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Safety Data Sheet Date of Issue: 19-May-2015 |Revision Date: 19-May-2015 |Revision Number: 1 Imperial Supplies Part Number: 0055360 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 5536 DIESEL TNK ADDTV ANTI-GEL CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Diesel Fuel Additive. 1.3. Name, Address, and Telephone of the Responsible Party Company: Imperial Supplies LLC 789 Armed Forces Drive P.O. Box 11008 Green Bay, WI 53407-1038 Phone: 1.4. Emergency Telephone Number Emergency | 1-800-424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2A damage/eye | irritation | Carcinogenicit|Category 2 y | Specific |Category 3 target organ | toxicity | (single | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 3 Liquids | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat|Health |Flame | | | |ion Mark|Hazard | | | | Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Causes skin irritation |Causes serious eye irritation |Suspected of causing cancer |May cause respiratory irritation. May cause |drowsiness or dizziness |May be fatal if swallowed and enters airways |Flammable liquid and vapor Precautionary Statements |Prevention (GHS-US) |Obtain special instructions before use |Do not handle until all safety precautions have been |read and understood |Wear protective gloves/protective clothing/eye |protection/face protection |Wash face, hands and any exposed skin thoroughly |after handling |Avoid breathing dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Keep container tightly closed |Ground/Bond container and receiving equipment |Use explosion-proof electrial/ventilating/lighting |/equipment. |Use only non-sparking tools |Take precautionary measures against static discharge | | |Response |If exposed or concerned: Get medical |advice/attention |Specific treatment (see first aid on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention |IF ON SKIN (or hair): Remove/Take off immediately |all contaminated clothing. Rinse skin with |water/shower |Wash contaminated clothing before reuse |If skin irritation occurs: Get medical |advice/attention |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |In case of fire: Use CO2, dry chemical, or foam for |extinction | |Storage |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Keep cool. | |Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |%* |Classification | | |(GHS-US) KEROSENE |8008-20-6 |50-60 | 2-ETHYLHEXYL NITRATE |27247-96-7 |10-20 | AROMATIC HYDROCARBON |64742-95-6 |1-10 | 2-BUTOXYETHANOL |111-76-2 |1-10 | 1,2,4-TRIMETHYL BENZENE |95-63-6 |1-10 | SOLVENT NAPHTHA |64742-94-5 |1-10 | NAPHTHALENE |91-20-3 |1-10 | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Avoid contact with eyes,skin, and clothing.Avoid breathing, vapors,mist,or gas. First-aid Measures After Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Get medical attention immediately if symptoms occur. First-aid Measures After Eye Contact: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek immediate medical attention/advice. First-aid Measures After Ingestion: Do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. Risk of product entering the lungs on vomiting after ingestion. Absorb with sand ,clay, or other suitable material. Hard surfaces may be mopped with water. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Inhalation causing Central Nervous System effects. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes eye irritation. Symptoms/Injuries After Ingestion: Ingestion causing lung damage. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use:. Dry chemical. Carbon dioxide (CO 2). Water spray. Alcohol-resistant foam. Unsuitable Extinguishing Media: Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Keep product and empty container away from heat and sources of ignition. Risk of ignition. Explosion Hazard: Sensitivity to Mechanical Impact: none. Sensitivity to Static Discharge: Yes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Pay attention to flashback. Take precautionary measures against static discharges. Absorb with sand ,clay, or other suitable material. Hard surfaces may be mopped with water. Emergency Procedures: 6.2. Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Take precautionary measures against static discharges. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Use only in area provided with appropriate exhaust ventilation. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away from heat, sparks and open flame. No smoking. Wear personal protective equipment. Do not breathe vapors or spray mist. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Hygiene Measures: When using, do not eat, drink or smoke. Provide regular cleaning of equipment, work area and clothing. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Keep in properly labeled containers. Storage Conditions: Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Keep in properly labeled containers. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH KEROSENE 8008-20-6 TWA: 200 mg/m3 total hydrocarbon vapor application restricted to conditions in which there are negligible aerosol exposures Skin - potential significant contribution to overall exposure by the cutaneous route - TWA: 100 mg/m3 2-BUTOXYETHANOL 111-76-2 TWA: 20 ppm TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3 1,2,4-TRIMETHYL BENZENE 95-63-6 - - TWA: 25 ppm TWA: 125 mg/m3 NAPHTHALENE 91-20-3 TWA: 10 ppm Skin - potential significant contribution to overall exposure by the cutaneous route TWA: 10 ppm TWA: 50 mg/m3 (vacated) TWA: 10 ppm (vacated) TWA: 50 mg/m3 (vacated) STEL: 15 ppm (vacated) STEL: 75 mg/m3 IDLH: 250 ppm TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Tightly fitting safety goggles. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Hazy Odor |Solvent Odor Threshold |No information available pH |No information available Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |42 �C / 108 �F Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 �C |No information available Relative Density | Specific Gravity |0.84 Solubility |Practically insoluble Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%): 86.59 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials None known based on information supplied. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Irritating to skin. Serious Eye Damage/Irritation: Irritating to eyes. Respiratory or Skin Sensitization: Irritating to respiratory system. Germ Cell Mutagenicity: None known. Carcinogenicity: The table below indicates whether each agency has evaluated a listed ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA 2-ETHYLHEXYL NITRATE 27247-96-7 - Group 2A - X 2-BUTOXYETHANOL 111-76-2 A3 Group 3 - - NAPHTHALENE 91-20-3 A3 Group 2B Reasonably Anticipated - Reproductive Toxicity: This product does not contain any known or suspected reproductive hazards. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): None under normal use conditions. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Vapors may irritate throat and respiratory system. May cause drownsiness and dizziness based on components. May cause irritation of respiratory tract. Avoid breathing vapors or mists. Symptoms/Injuries After Skin Contact: Irritating to skin. Repeated exposure may cause skin dryness or cracking. Prolonged skin contact may defat the skin and produce dermatitis. Avoid contact with skin. Symptoms/Injuries After Eye Contact: Irritation to eyes. Symptoms/Injuries After Ingestion: May be harmful or fatal if swallowed. Chronic Symptoms: Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac arrest. Prolonged skin contact may defat the skin and produce dermatitis. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates AROMATIC HYDROCARBON 64742-95-6 9.22 mg/L LC50 Oncorhynchus mykiss 96h 6.14 mg/L EC50 Daphnia magna 48h 2-BUTOXYETHANOL 111-76-2 1490 mg/L LC50 Lepomis macrochirus 96h static 2950 mg/L LC50 Lepomis macrochirus 96h 1000 mg/L EC50 Daphnia magna 48h 1,2,4-TRIMETHYL BENZENE 95-63-6 7.19 - 8.28 mg/L LC50 Pimephales promelas 96h flow-through 6.14 mg/L EC50 Daphnia magna 48h SOLVENT NAPHTHA 64742-94-5 1740 mg/L LC50 Lepomis macrochirus 96h static 19 mg/L LC50 Pimephales promelas 96h static 2.34 mg/L LC50 Oncorhynchus mykiss 96h 41 mg/L LC50 Pimephales promelas 96h 45 mg/L LC50 Pimephales promelas 96h flow-through 0.95 mg/L EC50 Daphnia magna 48h NAPHTHALENE 91-20-3 0.91 - 2.82 mg/L LC50 Oncorhynchus mykiss 96h static 5.74 - 6.44 mg/L LC50 Pimephales promelas 96h flow-through 1.6 mg/L LC50 Oncorhynchus mykiss 96h flow-through 1.99 mg/L LC50 Pimephales promelas 96h static 31.0265 mg/L LC50 Lepomis macrochirus 96h Static 1.09 - 3.4 mg/L EC50 Daphnia magna 48h Static 1.96 mg/L EC50 Daphnia magna 48h Flow through 2.16 mg/L LC50 Daphnia magna 48h 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste Disposal Methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging: Do not re-use empty containers. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |PETROLEUM DISTILLATES, N.O.S. Hazard Class |3 Identification Number|UN1268 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |PETROLEUM DISTILLATES N.O.S. Identification Number|UN1268 |<PICTOGRAM PHRASE> Hazard Class | 3 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight %* SARA 313 - Threshold Values % 2-BUTOXYETHANOL - 111-76-2 111-76-2 1-10 1.0 1,2,4-TRIMETHYL BENZENE - 95-63-6 95-63-6 1-10 1.0 NAPHTHALENE - 91-20-3 91-20-3 1-10 0.1 SARA Section 311/312 Hazard Classes |Acute Health Hazard |Yes |Chronic Health Hazard |Yes |Fire Hazard |Yes |Sudden Release of Pressure Hazard no |Reactive Hazard |no Toxic Substances Control Act (TSCA) |United States Toxic Substances Control Act |Section 8(b) Inventory 15.2 US State Regulations <COMPONENT> California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name California Prop. 65 NAPHTHALENE - 91-20-3 X U.S. State Right-to-Know Regulations This product does not contain any substances regulated by state right-to-know regulations Chemical Name New Jersey Massachusetts Pennsylvania KEROSENE 8008-20-6 X X X 2-ETHYLHEXYL NITRATE 27247-96-7 X X X 2-BUTOXYETHANOL 111-76-2 X X X 1,2,4-TRIMETHYL BENZENE 95-63-6 X X X NAPHTHALENE 91-20-3 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |19-May-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.