible Exposure Air Contaminants List West Virginia Air Toxic Pollutants List Wisconsin Hazardous Air Contaminants List SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |1/29/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.