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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 5556-0 GAS FUEL ANTI-FREEZE CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Antifreeze. 1.3. Name, Address, and Telephone of the Responsible Party Company Imperial Supplies LLC 789 Armed Forces Drive P.O. Box 11008 Green Bay, WI 53407-1008 Phone: 1.4. Emergency Telephone Number Emergency | Chemtrec 1-800-424-9300, 1-800-558-2808 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Acute Toxicity|Category 3 - Oral | Acute Toxicity|Category 3 - Dermal | Acute toxicity|Category 3 - Inhalation | (Dusts/Mists) | Specific |Category 1 target organ | toxicity | (single | exposure) | Flammable |Category 2 Liquids | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Skull and Crossbones |Health Hazard |Flame Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Toxic if swallowed |Toxic in contact with skin |Toxic if inhaled |Causes damage to organs (Central Nervous System, |Eyes, Gastrointestinal Tract, Respiratory System, |and Skin.) |Highly flammable liquid and vapor Precautionary Statements |Prevention: (GHS-US) |Wash face, hands and any exposed skin thoroughly |after handling |Wear protective gloves/protective clothing/eye |protection/face protection |Do not eat, drink or smoke when using this product |Use only outdoors or in a well-ventilated area |Do not breathe dust/fume/gas/mist/vapors/spray |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Keep container tightly closed |Ground/Bond container and receiving equipment |Use explosion-proof electrial/ventilating/lighting |/equipment. |Use only non-sparking tools |Take precautionary measures against static discharge | |Response: |Specific treatment (see first aid on this label) |IF exposed: Call a POISON CENTER or doctor/physician | |IF ON SKIN (or hair): Remove/Take off immediately |all contaminated clothing. Rinse skin with |water/shower |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Rinse mouth |In case of fire: Use CO2, dry chemical, or foam for |extinction |Storage: |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Keep cool. |Disposal: |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Harmful to aquatic life with long lasting effects 0.02% of the mixture consists of ingredient(s) of unknown toxicity 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) METHANOL |67-56-1 |90-100 | | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Artificial respiration and/or oxygen may be necessary. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediate medical attention is required. First-aid Measures After Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. Call a physician or Poison Control Center immediately. May be fatal or cause blindness if swallowed. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes damage to target organs. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media: Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: No information available. Explosion Hazard: Sensitivity to Mechanical Impact: none. Sensitivity to Static Discharge: none. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Absorb with sand, clay, or other suitable material. Hard surfaces may be mopped with water. Remove all sources of ignition. Avoid contact with the skin and the eyes. Evacuate personnel to be safe areas.Keep people away from and upwind of spill/leak. Contents under pressure. Do not puncture or incinerate cands. Wear protective gloves/clothing and eye/face protection. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Should not be released into the environment. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Clean contaminated surface thoroughly. After cleaning, flush away traces with water. Prevent product from entering drains. Ground and bond containers when transferring material. Avoid dust formation. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Keep away from open flames, hot surfaces and sources of ignition. Do not breathe vapors or spray mist. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep in properly labeled containers. Keep out of the reach of children. Store locked up. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH METHANOL 67-56-1 STEL: 250 ppm TWA: 200 ppm Skin - potential significant contribution to overall exposure by the cutaneous route TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3 STEL: 250 ppm STEL: 325 mg/m3 Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Clear Odor |Solvent Odor Threshold |No information available pH |No information available Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |11 Â°C / 52 Â°F (based on components) Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |.796 Solubility |Practically insoluble Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%): 99.98 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Strong acids, alkalis, or oxidizing agents. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Unknown Acute Toxicity: 0.02% of the mixture consists of ingredient(s) of unknown toxicity Skin Corrosion/Irritation: Toxic in contact with skin. Avoid contact with skin. Serious Eye Damage/Irritation: Avoid contact with eyes. Respiratory or Skin Sensitization: Inhalation: Avoid breathing vapors or mists. Very toxic by inhalation. Sensitization: None known. Germ Cell Mutagenicity: None known. Carcinogenicity: There are no known carcinogenic chemicals in this product. Reproductive Toxicity: This product does not contain any known or suspected reproductive hazards. Specific Target Organ Toxicity (Single Exposure): Causes damage to Target Organs listed below. Specific Target Organ Toxicity (Repeated Exposure): None under normal use conditions. Aspiration Hazard: Not applicable Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates METHANOL 67-56-1 28200 mg/L LC50 Pimephales promelas 96h flow-through 100 mg/L LC50 Pimephales promelas 96h static 19500 - 20700 mg/L LC50 Oncorhynchus mykiss 96h flow-through 18 - 20 mL/L LC50 Oncorhynchus mykiss 96h static 13500 - 17600 mg/L LC50 Lepomis macrochirus 96h flow-through 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. Chemical Name log Pow METHANOL 67-56-1 -0.77 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D |or |LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |METHANOL Hazard Class |3 (6.1) Identification Number|UN1230 Label Codes |PG II |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |METHANOL Identification Number|UN1230 |<PICTOGRAM PHRASE> Hazard Class |3 (6.1) | Label Codes |PG II | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes |Acute Health Hazard |Yes |Chronic Health Hazard |Yes |Fire Hazard |Yes |Sudden Release of Pressure Hazard |no |Reactive Hazard |no Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name California Prop. 65 METHANOL - 67-56-1 developmental SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |08-Sep-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.