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SDS Sheet 0055410

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: 5541 COMPLETE FUEL TANK ADDTV                                     
 
CAS No:                                                                         
 
Synonyms:  None                                                                 
 


1.2.  Intended Use of the Product
Use of the substance/mixture:  Fuel additive.                                   
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Imperial Supplies LLC                                                           
 
789 Armed Forces Drive                                                          
 
P.O. Box 11008                                                                  
 
Green Bay, WI 53407-1038                                                        
 
Phone                                                                           
 


1.4.  Emergency Telephone Number
Emergency     | Chemtrec 1-800-424-9300                                         
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Category 2    
corrosion/irri|              
tation        |              
Serious eye   |Category 2B   
damage/eye    |              
irritation    |              
Carcinogenicit|Category 2    
y             |              
Aspiration    |Category 1    
toxicity      |              
Flammable     |Category 3    
Liquids       |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamation Mark |Health Hazard |Flame
        
Signal Word (GHS-US)         |DANGER                                            
 
Hazard Statements (GHS-US)   |Causes skin irritation                            
 
                             |Causes eye irritation                             
 
                             |Suspected of causing cancer                       
 
                             |May be fatal if swallowed and enters airways      
 
                             |Flammable liquid and vapor                        
 
Precautionary Statements     |Prevention:                                       
 
(GHS-US)                     |Obtain special instructions before use            
 
                             |Do not handle until all safety precautions have
been
                             |read and understood                               
 
                             |Wear protective gloves/protective clothing/eye    
 
                             |protection/face protection                        
 
                             |Wash face, hands and any exposed skin thoroughly  
 
                             |after handling                                    
 
                             |Keep away from heat/sparks/open flames/hot
surfaces.
                             |- No smoking                                      
 
                             |Keep container tightly closed                     
 
                             |Ground/Bond container and receiving equipment     
 
                             |Use explosion-proof electrial/ventilating/lighting
 
                             |/equipment.                                       
 
                             |Use only non-sparking tools                       
 
                             |Take precautionary measures against static
discharge
                             |                                                  
 
                             |Response:                                         
 
                             |If exposed or concerned: Get medical              
 
                             |advice/attention                                  
 
                             |Specific treatment (see first aid on this label)  
 
                             |IF IN EYES: Rinse cautiously with water for
several 
                             |minutes. Remove contact lenses, if present and
easy 
                             |to do. Continue rinsing.                          
 
                             |If eye irritation persists: Get medical           
 
                             |advice/attention                                  
 
                             |IF ON SKIN (or hair): Remove/Take off immediately 
 
                             |all contaminated clothing. Rinse skin with        
 
                             |water/shower                                      
 
                             |Wash contaminated clothing before reuse           
 
                             |If skin irritation occurs: Get medical            
 
                             |advice/attention                                  
 
                             |IF SWALLOWED: Immediately call a POISON CENTER or 
 
                             |doctor/physician                                  
 
                             |Do NOT induce vomiting                            
 
                             |In case of fire: Use CO2, dry chemical, or foam
for 
                             |extinction                                        
 
                             |Storage:                                          
 
                             |Store locked up                                   
 
                             |Store in a well-ventilated place. Keep cool       
 
                             |Disposal:                                         
 
                             |Dispose of contents/container to an approved waste
 
                             |disposal plant                                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Toxic to aquatic life with
 
long lasting effects.                                                           
 


2.4.  Unknown Acute Toxicity (GHS-US)
1.7808% of the mixture consists of ingredient(s) of unknown toxicity            
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%*      |Classification  
 
                                |                     |        |(GHS-US)        
 
KEROSENE                        |8008-20-6            |90-100  |                
 
AROMATIC HYDROCARBON            |64742-95-6           |1-10    |                
 
NAPHTHALENE                     |91-20-3              |0.1-1   |                
 
                                |                     |        |                
 
*The exact percentage           |                     |        |                
 
(concentration) of composition  |                     |        |                
 
has been withheld as a trade    |                     |        |                
 
secret.                         |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Move to fresh air. If breathing is
difficult,
give oxygen. Artificial respiration and/or oxygen                               
 
may be necessary. If breathing has stopped, contact emergency medical services  
 
immediately.                                                                    
 
First-aid Measures After Skin Contact: Wash off immediately with soap and plenty
 
of water while removing all contaminated                                        
 
clothes and shoes. If skin irritation persists, call a physician.               
 
First-aid Measures After Eye Contact: Rinse immediately with plenty of water,
also
under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If
 
symptoms persist, call a physician.                                             
 
First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never  
 
give anything by mouth to an unconscious                                        
 
person. Drink plenty of water. Call a physician or Poison Control Center        
 
immediately.                                                                    
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: May cause skin and eye irritation. Harmful if inhaled.       
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Notes to physician:       Treat symptomatically.                                
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Water fog.Dry chemical. Carbon dioxide (CO2). Cool
 
containers/tanks with water spray. Cool containers / tanks with water spray.    
 
Unsuitable Extinguishing Media: Decomposition by contact with water may generate
 
vapors which can be ignited by heat or                                          
 
open flame.                                                                     
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:                                                                    
 
Explosion Hazard: Sensitivity to Mechanical Impact none.                        
 
Sensitivity to Static Discharge none.                                           
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire: As in any fire, wear self-contained breathing      
 
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective
gear.                                                                           
 
Firefighting Instructions:                                                      
 
Protection During Firefighting:                                                 
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Evacuate personnel to safe areas. Absorb with sand ,clay, or  
 
other suitable material. Hard surfaces may be mopped with water. Avoid contact  
 
with skin, eyes and clothing. Ensure adequate ventilation. Avoid dust formation.
 
Remove all sources of ignition. Keep people away from and upwind of spill/leak. 
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Prevent further leakage or spillage if safe to do so. Do not allow material to  
 
contaminate ground water system. Prevent product from entering drains. Do not   
 
flush into surface water or sanitary sewer system.                              
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Prevent further leakage or spillage if safe to do so. Absorb or
 
cover with dry earth, sand or other non-combustible material and transfer to    
 
containers.                                                                     
 
Methods for Cleaning Up: Pick up and transfer to properly labeled containers.
Soak
up with inert absorbent material. Clean contaminated surface thoroughly. After  
 
cleaning, flush away traces with water. Take precautionary measures against
static
discharges. Ground and bond containers when transferring material. Prevent
product
from entering drains.                                                           
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid contact with skin, eyes and clothing.  
 
Handle in accordance with good industrial                                       
 
hygiene and safety practice. Remove and wash contaminated clothing before
re-use. 
Hygiene Measures:  Handle in accordance with good industrial hygiene and safety 
 
practice.                                                                       
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Keep container tightly closed in a dry and well-ventilated  
 
place. Keep away from open flames, hot surfaces and sources of ignition. Keep in
 
properly labeled containers. Keep out of the reach of children. Store locked up.
 


7.3.  Specific End Use(s)
Incompatible products: Strong acids, alkalis, or oxidizing agents.              
 
Aerosol Level: 3                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Chemical Name                                                                   
 
ACGIH TLV                                                                       
 
OSHA PEL                                                                        
 
NIOSH IDLH                                                                      
 
                                                                                
 
KEROSENE                                                                        
 
8008-20-6                                                                       
 
TWA: 200 mg/m3 total                                                            
 
hydrocarbon vapor application                                                   
 
restricted to conditions in which                                               
 
there are negligible aerosol                                                    
 
exposures                                                                       
 
Skin - potential significant                                                    
 
contribution to overall exposure                                                
 
by the cutaneous route                                                          
 
-                                                                               
 
TWA: 100 mg/m3                                                                  
 
                                                                                
 
NAPHTHALENE                                                                     
 
91-20-3                                                                         
 
TWA: 10 ppm                                                                     
 
Skin - potential significant                                                    
 
contribution to overall exposure                                                
 
by the cutaneous route                                                          
 
TWA: 10 ppm                                                                     
 
TWA: 50 mg/m3                                                                   
 
(vacated) TWA: 10 ppm                                                           
 
(vacated) TWA: 50 mg/m3                                                         
 
(vacated) STEL: 15 ppm                                                          
 
(vacated) STEL: 75 mg/m3                                                        
 
IDLH: 250 ppm                                                                   
 
TWA: 10 ppm                                                                     
 
TWA: 50 mg/m3                                                                   
 
STEL: 15 ppm                                                                    
 
STEL: 75 mg/m3                                                                  
 
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Showers                                           
 
Controls                     |Eyewash stations                                  
 
                             |Ventilation systems.                              
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Safety glasses with side-shields.                 
 
Skin and Body Protection     |Chemical resistant apron. Protective gloves.      
 
Respiratory Protection       |If exposure limits are exceeded or irritation is  
 
                             |experienced, NIOSH/MSHA approved respiratory      
 
                             |protection should be worn. Positive-pressure      
 
                             |supplied air respirators may be required for high 
 
                             |airborne contaminant concentrations. Respiratory  
 
                             |protection must be provided in accordance with    
 
                             |current local regulations.                        
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
 
Appearance                          |Opaque                                     
 
Odor                                |Solvent                                    
 
Odor Threshold                      |No information available                   
 
pH                                  |No information available                   
 
Relative Evaporation Rate           |No information available                   
 
(butylacetate=1)                    |                                           
 
Melting Point                       |                                           
 
Freezing Point                      |                                           
 
Boiling Point                       |No information available                   
 
Flash Point                         |42.2 °C / 108 °F Based on propellant       
 
Auto-ignition Temperature           |No information available                   
 
Decomposition Temperature           |No information available                   
 
Flammability (solid, gas)           |No information available                   
 
Vapor Pressure                      |                                           
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |                                           
 
Specific Gravity                    |.901                                       
 
Solubility                          |                                           
 
Partition coefficient:              |                                           
 
n-octanol/water                     |                                           
 
Viscosity                           |No information available                   
 
Lower Flammable Limit               |No information available                   
 
Upper Flammable Limit               |No information available                   
 


9.2.  Other Information
VOC Content(%) 98.22                                                            
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No data available                                                               
 


10.2      Chemical Stability
Stable under recommended storage conditions.                                    
 


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   
 


10.4      Conditions to Avoid
Extremes of temperature and direct sunlight.                                    
 


10.5      Incompatible Materials
Strong acids, alkalis, or oxidizing agents.                                     
 


10.6      Hazardous Decomposition Products
None known based on information supplied.                                       
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity: Numerical measures of toxicity - Product Information            
 
Unknown Acute Toxicity 1.7808% of the mixture consists of ingredient(s) of
unknown
toxicity                                                                        
 
The following values are calculated based on chapter 3.1 of the GHS document .  
 
ATEmix (dermal) 170238 mg/kg                                                    
 
Skin Corrosion/Irritation: May cause skin irritation.                           
 
Serious Eye Damage/Irritation: Irritating to eyes. Avoid contact with eyes.     
 
Respiratory or Skin Sensitization: Avoid breathing vapors or mists.             
 
Germ Cell Mutagenicity:                                                         
 
Carcinogenicity:                                                                
 
Reproductive Toxicity: This product does not contain any known or suspected     
 
reproductive hazards.                                                           
 
Specific Target Organ Toxicity (Single Exposure): None under normal use         
 
conditions.  Central nervous system, Eyes, Respiratory system, Skin.            
 
Specific Target Organ Toxicity (Repeated Exposure): None under normal use       
 
conditions                                                                      
 
Aspiration Hazard: May be fatal if swallowed and enters airways.                
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact: Irritating to skin. Repeated exposure may 
 
cause skin dryness or cracking. Prolonged skin                                  
 
contact may defat the skin and produce dermatitis. Avoid contact with skin.     
 
Symptoms/Injuries After Eye Contact: May cause eye irritation.                  
 
Symptoms/Injuries After Ingestion: May be harmful or fatal if swallowed.        
 
Aspiration into the lungs during swallowing may                                 
 
cause serious lung damage which may be fatal.                                   
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Chemical Name                                                                   
 
Toxicity to algae                                                               
 
Toxicity to fish                                                                
 
Toxicity to                                                                     
 
Microorganisms                                                                  
 
Toxicity to daphnia and                                                         
 
other aquatic invertebrates                                                     
 
                                                                                
 
AROMATIC                                                                        
 
HYDROCARBON                                                                     
 
64742-95-6                                                                      
 
-                                                                               
 
9.22 mg/L LC50                                                                  
 
Oncorhynchus mykiss 96h                                                         
 
-                                                                               
 
6.14 mg/L EC50 Daphnia                                                          
 
magna 48h                                                                       
 
                                                                                
 
NAPHTHALENE                                                                     
 
91-20-3                                                                         
 
-                                                                               
 
0.91 - 2.82 mg/L LC50                                                           
 
Oncorhynchus mykiss 96h                                                         
 
static 5.74 - 6.44 mg/L LC50                                                    
 
Pimephales promelas 96h                                                         
 
flow-through 1.6 mg/L LC50                                                      
 
Oncorhynchus mykiss 96h                                                         
 
flow-through 1.99 mg/L LC50                                                     
 
Pimephales promelas 96h                                                         
 
static 31.0265 mg/L LC50                                                        
 
Lepomis macrochirus 96h                                                         
 
Static                                                                          
 
-                                                                               
 
1.09 - 3.4 mg/L EC50                                                            
 
Daphnia magna 48h Static                                                        
 
1.96 mg/L EC50 Daphnia                                                          
 
magna 48h Flow through                                                          
 
2.16 mg/L LC50 Daphnia                                                          
 
magna 48h                                                                       
 
                                                                                
 


12.2. Persistence and Degradability
No information available.                                                       
 


12.3. Bioaccumulative Potential
No information available.                                                       
 
Chemical Name                                  log Pow                          
 
NAPHTHALENE                                         3.3                         
 
91-20-3                                                                         
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
No information available                                                        
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: This material, as supplied, is a hazardous waste
 
according to federal regulations (40 CFR                                        
 
261).                                                                           
 
Additional Information: Contaminated packaging: Do not re-use empty containers. 
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |NOT REGULATED FOR SHIPMENT                                
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |KEROSENE SOLUTION                                         
 
Hazard Class         |3                                                         
 
Identification Number|UN1223                                                    
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |KEROSENE SOLUTION                                         
 
Identification Number|UN1223,                |<PICTOGRAM PHRASE>                
  
Hazard Class         |3                      |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA 313: Section 313 of Title III of the Superfund Amendments and              
 
Re-authorization Act of 1986 (SARA). This product contains a chemical or
chemicals
which are subject to the reporting requirements of the Act and Title 40 of the  
 
Code of Federal Regulations, Part 372:                                          
 
Chemical Name                         CAS-No     Weight %*   SARA 313 -
Threshold 
Values %                                                                        
 
NAPHTHALENE - 91-20-3         91-20-3          0.1-1                 0.1        
 
                                                                                
 
Clean Water Act                                                                 
 
This product contains the following substances which are regulated pollutants   
 
pursuant to the Clean Water Act (40 CFR 122.21                                  
 
and 40 CFR 122.42):                                                             
 
Chemical Name                                                                   
 
CWA - Reportable                                                                
 
Quantities                                                                      
 
CWA - Toxic Pollutants                                                          
 
CWA - Priority Pollutants                                                       
 
CWA - Hazardous                                                                 
 
Substances                                                                      
 
                                                                                
 
NAPHTHALENE                                                                     
 
91-20-3                                                                         
 
100 lb                                                                          
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
CERCLA                                                                          
 
This material, as supplied, contains one or more substances regulated as a      
 
hazardous substance under the Comprehensive                                     
 
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):    
 
Chemical Name                                                                   
 
Hazardous Substances RQs                                                        
 
Extremely Hazardous Substances RQs                                              
 
RQ                                                                              
 
                                                                                
 
NAPHTHALENE                                                                     
 
91-20-3                                                                         
 
100 lb 1 lb                                                                     
 
                                                                                
 
RQ 100 lb final RQ                                                              
 
RQ 45.4 kg final RQ RQ 1 lb final                                               
 
RQ                                                                              
 
RQ 0.454 kg final RQ                                                            
 
                                                                                
 
SARA Section 311/312 Hazard Classes |Acute Health Hazard: Yes                   
 
                                    |Chronic Health Hazard: Yes                 
 
                                    |Fire Hazard: Yes                           
 
                                    |Sudden Release of Pressure Hazard: no      
 
                                    |Reactive Hazard: no                        
 
Toxic Substances Control Act (TSCA) |   Chemical Name     TSCA                  
 
                                    |KEROSENE                    X              
 
                                    |AROMATIC                 x                 
 
                                    |HYDROCARBON                                
 
                                    |NAPHTHALENE         X                      
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Proposition 65                                                       
 
This product contains the following Proposition 65 chemicals                    
 
Chemical Name                                 California Prop. 65               
 
NAPHTHALENE - 91-20-3                      X                                    
 
U.S. State Right-to-Know Regulations                                            
 
Chemical Name                                                                   
 
New Jersey                                                                      
 
Massachusetts                                                                   
 
Pennsylvania                                                                    
 
                                                                                
 
KEROSENE                                                                        
 
8008-20-6                                                                       
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
NAPHTHALENE                                                                     
 
91-20-3                                                                         
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
EPA Pesticide Registration Number Not applicable                                
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |19-May-2015                                                    
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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