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MSDS Sheet 0052752Printer Friendly View
Material Safety Data Sheet Date of Issue: |Revision Date: March 2015 |Revision Number: Imperial Supplies Part Number: 0052752 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Energizer Battery CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Energizer Battery Manufacturing, Inc. 25225 Detroit Rd. Westlake, OH 44145 Phone: 800-383-7323 1.4. Emergency Telephone Number Emergency | number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) N/A | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) |N/A Hazard Statements (GHS-US) | Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Carbon Black |1333-86-4 |0-1 | 1,2-Dimethoxyethane |110-71-4 |0-6 | 1,3-Dioxolane |646-06-0 |0-8 | Graphite |7782-42-5 |0-3 | Lithium or Lithium Alloy |7439-93-2 |1-6 | Lithium |33454-82-9 |0-3 | Trifluoromethanesulfonate | | | Lithium |90076-65-6 |0-3 | Trifluoromethanesulfonimide | | | Manganese Dioxide |1313-13-9 |12-42 | Propylene Carbonate |108-32-7 |0-8 | Non-Hazardous Components: | | | Steel (iron) |65997-19-5 |20 | Plastic and Other | |Balance | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the chemical remains. Seek medical attention. First-aid Measures After Skin Contact: Remove contaminated clothing and wash skin with soap and water. First-aid Measures After Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the chemical remains. Seek medical attention. First-aid Measures After Ingestion: Do not induce vomiting or give food or drink. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: In case of fire where lithium batteries are present, flood area with water or smother with a Class D fire extinguishant appropriate for lithium metal, such as Lith-X. Water may not extinguish burning batteries but will cool the adjacent batteries and control the spread of fire. Burning batteries will burn themselves out. Virtually all fires involving lithium batteries can be controlled by flooding with water. However, the contents of the battery will react with water and form hydrogen gas. In a confined space, hydrogen gas can form an explosive mixture. In this situation, smothering agents are recommended. A smothering agent will extinguish burning lithium batteries. Emergency Responders should wear self-contained breathing apparatus. Burning lithium manganese dioxide batteries produce toxic and corrosive lithium hydroxide fumes. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Mechanical Containment: If potting or sealing the battery in an airtight or watertight container is required, consult your Energizer Battery Manufacturing, Inc. representative for precautionary suggestions. Do not obstruct safety release vents on batteries. Encapsulation of batteries will not allow cell venting and can cause high pressure rupture. Methods for Cleaning Up: To cleanup leaking batteries: Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries. Respiratory Protection: Avoid exposure to electrolyte fumes from open or leaking batteries. Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery. Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery. Battery materials should be collected in a leak-proof container. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit will cause the battery to lose energy, generate significant heat and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into devices. Damaging a lithium battery may result in an internal short circuit. The contents of an open battery, including a vented battery, when exposed to water, may result in a fire and/or explosion. Crushed or damaged batteries may result in a fire. If soldering or welding to the battery is required, consult your Energizer representative for proper precautions to prevent seal damage or short circuit. Charging: This battery is manufactured in a charged state. It is not designed for recharging. Recharging can cause battery leakage or, in some cases, high pressure rupture. Inadvertent charging can occur if a battery is installed backwards. Labeling: If the Energizer label or package warnings are not visible, it is important to provide a package and/or device label stating: WARNING: Battery can explode or leak and cause burns if installed backwards, disassembled, charged, or exposed to water, fire or high temperature. Where accidental ingestion of small batteries is possible, the label should include: Warning. (1) KEEP OUT OF REACH OF CHILDREN. Swallowing may lead to serious injury or death in as little as 2 hours due to chemical burns and potential perforation of the esophagus. Immediately see doctor; have doctor phone (202) 625-3333. Keep in original package until ready to use. Dispose of used batteries immediately. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life. In locations that handle large quantities of lithium batteries, such as warehouses, lithium batteries should be isolated from unnecessary combustibles. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective |Gloves: Not necessary under normal conditions. Clothing | Hand Protection | Eye Protection |Not necessary under normal conditions. Skin and Body Protection | Respiratory Protection |Not necessary under normal conditions. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid Appearance |Solid object Odor |No odor Odor Threshold |No odor pH |Not applicable for an Article. Relative Evaporation Rate |Not applicable for an Article. (butylacetate=1) | Melting Point |Not applicable for an Article. Freezing Point |Not applicable for an Article. Boiling Point |Not applicable for an Article. Flash Point |Not applicable for an Article. Auto-ignition Temperature |Not applicable for an Article. Decomposition Temperature |Not applicable for an Article. Flammability (solid, gas) |Not applicable for an Article. Vapor Pressure |Not applicable for an Article. Relative Vapor Density at 20 Â°C |Not applicable for an Article. Relative Density | Specific Gravity | Solubility |Not applicable for an Article. Partition coefficient: |Not applicable for an Article. n-octanol/water | Viscosity |Not applicable for an Article. Lower Flammable Limit |Not applicable for an Article. Upper Flammable Limit |Not applicable for an Article. 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Lithium manganese dioxide batteries contain no sulfides or cyanides and they do not meet any other reactivity criteria including "reacts violently with water" and therefore do not meet any of the criteria established in 40 CFR 261.2 for reactivity. 10.2 Chemical Stability 10.3 Possibility of Hazardous Reactions 10.4 Conditions to Avoid 10.5 Incompatible Materials 10.6 Hazardous Decomposition Products SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Under normal conditions of use, lithium manganese dioxide batteries are non-toxic. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Issues such as ecotoxicity, persistence and bioaccumulation are not applicable for articles. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Lithium iron disulfide batteries are not hazardous waste per the United States Resource Conservation and Recovery Act (RCRA) - 40 CFR Part 261 Subpart C. Dispose of in accordance with all applicable federal, state and local regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Outside of the transportation requirements noted in Section 14, lithium manganese dioxide batteries marketed by Energizer Battery Manufacturing, Inc. are not regulated. SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and Community Right-To-Know Act. SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.