Request Account    |    Login

National Distributor of Quality Maintenance Supplies Since 1958

1-800-558-2808

Track Order Status
Order No:
Zip Code:

MSDS Sheet 0052670

Printer Friendly View
        

Material Safety Data Sheet                                                
Date of issue:      |Revision Date: March 28, 2013|Revision Number:       
Imperial Supplies Part Number: 0052560.0052710.0052720.0052760.0054800    
1. PRODUCT AND COMPANY IDENTIFICATION                                     
Manufacturer: Duracell, a P&G brand                                       
EUROPEAN OFFICE                                                           
Berkshire Corporate Park                                                  
Procter& Gamble                                                           
Bethel, CT 06801 USA                                                      
Switzerland SARL                                                          
Telephone: 203-796-4000                                                   
Route de Saint-Georges 47                                                 
1213 Petit-Lancy, 1, Geneva,                                              
Telephone: +41-58-004-6111                                                
Emergency  Phone                                                          
                                                                          
                                                                          
Product Name: DURACELL LITHIUM MANGANESE DIOXIDE COIN CELLS               
Product Code(s):  The gram weight of lithium metal in Duracell lithium    
metal cells & batteries is:                                               
Catalog Number                                                            
Total Lithium Content                                                     
Description                                                               
                                                                          
DL 1616                                                                   
.02 g                                                                     
Coin Cell                                                                 
                                                                          
DL 1620                                                                   
.02 g                                                                     
Coin Cell                                                                 
                                                                          
DL 2016                                                                   
.02 g                                                                     
Coin Cell                                                                 
                                                                          
DL 2025                                                                   
.07g                                                                      
Coin Cell                                                                 
                                                                          
DL 2032                                                                   
.07 g                                                                     
Coin Cell                                                                 
                                                                          
DL 2430                                                                   
.07 g                                                                     
Coin Cell                                                                 
                                                                          
DL 2450                                                                   
.15 g                                                                     
Coin Cell                                                                 
                                                                          
Recommended Use: Energy Source                                            
UN-Number: UN3090                                                         
Product Type:                                                             
                                                                          
2.  HAZARDS IDENTIFICATION                                                
                                                                          
These products are classified as Articles under REACH and are not subject 
to the requirements for Information in the Supply Chain (Safety Data      
Sheets and Labels). While batteries may release hazardous substances if   
damaged, this is not an intended release as defined under REACH. Batteries
are not classified as hazardous under the CLP. The following information  
is provided to assist in the safe use of our products.                    
CAUTION: Battery can explode or leak if heated, disassembled, shorted,    
recharged, exposed to fire or high temperature or inserted incorrectly.   
Keep in original package until ready to use. Do not carry batteries loose 
in your pocket or purse. Keep batteries away from children. If swallowed, 
consult a physician at once. Under certain misuse conditions and by       
abusively opening the battery, exposed lithium can react with water or    
moisture in the air causing potential thermal burns or fire.              
                                                                          
Appearance: Coin     |Physical State:          |Odor: Coin cells.         
cells.               |                         |                          
                                                                          
Potential Health Effects: The chemicals and metals in this product are    
contained in a sealed can. Exposure to the contents will not occur unless 
the battery leaks, is exposed to high temperatures or is mechanically,    
physically, or electrically abused.                                       
Principle Routes of Exposure                                              
                                                                          
Acute Effects:                                                            
Eyes                 |                                                    
Skin                 |                                                    
Inhalation           |                                                    
Ingestion            |                                                    
Notes:                                                                    
                                                                          
Chronic Effects:                                                          
Eyes                 |                                                    
Skin                 |                                                    
Inhalation           |                                                    
Ingestion            |                                                    
Notes:                                                                    
                                                                          
Aggravated Medical Conditions                                             
                                                                          
Environmental Hazard                                                      
                                                                          
3.  COMPOSITION/INFORMATION ON INGREDIENTS                                
                                                                          
Chemical/Ingredient Name |CAS-No     |Weight%   |ACGIH,    |OSHA-PE|Other 
                         |           |          |TLV-TWA   |L      |      
Manganese Dioxide        |1313-13-9  |15-75 %   |          |       |      
Propylene Carbonate      |108-32-7   |2-15 %    |          |       |      
Lithium                  |7439-93-2  |1-10 %    |          |       |      
Graphite, synthetic      |7440-44-0  |1-10 %    |          |       |      
1,2-Dimethoxyethane*     |110-71-4   |1-10 %    |          |       |      
Lithium Perchlorate      |7791-03-9  |<1.5 %    |          |       |      
                         |           |          |          |       |      
Notes: *SVHC Substance per Candidate List Updated June 18, 2012           
                                                                          
4.  FIRST AID MEASURES                                                    
                                                                          
General Advice: The chemicals and metals in this product are contained in 
a sealed can. Exposure to the contents will not occur unless the battery  
leaks, is exposed to high temperatures or is mechanically, physically, or 
electrically abused.                                                      
Eyes               |If battery is leaking and material contacts the eye, 
                   |flush thoroughly with copious amounts of running     
                   |water for 30 minutes. Seek immediate medical advice. 
Skin               |If battery is leaking and material contacts the skin,
                   |remove any contaminated clothing and flush exposed   
                   |skin with copious amounts of running water for at    
                   |least 15 minutes. If irritation, injury or pain      
                   |persists, seek medical advice.                       
Inhalation         |Inhaled: If battery is leaking, contents may be      
                   |irritating to respiratory passages. Move to fresh    
                   |air. If irritation persists, seek medical advice.    
Ingestion          |Swallowed: If battery is swallowed seek immediate    
                   |medical advice. Batteries lodged in the esophagus    
                   |should be removed immediately since leakage, caustic 
                   |burns and perforation can occur as soon as two hours 
                   |after ingestion. If mouth area irritation or burning 
                   |has occurred, rinse the mouth and surrounding area   
                   |with tepid water for at least 15 minutes. Do not give
                   |ipecac.                                              
Notes to Physician |Published reports recommend removal from the         
                   |esophagus be done endoscopically (under direct       
                   |visualization). Batteries beyond the esophagus need  
                   |not be retrieved unless there are signs of injury to 
                   |the GI tract or a large diameter battery fails to    
                   |pass the pylorus. If asymptomatic, follow-up x-rays  
                   |are necessary only to confirm the passage of larger  
                   |batteries. Confirmation by stool inspection is       
                   |preferable under most circumstances. Potential       
                   |leakage of less than 50 milligrams of dimethoxyethane
                   |and propylene carbonate. Dimethoxyethane rapidly     
                   |evaporates. Do not give ipecac.                      
Protection of      |                                                     
First-aiders       |                                                     
Notes              |                                                     
                                                                          
5.  FIRE-FIGHTING MEASURES                                                
                                                                          
Flammability/Flammable     |                                              
properties                 |                                              
Flash point                |                                              
Recommended Extinguishing  |Use any extinguishing media that is           
Media                      |appropriate for the surrounding fire.         
Special  Fire-Fighting     |Firefighters should wear positive pressure    
Procedures                 |self-contained breathing apparatus and full   
                           |protective clothing. Fight fire from a        
                           |distance or protected area. Cool fire exposed 
                           |batteries to prevent rupture. Use caution when
                           |handling fire-exposed containers (batteries   
                           |may explode in heat of fire).                 
                           |                                              
Explosion Data             |Batteries may burst and release hazardous     
                           |decomposition products when exposed to a fire 
                           |situation.                                    
                           |Hazardous Combustion Products: Thermal        
                           |degradation may produce hazardous fumes of    
                           |lithium and manganese;                        
                           |oxides of carbon and other toxic by-products. 
Sensitivity to Mechanical  |                                              
Impact                     |                                              
Sensitivity to Static      |                                              
Discharge                  |                                              
                           |                                              
Specific Hazards from      |                                              
Chemical                   |                                              
                           |                                              
Protective Equipment       |                                              
                                                                          
NFPA |Health Hazard: |Flammability:  |Instability:|Physical Hazard        
                                                                          
HMIS |Health Hazard: |Flammability:  |Physical      |PPE:                 
     |               |               |Hazard:       |                     
                                                                          
6.  ACCIDENTAL RELEASE MEASURES                                           
                                                                          
Personal Precautions                                                      
Environmental Precautions                                                 
Methods for Containment                                                   
Methods for Cleaning Up                                                   
Notes:  Notify safety personnel of large spills. Irritating vapors and    
flammable may be released from leaking or ruptured batteries. Eliminate   
all ignition sources. Evacuate the area and allow the vapors to dissipate.
Clean-up personnel should wear appropriate protective clothing to avoid   
eye and skin contact and inhalation of vapors or fumes. Increase          
ventilation. Carefully collect batteries and place in an appropriate      
container for disposal. Remove spilled liquid with absorbent and contain  
for disposal.                                                             
                                                                          
7.  HANDLING AND STORAGE                                                  
                                                                          
Handling: Avoid mechanical or electrical abuse. DO NOT short circuit or   
install incorrectly. Batteries may explode, pyrolize or vent if           
disassembled, crushed, recharged or exposed to high temperatures. Install 
batteries in accordance with equipment instructions. Replace all batteries
in equipment at the same time. Do not carry batteries loose in a pocket or
bag.                                                                      
Storage: Store batteries in a dry place at normal room temperature.       
                                                                          
8.  EXPOSURE CONTROLS/PERSONAL PROTECTION                                 
                                                                          
Exposure Guidelines: No exposure to the battery components should occur   
during normal use.                                                        
                                                                          
Chemical Name    |ACGIH TLV    |OSHA PEL      |NIOSH IDLH     |OTHER      
                 |             |              |               |           
                 |             |              |               |           
                 |             |              |               |           
                                                                          
Engineering Measures                                                      
                                                                          
Personal Protective Equipment                                             
Eyes/Face          |None required for normal use. Wear safety goggles    
Protection         |when handling leaking batteries.                     
Skin and Body      |None required for normal use. Use butyl rubber gloves
Protection         |when handling leaking batteries.                     
Respiratory        |None required for normal use.                        
Protection         |                                                     
Ventilation/Other  |No special ventilation is needed for normal use.     
Hygiene Measures                                                          
                                                                          
9.  PHYSICAL AND CHEMICAL PROPERTIES                                      
                                                                          
Appearance       |Coin cells.  |Odor                |                    
Odor Threshold   |             |Physical State      |                    
Color            |             |Viscosity           |                    
pH               |             |Percent  Volatile,  |                    
                 |             |wt. %               |                    
Flash Point      |29°F (-2°C)  |Auto-ignition       |                    
                 |(1,2-Dimethox|Temperature         |                    
                 |ye hane)     |                    |                    
Decomposition    |             |Boiling Point/ Range|                    
Temp             |             |                    |                    
Melting          |             |Freezing Point      |                    
Point/Range      |             |                    |                    
Flammability     |             |Explosion Limits    |                    
Specific Gravity |             |Water Solubility    |Insoluble           
Solubility       |             |Evaporation Rate    |                    
Vapor Pressure   |             |Vapor Density       |                    
VOC content, wt. |             |                    |                    
%                |             |                    |                    
                 |             |                    |                    
Notes                                                                     
                                                                          
10. STABILITY AND REACTIVITY                                              
                                                                          
Chemical Stability        |This product is stable.                        
Incompatible Products     |Contents are incompatible with strong oxidizing
                          |agents. Do not heat, crush, disassemble, short 
                          |circuit or recharge.                           
Conditions to avoid       |                                               
Hazardous Decomposition   |Thermal decomposition may produce hazardous    
Products                  |fumes of lithium and manganese; oxides of      
                          |carbon and other toxic by-products.            
Hazardous Polymerization  |Will not occur.                                
Notes                                                                     
                                                                          
11. TOXICOLOGY INFORMATION                                                
                                                                          
Acute Toxicity                                                            
                                                                          
Product          |                                                        
Information      |                                                        
Inhalation      |Inhalation of vapors or fumes released due to heat or a 
                |large number of leaking batteries may cause respiratory 
                |and eye irritation.                                     
Eye Contact     |Contact with battery contents may cause irritation.     
Skin Contact    |Contact with battery contents may cause irritation.     
Ingestion       |Seek immediate medical advice. Batteries lodged in the  
                |esophagus should be removed immediately since leakage,  
                |caustic burns and perforation can occur as soon as two  
                |hours after ingestion. Irritation to the                
                |internal/external mouth areas, may occur following      
                |exposure to a leaking battery.                          
                                                                          
Chemical Name   |LD50 Oral      |LD50 Dermal       |LC50 Inhalation      
                |               |                  |                     
                |               |                  |                     
                                                                          
Chronic Toxicity|                                                        
                                                                          
Chemical Name   |ACGIH            |IARC      |NTP          |OSHA          
                |                 |          |             |              
                |                 |          |             |              
                                                                          
Target Organ Effects                                                      
                                                                          
12.  ECOLOGICAL INFORMATION                                               
                                                                          
Ecotoxicity: No ecotoxicity data is available. This product is not        
expected to present an environmental hazard.                              
The Environmental impact of this product has been fully investigated      
                                                                          
Chemical Name|Toxicity to    |Toxicity to  |Tox, to       |Daphnia Magna   
             |Algea          |Fish         |Microorganisms|(water flea)    
             |               |             |              |                
             |               |             |              |                
             |               |             |              |                
                                                                          
Notes                                                                     
                                                                          
13.  DISPOSAL CONSIDERATIONS                                              
                                                                          
Waste Disposal Methods: Disposal should be in accordance with national and
local regulations. Do not incinerate for disposal except for in a         
controlled incinerator. Duracell manganese dioxide lithium coin cell      
batteries are labeled in compliance with the EU Battery Directive 2006/66.
                                                                          
Contaminated Packaging                                                    
                                                                          
US EPA Waste number                                                       
                                                                          
Notes                                                                     
                                                                          
                                                                          
14.  TRANSPORTATION INFORMATION                                           
                                                                          
DOT                                                                       
UN-Number           |UN3090                                               
                    |                                                     
                    |UN3091                                               
Proper Shipping name|Primary lithium metal batteries                      
                    |                                                     
                    |Primary lithium metal batteries packed with or       
                    |contained in equipment                               
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |DURACELL lithium metal batteries are produced and    
                    |delivered in accordance with US DOT Regulations.     
                    |DURACELL lithium metal cells and batteries are not   
                    |subject to the other provisions of the Dangerous     
                    |Goods regulations as long as they are packaged and   
                    |marked in accordance with the appropriate            
                    |regulations. All persons who prepare or offer lithium
                    |batteries for transport are required by regulation to
                    |be sufficiently trained                              
                    |and aware of all applicable regulations. Regulatory  
                    |guidance for safe packaging requires that batteries  
                    |be packaged in a manner that prevents short circuits,
                    |prevent battery movement within the package and that 
                    |prevents spillage of contents.                       
                    |                                                     
                    |Special Provision 49CFR-173.1859(c ) - SP A101       
                    |                                                     
                    |DURACELL certifies that all of its lithium batteries 
                    |meet the requirements of the UN Manual of Tests and  
                    |Criteria, Part III subsection 38.3 and the batteries 
                    |were.                                                
                    |                                                     
                    |Air travelers should consult the US Department of    
                    |Transportation (DOT) Safety Travel web site at       
                    |http://safetravel.dot.gov for guidance regarding     
                    |carry on of lithium batteries.                       
Emergency Response  |CHEMTREC 24-Hour Emergency Response Hotline          
Guide Number        |+703-527-3887 (United States of America)             
                                                                          
TDG                                                                       
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
MEX                 |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
ICAO                                                                      
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |DURACELL lithium metal batteries are produced and    
                    |delivered in accordance with IATA 56th ICAO, IMO and 
                    |US DOT Regulations. DURACELL lithium metal cells and 
                    |batteries are not subject to the other provisions of 
                    |the Dangerous Goods regulations as long as they are  
                    |packaged and marked in accordance with the           
                    |appropriate regulations.                             
                    |All persons who prepare or offer lithium batteries   
                    |for transport are required by regulation to be       
                    |sufficiently trained and aware of all applicable     
                    |regulations. Regulatory guidance for safe packaging  
                    |requires that batteries be packaged in a manner that 
                    |prevents short circuits, prevent battery movement    
                    |within the package and that prevents spillage of     
                    |contents.                                            
                    |                                                     
                    |Special Provisions A88, A99, A154, A164, A183, A201  
                    |PI 968 - Lithium metal batteries only                
                    |PI 969 - Lithium metal batteries packed with         
                    |equipment                                            
                    |PI 970 - Lithium metal batteries contained in        
                    |equipment                                            
                                                                          
IATA                                                                      
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
ERG Code            |                                                     
Description         |DURACELL lithium metal batteries are produced and    
                    |delivered in accordance with IATA 56th ICAO, IMO and 
                    |US DOT Regulations. DURACELL lithium metal cells and 
                    |batteries are not subject to the other provisions of 
                    |the Dangerous Goods regulations as long as they are  
                    |packaged and marked in accordance with the           
                    |appropriate regulations. All persons who prepare or  
                    |offer lithium batteries for transport are required by
                    |regulation to be sufficiently trained and aware of   
                    |all applicable regulations. Regulatory guidance for  
                    |safe packaging requires that batteries be packaged in
                    |a manner that prevents short circuits, prevent       
                    |battery movement within the package and that prevents
                    |spillage                                             
                    |of contents..                                        
                    |                                                     
                    |Special Provisions A88, A99, A154, A164, A183, A201  
                    |PI 968 - Lithium metal batteries only                
                    |PI 969 - Lithium metal batteries packed with         
                    |equipment                                            
                    |PI 970 - Lithium metal batteries contained in        
                    |equipment                                            
                                                                          
IMDG/IMO                                                                  
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
EmS No.             |                                                     
Description         |DURACELL lithium metal batteries are produced and    
                    |delivered in accordance with IATA 56th ICAO, IMO and 
                    |US DOT Regulations. DURACELL lithium metal cells and 
                    |batteries are not subject to the other provisions of 
                    |the Dangerous Goods regulations as long as they are  
                    |packaged and marked in accordance with the           
                    |appropriate Regulations. All persons who prepare or  
                    |offer lithium batteries for transport are required by
                    |regulation to be sufficiently trained and aware of   
                    |all applicable regulations. Regulatory guidance for  
                    |safe packaging requires that batteries be packaged in
                    |a manner that prevents short circuits, prevent       
                    |battery movement within the package and that prevents
                    |spillage of contents.                                
                    |                                                     
                    |Special Provision 188, 230, 310, 957                 
                                                                          
RID                                                                       
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |                                                     
ADR/RID-Labels     |                                                     
                                                                          
ADR                                                                       
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |Special Provisions: 188, 230, 310, 957               
ADR/RID-Labels     |                                                     
                                                                          
ADN                                                                       
UN-Number                                                                 
Proper Shipping name                                                      
Hazard Class                                                              
Packing Group                                                             
Classification Code                                                       
Special Provisions                                                        
Description                                                               
Hazard Labels                                                             
Limited Quantity                                                          
                                                                          
15.  REGULATORY INFORMATION                                               
                                                                          
International Inventories                                                 
TSCA                                                                      
DSL                                                                       
EINECS                                                                    
ENCS                                                                      
IECSC                                                                     
PICCS                                                                     
AICS                                                                      
                                                                          
U.S. Federal Regulations                                                  
SARA 313                                                                  
SARA 311/312 Hazard Categories                                            
Acute Health Hazard                                                       
Chronic Health Hazard                                                     
Fire Hazard                                                               
Sudden Release of Pressure Hazard                                         
Reactive Hazard                                                           
                                                                          
Clean Water Act                                                           
                                                                          
CERCLA                                                                    
                                                                          
U.S. State Regulations                                                    
                                                                          
U.S. State Right-to-Know Regulations                                      
                                                                          
International Regulations: EU BATTERY DIRECTIVE: These batteries comply   
with the Directive substance limits and labeling requirements.            
EU REACH REGISTRATION: These products are manufactured articles and not   
subject to REACH registration requirements.                               
EU REACH SVHC: These products contains 1, 2-dimethoxyethane (ethylene     
glycol dimethyl ether) which is listed on the Candidate List of Substances
of Very High Concern.                                                     
EU Labeling: Labeling is not required because batteries are classified as 
articles under the both REACH and the Dangerous Preparations Directive and
as such are exempt from the requirement for labeling.                     
                                                                          
Canada                                                                    
                                                                          
                                                                          
                                                                          
16.  OTHER INFORMATION                                                    
                                                                          
Prepared By:                                                              
Revision Date: March 28, 2013                                             
Company: Duracell, a P&G brand                                            
Revision number                                                           
Telephone number: 203-796-4000                                            
                                                                          
Notes: P&G Hazard Rating: Health: 0 Fire: 0 Reactivity: 0                 
                                                                          
Other Information: Data supplied is for use only in connection with       
occupational safety and health.                                           
                                                                          
Disclaimer information: This PSDS is intended to provide a brief summary  
of our knowledge and guidance regarding the use of this material. The     
information contained here has been compiled from sources considered by   
Procter & Gamble to be dependable and is accurate to the best of the      
Company's knowledge. It is not meant to be an all-inclusive document on   
worldwide hazard communication regulations.                               
This information is offered in good faith. Each user of this material     
needs to evaluate the conditions of use and design the appropriate        
protective mechanisms to prevent employee exposures, property damage or   
release to the environment. Procter & Gamble assumed no responsibility for
injury to the recipient or third persons, or for any damage to any        
property resulting from misuse of the product.                            
                                                                          
                                                                          
END OF MATERIAL SAFETY DATA SHEET                                         




    

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.

Feedback